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The results show that for a supersonic shear layer without reaction, a disturbance can make the shear layer become unstable, this results in one vortex or more than one vortex. The combination and seperation of vortex can intensify the mixing. But it is not easy for supersonic reacting shear layer with exotherm to become unstable with disturbance, and the effect duration is very long.

结果表明,对完全气体的超声速剪切层流动,一定的激励方式能使原先较为稳定的剪切层流动变得不稳定,产生单涡或多涡结构,发生多涡间的合并,使混合加剧;但对于存在放热现象的反应超声速剪切层流动,外加激励方式不易使流动从稳定变为不稳定,而且外加扰动的作用特征时间也较长,实际应用前景不乐观。

The initiation temperature of the exotherm of P was little influenced by the atmosphere, however, distinctly decreased with the enhancement of IA content in the copolymer, which implied that the initiation of nitrile cyclization reaction preceded the onset of oxidation reaction through an ionic mechanism.

P共聚物的放热峰起始温度受气氛影响不大,却随着IA含量的增加而明显降低,表明在热稳定化过程中它可能首先以离子机理发生氰基环化反应,再发生氧化反应。

The occurrence of a pre-endotherm is observed when a properly annealed HQG undergoes a calorimetric upscan. The pre-endotherm is followed by an exotherm due to the release of the excess energy stored during hyperquenching, and subsequently by the endothermic glass transition.

如果对一个适当退火的急冷玻璃升温差热扫描,将会先后出现预吸热峰,释放急冷中储存在玻璃中能量的放热峰,以及玻璃转变吸热峰。

Apparent different thermal behaviors between micro-PS and o-PS were observed during DSC scan: micro-PS displayed an irregular exotherm aboveglass transition and an exotherm of about 6.4 J/g at around 157 ℃ during the firstscan, and only one glass transition similar to o-PS was shown in the subsequent scan.

具体表现为两者在热行为方面的差异:第一次DSC扫描过程中,micro-PS出现两个放热峰,第一个不规则且与玻璃化转变重叠,第二个在157 ℃;而第二次DSC扫描则仅表现出与o-PS一样的玻璃化转变。

The second exotherm could be ascribed to the relatively compactconformation of individual polystyrene chains; upon heating during DSC scan, phenylring could stack to form some kind of ordered regions inside micro-PS.

而广角X射线衍射以及in situ FTIR等研究证明第二个放热峰则归因于micro-PS特殊的链构象:DSC升温过程中链的疏松构象易于通过苯环的堆积形成局部链段有序化,从而放出热量(大约6.4 J/g)。

Firstly, the different effect of rectorite modification for the mechanical property of E-51 system were compared; the effect of organic clay for the viscosity and Gel-time of pure E-51 epoxy resin were checked separately; the influence of organic clay for hardening process was studied with FTIR technology; And, the infection of organic rectorite content in matrix for the mechanical property thermal-wet tolerance property aging resistance property and medium endure property for the both of two system were studied relatively. The effect of organization for the inter-layer distance of clay was denoted by XRD technology; To probe into the thermodynamics status about reaction, we investigated the heat discharging of reaction system in the help of DSC. The impact and crooking of solidifying system was observed with the SEM to investigate the decentralization of organic clay, and, at the base of this ,we discuss the mechanism of clay toughing-buildup polymer matrix.

分别考察了有机粘土对树脂体系粘度和凝胶特性的影响,利用红外光谱分析技术研究了有机粘土的加入对体系固化工艺的影响;分别考察了有机粘土含量对二体系的力学性能、耐湿热性能、耐老化性能以及耐介质性能等的影响;采用X-衍射实验表征复合材料中有机粘土层间距的变化;用视差扫描量热法考察了体系的放热情况,以探讨反应的有关热力学状况;通过扫描电子显微分析技术对浇注体的弯曲、冲击断口进行观察分析,以考察、表征有机粘土的分散情况,并在此基础上探讨了有机粘土改性环氧树脂的机理。

For the cement, the surface hydration is the primary process at the initial stage, the kaolin disorganizes and gets into the solution in the form of the silicate tetrahedron and aluminate tetrahedron at the induce stage; the silicon-aluminum tetrahedron network structure is formed at the accelerate stage; the unti-network structure is formed and the rate of heat evolution falls at the decelerate stage; the reaction finished ultimately at the stable stage.

但其水化机理与传统的硅酸盐水泥不同:初始期主要是表面水化,诱导期是高岭土解体并以硅氧四面和铝氧四面体的形式进入液相;加速期形成硅铝四面体网络结构;减速期网络基本形成,水化放热速率降低;稳定期反应速率很低,网络结构趋于稳定。

The heating band has a cloth band (3) made from fibre interfused into radiating far infrared ore powder, a heating body (4) for generating heat, a heat storage body (5) used for storing heat, a alleviation body (6) for slow the heat discharge to the outside, and a bag decorating cloth (7) for enclosing all the cascading components when the band shape cascading components are formed in above order.

其结构为具有由混入放射远红外线矿石粉末的纤维构成的布带(3)、用于使其产生热量的加热体(4)、用于储蓄热量的蓄热体(5)、用于缓慢向外部放热的缓和体(6)、按此顺序层叠,形成带状层叠部件的同时,使用袋状装饰布(7),套装全部层叠部件。

But when it melts,it will lose heat.

但是当它融化时,它也会放热

Therefore,we try to directly couple the endothermic reaction of long chain alkane dehydrogenation with the exothermic reaction of methane catalytic combustion by using the metallic monolithic catalysts,which highly miniaturizes reactor size and significantly increases heat efficiency.

因此,本文以长链烷烃脱氢和甲烷催化燃烧为模型反应体系,利用金属基整体式催化剂将上述吸热与放热催化反应直接进行热耦合,以期实现工艺过程的高度集成并提高热利用效率。

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