摩尔体积

This basic research is armed to find out and to predict SCF particularity, which are very important for the SCF application. Firstly the densities of the binary mixtures of CO2—methanol, CO2—ethanol, CO2—n— butyraldehyde and CO2—i—butyraldehyde were measured from 313.5K to 323.5K under the pressure range from 7 to 14MPa.

本文首先在313.5～323.5K、7～14MPa范围内测定了CO2及CO2—甲醇、CO2—乙醇、CO2—正丁醛、CO2—异丁醛二元混合流体的表观密度，讨论了压力、第2组分的种类和加入量对CO2表观密度的影响，在此基础上计算了溶质的偏摩尔体积，讨论了温度、压力和第2组分的性质对溶质偏摩尔体积的影响规律。

The experimental results show that the transfer volumes for these amino acids from water to sodium acetate, sodium butyrate, sodium caproate, sodium caprylate and guanidium hydrochloride solution are positive and increase with the increasing concentration of denaturant The standard partial molar transfer volume of zwitterionic end group (NH〓, CO0〓) are larger positive values and the corresponding values of methylene group CH〓 are smaller and negative.

实验结果表明，氨基酸从水到乙酸钠、丁酸钠、己酸钠、辛酸钠和盐酸胍水溶液的标准转移偏摩尔体积为正值，且随变性剂浓度的增加而增大；氨基酸的两性端基的标准转移偏摩尔体积为较大的正值，而CH〓基团标准转移偏摩尔体积为较小的负值。

The excess molar volumes of {1,8- cineole +CCl 4,+CHCl 3} were determined as a function of mole fraction x using a vibrating-tube densimeter at the temperatures 298 15 and 308 15K All mixtures exhibit negative values over the entire composition range at both temperatures.

在 2 98 15K和 30 8 15K下用振动管密度计在全浓度范围内测量了桉叶油素分别与四氯化碳和三氯甲烷构成的二元系的过量摩尔体积。这 2个二元系的过量摩尔体积均为负值，且桉叶油素与氯仿的过量体积显著大于桉叶油素与四氯化碳的过量体积

Both the and DtV$ for the glycyl dipeptides increase with increasing molality of sodium acetate. The interactions between charged center or glycyl units of the peptide and ions dominate those between alkyl groups of the peptide and the ions. The interaction between the peptides and sodium acetate is mainly pairwise. The results were interpreted successfully by the cosphere overlap model.

结果表明：甘氨酰二肽的标准偏摩尔体积和标准偏摩尔转移体积均随乙酸钠浓度的增加而增大，溶液中离子与肽带电基团/甘氨酰基团(CH2CONH)之间的相互作用大于离子与肽的非极性基团间的相互作用，乙酸钠和甘氨酰二肽之间主要是对相互作用。

The molar volume of gas is important too.

气体摩尔体积也是同等重要，我们应该学会一些简单的关于物质的量和气体摩尔体积之间的计算，并且要善于发现它与质量与物质的量之间计算的不同点！

An improved hard-sphere model predicted rightly the changing trend of the standard partial molar volume of alkyl chain of amino acids with concentration of electrolyte,and confirmed the assumption that the sum of standard partial molar volume s of CH and CH3 groups is twice as many as the standard partial molar volume of CH2 group.

根据改进的硬球混合物模型，正确预测了氨基酸分子的烃链在电解质水溶液中的标准偏摩尔体积随电解质浓度的变化关系，并证实了"氨基酸分子中CH和CH3基团的标准偏摩尔体积之和是CH2基团标准偏摩尔体积的2倍"这一假定。

Densities of glycine and L-serine in aqueous LiNO3, NaNO3 and KNO3 solutions have been measured at 298.15 K with an Anton Paar Model 55 densimeter. Apparent molar volumes, limiting partial molar volumes and transfer volumes have been calculated. Hydration numbers and volumetric interaction coefficients for amino acids were evaluated.

用Anton Paar DMA 55精密数字密度计测定了甘氨酸和L-丝氨酸在LiNO3， NaNO3和KNO3水溶液中的密度，计算了氨基酸的表观摩尔体积、极限偏摩尔体积、迁移偏摩尔体积、理论水化数和体积作用系数。

In this part, the densities of sodium benzoate, sodium nitrobenzoate, sodium chlorobenzoate and sodium methylbenzoate in DMFwater mixed solvents have been measured at 298.15K with an Anton Paar Model 55 densimeter. From these densities, apparent molar volumes and partial molar volumes have been calculated, transfer volumes from water to DMF-water mixtures and substituent contributions to the transfer volumes have also been obtained. Solvent and substituent effects are discussed in detail. The Scaled Partical Theory has been applied to the ternary solutions to evaluate the partial molar volumes of cavity formation and the volumes change associated with solute-solvent interaction.

选择了含有取代基团的芳香类有机电解质，主要是苯甲酸钠、硝基苯甲酸钠、氯苯甲酸钠和甲基苯甲酸钠的邻、间、对同分异构体作为研究对象，用DMA 55型振荡管密度计测定了它们在不同质量百分数组成的DMF-水混合溶剂中的密度，利用这些密度数据，计算了表观摩尔体积和偏摩尔体积，得到了这些单取代苯甲酸钠从水到DMF-水混合溶剂中的迁移偏摩尔体积及苯环上不同位置的取代基对迁移偏摩尔体积的贡献值，讨论了溶剂效应和取代基效应，并将定标粒子理论应用于此三元电解质溶液中。

Densities of glycylglycine in sucrose-water mixed solvent have been measured at 288.15, 298.15 and 308.15 K by Anton Paar DMA55 vibrating-tube digital densimeter. The apparent molar volume VΦ, limiting partial molar volume , partial molar volumes of transfer Δtrs from water to sucrose-water mixed solvent and the hydration numbers Nh for glycylglycine have been calculated.

利用Anton Paar DMA55精密数字密度计测定了288.15， 298.15和308.15 K甘氨酰甘氨酸在蔗糖-水混合溶剂中的密度，计算了甘氨酰甘氨酸的表观摩尔体积VΦ和极限偏摩尔体积，得到了其由纯水溶剂转移至混合溶剂中的迁移偏摩尔体积Δtrs 和理论水化数Nh。

Densities of glycine in glucose-water and sucrose-water mixed solvents have been measured to 298.15 K by an oscillating-tube densimeter. Apparent molar volumes, limiting partial molar volumes and number of hydration of glycine have been calculated. The transfer volumes from water to sugar-water mixtures have been obtained and discussed in terms of the structural hydration interaction model.

利用精密数字密度计测定了甘氨酸与不同组成葡萄糖-水、蔗糖、水混合溶剂构成的三元系溶液的密度，计算了甘氨酸的表观摩尔体积、极限偏摩尔体积和理论水化数，根据结构水合作用模型讨论了迁移偏摩尔体积的变化规律，并与乙二醇-水和丙三醇-水等多羟基体系作了比较。

The absorption and distribution of chromium were studied in ryeusing nutrient culture technique and pot experiment.

采用不同浓度K2CrO4(0，0.4，0.8和1.2 mmol/L)的Hoagland营养液处理黑麦幼苗，测定铬在黑麦体内的亚细胞分布、铬化学形态及不同部位的积累。

By analyzing theory foundation of mathematical morphology in the digital image processing, researching morphology arithmetic of the binary Image, discussing two basic forms for the least structure element: dilation and erosion.

通过分析数学形态学在图像中的理论基础，研究二值图像的形态分析算法，探讨最小结构元素的两种基本形态：膨胀和腐蚀；分析了数学形态学复杂算法的基本原理，把数学形态学的部分并行处理理念引入到家实际应用中。