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The feet and tail support the tripod , and the bird's wings stretch backward as if it is pouncing on something.

鹰的双足和尾部为鼎足稳定地撑柱于地,后收的双翅围过鼎的中后部,形成一种前扑的动势

The feet and tail support the tripod, and the bird's wing s stretch backward as if it is pouncing on something.

鹰的双足和尾部为鼎足稳定地撑柱于地,后收的双翅围过鼎的中后部,形成一种前扑的动势

Pillared montmorillonite, as a representative of Sandwich like pillared interlayered clays ,caught many scientist"s attention not only because of its special structure of two-dimensional sheets but also its excellent activity of catalysis and adsorption. It is well documented that the method to prepare PILM, ion-exchanging, needed a long periods and was affected by many factors, and that the product had low thermal stability especially hydro-thermal stability which was the primary obstruction of its using in large-scale production. At the same time, PILM was well documented prepared with Na-montmorillonite, while there were a few documents about PILM prepared with Ca-montmorillonite. The large cost of remodel of Ca-montmorillonite to Na-montmorillonite was another obstacle of the application of PILM, while Ca-montmorillonite was widely distributed in nature, as a result, to prepare PILM with Ca-montmorillonite has practical significance. What"s more, PILM was mainly studied as a catalyst in oil refining process till now, but rarely documented in other catalysis reactions, especially in coal liquification filed which also needed high activity catalyst.

以柱撑蒙脱石为代表的具有"三明治"结构的柱撑粘土矿物因其特殊的二维孔道结构和优良的催化和吸附性能近年来成为国内外广泛关注和研究的热点,但是目前国内外大量报道的PILM制备大多采用离子交换法,生产周期很长,影响因素很多,并且产物热稳定性不够高,特别是水热稳定性较差,这是其不能在实际中大规模生产和应用的主要障碍,因此制备一种高稳定性的PILM意义非常;文献中大量报道的都是钠基蒙脱石合成的柱撑粘土矿物,传统的离子交换法必须将钙基蒙脱石钠化改型,其成本相当高,而自然界中大量存在的却是钙基蒙脱石,直接用钙基蒙脱石合成柱撑粘土矿物有很现实的意义,但目前这方面的报道却很少见;另外,迄今为止,PILM作为催化剂的研究领域主要在石油的炼制中应用,而在煤炭的液化中却鲜有报道,如果能在煤炭转化领域应用这一成果,其影响也将是相当大的。

Pillared montmorillonite, as a representative of Sandwich like pillared interlayered clays ,caught many scientist's attention not only because of its special structure of two-dimensional sheets but also its excellent activity of catalysis and adsorption. It is well documented that the method to prepare PILM, ion-exchanging, needed a long periods and was affected by many factors, and that the product had low thermal stability especially hydro-thermal stability which was the primary obstruction of its using in large-scale production. At the same time, PILM was well documented prepared with Na-montmorillonite, while there were a few documents about PILM prepared with Ca-montmorillonite. The large cost of remodel of Ca-montmorillonite to Na-montmorillonite was another obstacle of the application of PILM, while Ca-montmorillonite was widely distributed in nature, as a result, to prepare PILM with Ca-montmorillonite has practical significance. What's more, PILM was mainly studied as a catalyst in oil refinin g process till now, but rarely documented in other catalysis reactions, especially in coal liquification filed which also needed high activity catalyst.

以柱撑蒙脱石为代表的具有"三明治"结构的柱撑粘土矿物因其特殊的二维孔道结构和优良的催化和吸附性能近年来成为国内外广泛关注和研究的热点,但是目前国内外大量报道的PILM制备大多采用离子交换法,生产周期很长,影响因素很多,并且产物热稳定性不够高,特别是水热稳定性较差,这是其不能在实际中大规模生产和应用的主要障碍,因此制备一种高稳定性的PILM意义非常;文献中大量报道的都是钠基蒙脱石合成的柱撑粘土矿物,传统的离子交换法必须将钙基蒙脱石钠化改型,其成本相当高,而自然界中大量存在的却是钙基蒙脱石,直接用钙基蒙脱石合成柱撑粘土矿物有很现实的意义,但目前这方面的报道却很少见;另外,迄今为止,PILM作为催化剂的研究领域主要在石油的炼制中应用,而在煤炭的液化中却鲜有报道,如果能在煤炭转化领域应用这一成果,其影响也将是相当大的。

X-ray diffraction showed that the hydroxy-chromium oligocations can be used as a stable pillaring agent after aging at 70 ℃ for four days, and a pillared composite with high crystallinity can be obtain...

与原料2H-MoS2相比,柱撑材料的层间距增大,晶粒变小,比表面积增加并且热稳定性提高。对催化苯饱和加氢反应表明,柱撑材料Cr-MoS2的催化活性明显优于未柱撑的2H-MoS2和RaneyNi催化剂,且结晶度较好的柱撑材料更具有较高的催化活性和较好的可重复性。

The results indicate that the pillaring process and crystal growing of anatase can be more easily realized by increasing the acid-base ratio of pillaring agents, raising the pillaring temperature and adding proper quantities of alkali. The calcination of Ti-pillared precursor brings the growth of TiO2 grain, at the same time the layer distance is declined. In order to obtain ideal products, the right pillaring conditions are: the acid-base ratio of pillaring agents of 13, pillaring temperature of 65 ℃ and the volume of alkali (2 mol/L) in pillaring liquid of 6 mL.

结果表明:在一定范围内增大柱撑剂酸碱比、提高柱撑温度以及加入适量碱,有利于插层复合反应的进行和锐钛晶型的生长;柱撑前驱物焙烧后TiO2晶粒长大,同时焙烧引起的脱水导致膨润土层间距的下降;为获得较理想的产物,合适的柱化条件为:柱撑剂酸碱比 n n (HNO3)为13、柱撑温度65 ℃和柱撑液加碱量为(2 mol/L NaOH) 6 mL。

First, organic pillared montmorillonite were prepared in which three kinds of organic quaternary ammonium salts were used as pillaring agent. Physiochemical properties of organic pillared montmorillonites were characterized by XRD, FT-IR, TG-DTA. Furthermore their characters that have been testified are excellence.

首先用三种有机季胺盐作为柱撑剂制各出有机柱撑蒙脱石,并通过XRD、FT-ZR、TG-DTA等测试手段对其进行了表征,并且对制备的有机柱撑蒙脱石进行了性能测试,证明其性能优良,说明利用干法制备有机柱撑蒙脱石是切实可行的。

The experimental results show that the optimum preparation conditions of catalyst of SO42-/Zr-CLC are achieved :pillaring material is 0.5mol/l ZrOCb,Zr/clay is 3mmol/g,accelerant is (NH4)2SO4 and the quantity of SO42- is 30%, the precursor of Zr-CLC is dipped by SO42- and is calcinated at temperature of 500 癈 for 2h.

将聚合羟基锆阳离子交联剂通过离子交换引入膨润土层间域撑柱膨润土,同时通过浸渍将SO42-引入到膨润土层间的锆阳离子表面,高温焙烧活化,合成了催化性能良好的中孔固体酸催化剂SO42/Zr-CLC,同时对催化剂的性能和结构进行了研究。

Red lacquer亭内logs from Kim, plus four檐柱granite, glazed double up the head of green glazed tile roofs and a sharp ding save.

亭内由四根朱漆圆木金柱,外加四根花岗岩檐柱,撑起头上双重的琉璃碧瓦的飞檐和一个攒尖宝顶。

The main product categories: PEM standard parts: pressure riveting nut; pressure riveting nut column (SO, SOO, BSO-type); insert nut; pressure rivets; pressure riveting screw ; floating nut; Squeeze Nut; grounding nut column; spring screws; positioning shoring holders; positioning pin and so on.

主要产品种类: PEM标准件:压铆螺母;压铆螺母柱(SO、SOO、BSO类);镶螺母;压铆钉;压铆螺钉;浮动螺母;挤压螺母;接地螺母柱;弹簧螺丝;定位持撑柱;定位销等。

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