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This paper study the adsorption characteristic and application of bentonites on waste water treatment, which is bacesd on previously study on OH-Fe and OH-Fe-Al pillared bentonites.

本文立足于前人的研究,对羟基铁柱撑和羟基铁铝柱撑膨润土的吸附性能及应用进行了实验研究。

The Ti\|pillared rectorite with 16 A interlayer porosities is a new type of clay mineral materials which c...

钛基柱撑累托石具 1 。6nm的层孔隙,是一种很有应用前途的柱撑粘土矿物材料,有望在催化剂载体及环保材料领域中得到广泛的使用。

The results indicate on the same condition the adsorptive effictiveness of organic pillared interlayered montmorillonite on Cr is better than that of purified montmorillonite ,and it is in comfirmity with the the Langmuir adsorption isotherms at the same time; Using Ponceau 4R imitate the dyestuff wasterwater ,the suitable conditions and adsorption isotherms of adsorbing dyestuff wasterwater by organic pillared interlayered montmorillonite are studied .

结果表明:在相同条件下,有机柱撑蒙脱石对Cr~(3+)的吸附效果优于纯蒙脱石,且符合Langmuir吸附等温式;用酸性大红模拟染料废水,研究柱撑蒙脱石的脱色性能及其脱色机理。

Organic pillaring reaction has an important signification for researching the montmorillonite micro structure and understanding the reaction mechanism between natural organic matters and minerals.

蒙脱石有机柱撑反应对于探测蒙脱石内部微结构特征、了解柱撑产物体系中有机物与矿物的作用机制和有机物在层间域内的性质、构型研究都具有重要意义。

Based on the above experiments, the author studied the mixed metallic pillared and modified montmorillonites. The experimental result indicated that the microporous structure of Fe-Al-PLMs was affected by the changing of interlayer Fe-Al polymer with different Fe/Al ratio. But the presence of Al iron was helpful to incorporate Fe iron into interlayer of montmorillonites.. Introducing Zr helped Al-PLMs getting better larger spacing, thermal stability, surface area and pore volumes. Its successful to apply Zr-Al-PLMs to treat wastewater containing Cr iron. The experiment of modifying Al-PLMs by PVA showed that the order of adding starting materials (Al-pillaring solution, PVA, montmorillonite solution) was related to the property of Al-PLMs. The PVA as precursor was beneficial for Al to go into interlayer of the clay and to form larger basal spacing porous clay. The surface area and pore volumes of Al-PLMs increased mainly because of increasing the external surface area and mesoporous volumes after acid-activating. This conclusion confirmed that the microporous structure of pillaring clay depends upon the interlayer pillar.

实验结果表明:在Al-PLMs中引入Fe离子,不同Fe/Al比制得的Fe-Al-PLMs因层间的Fe-Al聚合离子结构不同而影响其微孔结构,但羟基Al离子的存在有利于Fe离子进入蒙脱石层间;在Al-PLMs中引入Zr离子,有助于其层间距、比表面积、孔体积增大,所得Zr-Al-PLMs应用于含Cr废水处理效果显著;PVA改性后的Al-PLMs其物化性质变化与铝柱化剂、PVA溶液、蒙脱石溶液三者不同添加顺序有关,说明PVA的前撑有利于Al进入蒙脱石层间得到较大层间距的Al-PLMs;经酸化处理得Al-acid-PLMs,其比表面积增大以外表面积为主,孔体积增大以中孔为主,这也证实了柱撑蒙脱石的微孔结构取决于其层间的柱化物。

Pillared montmorillonite, as a representative of Sandwich like pillared interlayered clays ,caught many scientist"s attention not only because of its special structure of two-dimensional sheets but also its excellent activity of catalysis and adsorption. It is well documented that the method to prepare PILM, ion-exchanging, needed a long periods and was affected by many factors, and that the product had low thermal stability especially hydro-thermal stability which was the primary obstruction of its using in large-scale production. At the same time, PILM was well documented prepared with Na-montmorillonite, while there were a few documents about PILM prepared with Ca-montmorillonite. The large cost of remodel of Ca-montmorillonite to Na-montmorillonite was another obstacle of the application of PILM, while Ca-montmorillonite was widely distributed in nature, as a result, to prepare PILM with Ca-montmorillonite has practical significance. What"s more, PILM was mainly studied as a catalyst in oil refining process till now, but rarely documented in other catalysis reactions, especially in coal liquification filed which also needed high activity catalyst.

以柱撑蒙脱石为代表的具有&三明治&结构的柱撑粘土矿物因其特殊的二维孔道结构和优良的催化和吸附性能近年来成为国内外广泛关注和研究的热点,但是目前国内外大量报道的PILM制备大多采用离子交换法,生产周期很长,影响因素很多,并且产物热稳定性不够高,特别是水热稳定性较差,这是其不能在实际中大规模生产和应用的主要障碍,因此制备一种高稳定性的PILM意义非常;文献中大量报道的都是钠基蒙脱石合成的柱撑粘土矿物,传统的离子交换法必须将钙基蒙脱石钠化改型,其成本相当高,而自然界中大量存在的却是钙基蒙脱石,直接用钙基蒙脱石合成柱撑粘土矿物有很现实的意义,但目前这方面的报道却很少见;另外,迄今为止,PILM作为催化剂的研究领域主要在石油的炼制中应用,而在煤炭的液化中却鲜有报道,如果能在煤炭转化领域应用这一成果,其影响也将是相当大的。

Pillared montmorillonite, as a representative of Sandwich like pillared interlayered clays ,caught many scientist's attention not only because of its special structure of two-dimensional sheets but also its excellent activity of catalysis and adsorption. It is well documented that the method to prepare PILM, ion-exchanging, needed a long periods and was affected by many factors, and that the product had low thermal stability especially hydro-thermal stability which was the primary obstruction of its using in large-scale production. At the same time, PILM was well documented prepared with Na-montmorillonite, while there were a few documents about PILM prepared with Ca-montmorillonite. The large cost of remodel of Ca-montmorillonite to Na-montmorillonite was another obstacle of the application of PILM, while Ca-montmorillonite was widely distributed in nature, as a result, to prepare PILM with Ca-montmorillonite has practical significance. What's more, PILM was mainly studied as a catalyst in oil refinin g process till now, but rarely documented in other catalysis reactions, especially in coal liquification filed which also needed high activity catalyst.

以柱撑蒙脱石为代表的具有&三明治&结构的柱撑粘土矿物因其特殊的二维孔道结构和优良的催化和吸附性能近年来成为国内外广泛关注和研究的热点,但是目前国内外大量报道的PILM制备大多采用离子交换法,生产周期很长,影响因素很多,并且产物热稳定性不够高,特别是水热稳定性较差,这是其不能在实际中大规模生产和应用的主要障碍,因此制备一种高稳定性的PILM意义非常;文献中大量报道的都是钠基蒙脱石合成的柱撑粘土矿物,传统的离子交换法必须将钙基蒙脱石钠化改型,其成本相当高,而自然界中大量存在的却是钙基蒙脱石,直接用钙基蒙脱石合成柱撑粘土矿物有很现实的意义,但目前这方面的报道却很少见;另外,迄今为止,PILM作为催化剂的研究领域主要在石油的炼制中应用,而在煤炭的液化中却鲜有报道,如果能在煤炭转化领域应用这一成果,其影响也将是相当大的。

Help the discussions above is useful for the relative research in the future. From experiment, we found the gussets buckle without stiffeners. After adding stiffeners at the edges of gusset, the buckling of gussets never occurred.

试验过程当中发现斜撑之接合板在未加劲之下会产生挫屈的现象,而在加劲过后挫屈现象便受到有效的控制,分析中发现亦可以缩短斜撑端部与所接梁柱之距离来避免接合板挫屈的发生。

Border fills the frame that prop up (Knee-braced Frame, KBF) is one ductility cost is set around bridge column connective can border is maintained, advocate the aseismatic construction system that the join that prop up is maintained in this border and makes.

梗概: 隅撑支撑框架(knee-braced frame,KBF)是在梁柱连接的四周设一延性耗能的隅撑,主支撑连接在此隅撑上而构成的抗震结构体系。

There are three main types of shoring – raking, flying and dead shore.

主要有三种类型的支撑,斜撑、横撑和支撑柱

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