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The activation energy of each exothermic reaction has been calculated.

计算了晶化过程各放热转变的激活能。

An engine cyclic variation model has been built by using the residual gas temperature for the n-th cycle as the input of the model, through constant pressure intake process, adiabatic compression process, constant volume combustion process, adiabatic expansion process, adiabatic blow down process and constant pressure exhaust process to approximate the thermodynamic processes in the cylinder, finally the residual gas temperature for the (n+1)-th cycle can be estimated.

基于循环间变动的排气温度建立了一个发动机循环变动模型。在这个模型中,第n个循环的排气温度作为模型的输入,通过定压进气过程、绝热压缩过程、定容燃烧过程、绝热膨胀过程、定容放热过程和定压排气过程来近似汽缸内的热力学过程,最后得出第n+1个循环的排气温度。

In order to simulate phenomenologically the process of transformation from fuel injection rate to heat release rate, a quasi-dimensional combustion model has been established, which includes fuel-air mixing, droplet evaporation, ignition delay, heat release and heat transfer.

在只有喷油规律的条件下,本文建立了分韦柏放热规律模型,通过对喷油规律依次分段,各分量按各自韦柏规律燃烧,实现了从喷油规律对放热规律的直接快速预测。

The exothemicity of impregnated catalyst is not only little in air, but exothemicity is little and heat is dispersed during sulfurization. H2S concentration is much higher in effluent gas, if the effluent gas could be recycled, then sulfiding degree of catalyst is increased and resource is saved.

浸渍催化剂不仅在空气中保管时放热温升小,而且硫化时放热少且分散;尾气中H_2S浓度较大,如果能循环利用尾气,那么既能提高催化剂的硫化度又能节省能源。

Promoting heating rate resulted in a shift of the exotherm to a higher temperature, and a more rapid liberation of heat.

提高升温速率会导致放热峰向高温偏移和放热速率加快。

The copolymer derived from the copolymerization in high capacity kettle were testified that copolymerization between AN and MMA occurred. The microcapsules in the films are distributed in the copolymer film matrix. The heat-absorbing temperatures and heat-evolving temperatures of the films are almost the same as that of the MOCT, respectively. In addition, the enthalpy efficiency of MOCT, the melting enthalpy and the crystallizing enthalpy rises with the contents of MOCT increasing.The decomposition temperature of copolymers in the films containing various contents of MOCT decreases with the contents of MOCT increasing.

采用30升聚合釜合成了丙烯腈—甲基丙烯酸甲酯共聚物,证实了丙烯腈和甲基丙烯酸甲酯发生了共聚反应;正十八烷微胶囊分散和镶嵌到了共聚物膜基体中;正十八烷微胶囊含量不同的共聚物膜的吸热温度放热温度与纯正十八烷微胶囊的吸放热温度基本相同;随着正十八烷微胶囊含量的增加,共聚物膜的热焓和热效率逐渐增加;共聚物膜中的共聚物的热稳定性温度随着正十八烷微胶囊含量的增加逐渐减小,共聚物膜的结晶度则有所增大。

Multiple-paths hydrogen abstraction reactions of fluorine -with CH_3OH have been investigated at the MP2/6-311 ++ g level. The potential energy surfaces for H-abstraction reaction from carbon atom and oxygen atom were given respectively. The results indicate that there is only one minimum energy path for hydrogen abstraction from carbon atom, while multiple paths were found for hydrogen abstraction from oxygen atom. All the stationary structures, frequencies as well as PES sketch of all channels were given, in which the dominant channel is by a five-member ring transition state. The calculated heat of reaction is 170.62 kj/mol for channel 1, 119.41 kJ/ mol for branch channel 6. The results are in good agreement with experimental data.

以MP2/6-311 ++g水平上详细研究了氟原子与甲醇抽氢反应的多通道反应机理,得到了各条通道中涉及的驻点的构型和振动频率及其能量,给出了两张完整的反应势能面,结果表明,氟原子从C原子上抽氢时有一条明显的最低能量通道,而从氧原子上抽氢时要涉及多条分支通道和多个驻点构型,给出了各分支通道势能面示意图,结果表明以形成五元环状过渡态通道为优势通道,计算得到经途径1生成CH_2OH时反应放热170.62kJ/mol,经分支途径6生成CH_3O自由基时反应放热119.4 kJ/mol,此结果与实验值一致。

DO6O of XRD analysis and skeletal vibration of IR spectrum reveals that nickel ions were located at the centers of octahedra.

CLS在1000℃左右层结构瓦解,出现一个放热峰,而NiSMM上不存在这一放热峰,表明NiSMM的层结构到1000℃时也未被破坏。

WF exothermic welding is Weaflida's patent product in China, which has the best quality in China as the same product in U.S and U.K. So WF Exothermic welding powder is qualified by national authority test department.

WF放热焊接是Weaflida在中国的专利产品,其放热焊粉也通过了国家权威部门的检测,因此在中国市场上它是同类产品中质量最好的,并达到了美国,英国在此产品中的生产标准。

The morphological structure of cured vinyl-ester resin and the formation of two-phase structures in vinyl-ester resin has been studied by using SEM and differential scanning calorimetry.The results demonstrated the existence of clusters of gel-particles with a size of about 20 μ m,each cluster of gel-particles containing many gel-particles with coral-like structures.The formation of gel-particles resulted in two-phase structure characterized by the two peaks in the rescanned DSC thermographs of the resin. The cure conditions (temperatures,post-cure) affected microstructure in the cured resins.

采用SEM、DSC研究了乙烯基酯树脂固化过程中凝胶粒子的形成过程及两相结构对固化放热的影响,结果表明,凝胶粒子在固化树脂中呈群状分布,每群凝胶粒子的最大尺寸为20μ m左右,每群凝胶粒子由许多独立凝胶粒子组成;凝胶粒子的形成使树脂产生了两相结构,使树脂的恒温DSC残余放热呈双峰分布;树脂的固化条件影响其微观结构。

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