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Research on Peculiarity of All-Optical Poling for the Azo Adulterant Polymer Spin Film.

偶氮掺杂聚合物旋涂膜的全光极化特性研究。中国激光, 2008, 35(s1): 153~156

Because pat guest content to pay close attention to spent uncertainty, and adulterate without copyright content in great quantities among them.

由于拍客内容关注度的不确定性,以及大量无版权内容掺杂其中。

Use semiconductor to adulterate to also can improve the smooth catalysis performance of TiO_2 film well, among them with SnO_2 effect best.

采用半导体掺杂也能很好地提高TiO_2薄膜的光催化性能,其中以SnO_2效果最好。

This would also be the case if the products demonstrate actual adulteration or misbranding.

这也有一种情况,产品表明有实际的掺杂或贴错假标记。

The composi-tion of the seawater has changed rapidly since Phanerozoic, and the prolonged mineralogical changes of marine non-skeletal limestone and potash evaporates occurred in a phase on a 100-200 Ma.

结果表明:显生宙以来海水组分发生变化,经海相非骨骼灰岩和钾盐蒸发岩矿物学研究,发现这两种沉积岩长期以来连续变化,在"文石海"是MgSO4型蒸发盐,在"方解石海"是KCl型蒸发盐,从白垩纪晚期、第三纪早期的底部石盐溴含量及矿物学特征表明,此时处于"方解石海",古海水组分的特点是造成缺硫酸盐型钾盐矿床形成的物化基础;通过NaCl-KCl-MgCl2-H2O和NaCl-KCl-MgCl2-CaCl2-H2O两个体系相图的分析认为,当时所形成的成钾原始体系母液是高镁、低钾氯化物型的卤水,在母液蒸发过程中,由于原始海侵母液与残余高镁母液的掺杂作用,致使结晶路线直接从氯化钠区到E点母液或光卤石与氯化钠共饱线上,而没有通过氯化钠和氯化钾的共饱线,因而在矿体中氯化钾相很少或几乎不存在,由于外界CaCl2型水体的掺杂,使成钾母液进入光卤石相区,随着蒸发的进行,最终形成溢晶石矿物。

The results showed that the TiN andN films are polycrystalline phase. The properties and structure of TiN films are mainly determined by the N2 mass flow rate, and as the N2 mass flow rate increases, the structure of the TiN films transforms to f.c.c. type leading to better the properties of films. The presence of negative bias voltage can optimize the grain of TiN films, lower the defect proportion and denser the films, which improves the hardness of films. The TiN films conform to the free carrier absorption mechanism and there are many of free electrons with lower N content in TiN films. With the increase of N content, the quantity of free electrons and reflectivity of films decrease, and the plasma frequence shifts to the lower energy, which leads to the regular change of colors of films from silver, yellowy, golden to yellow-red, meanwhile the lightness of films decreases. The goldenN film consists of TiN and ZrN phase, but belongs to a sigle f.c.c. structure with (111) preferred orientation. The Zr-doping dosen't change the position of the valance band, conduction band and forbidden band ofN film, but leads to the presence of new energy levels, which is the reason thatN film remains golden. The transparent hard films with good corrosion resistance and high hardness have been prepared and the further reseachs showed that the grain size of those films is by far smaller than the wave length and the width of forbidden band of those films is very broad, is the reasons that those films are transparent.

研究表明:氮化钛和N 薄膜为多晶态,氮流量决定了氮化钛薄膜的结构和性能,增加氮流量能使氮化钛薄膜的结构向面心立方结构转变,从而得到性能良好的氮化钛薄膜;施加负偏压能优化氮化钛晶粒和减少薄膜中的缺陷,使膜层变得更致密,从而提高薄膜硬度;氮化钛主要遵循自由载流子光吸收,氮含量较少时薄膜中的自由电子数目较多,随着氮含量的增加,薄膜中的自由电子数目不断减少,反射率逐渐降低,等离子体频率向低能端移动,从而使薄膜颜色出现规律变化,由金属色银白色到淡黄、金黄再到红黄,并且薄膜亮度呈下降趋势;金黄色的N 薄膜中存在TiN 和ZrN 的分离相,但其为单一的面心立方结构并具有(111)面择优取向;相对于TiN 薄膜,Zr 掺杂后,并没有使薄膜的导带、价带和禁带发生变化,只是在TiN 禁带内增加了新能级,这也正是掺杂Zr 后,薄膜仍

In Chapter 5, photo-induced absorption is used to study the intersystem crossing from singlet to triplet states of two polyfluorenes after doped with Ir-complex. It is found that the triplet exciton lifetime of PFs is reduced by the dopants. But instead of decreasing, the population density of PF triplet exciton increases by almost one order of magnitude. The finding shows that the ISC rate can increase over 100 times due to the spin-orbital interaction with the Ir ions.

第五章以光诱发吸收光谱技术研究两种聚芴高分子掺杂绿光铱错合物后,聚芴的单重态到三重态的内部系统转换效率的改变;研究发现在掺杂后,聚芴的三重态生命期减短,但出乎意料的是其三重态的态密度并没有随之降低反而有一个数量级的增加,其原因为单重态到三重态的内部系统转换受铱错合物的影响效率增加了100倍。

We adopted DCJTB and TBPe to make two homochrom OLEDs as the red and blue dyes, the configurations are respectively as follows: ITO/CuPc(15nm)/NPB(50nm)/Alq3(30 nm):rubrene: DCJTB(6.1)/Alq3(30nm)/LiF(1nm)/Al(100nm),(x=2,3.7,4.2,5 nm,the dopped concentration is 1.1%,2.1%,2.3% and 2.8% respective -ly) for red OLEDs and ITO/CuPc(150 nm)/NPB(500 nm)/ADN(300 nm):TBPe(30 nm)/Alq3(350 nm)/RbF(20 nm)/Al(1,000 nm)for blue OLED. We discussed the electroluminescent mechanism and the infection of the dopped concentration of rubrene on the perform -ances of red OLEDs; And after a lot of designments and manufactures we found an integrated and reasonable scheme,and carried out some test -ings and discussions on the characteristics of current -voltage curve, efficiency- voltage curve and luminescence-spectrum curve and so on. Subsequently,we made two kinds of WOLEDs.

然后分别采用以DCJTB和TBPe作为红色、蓝色发光染料制作了两种单色OLED器件,制备了器件结构为ATO/CuPc(15nm)/NPB(50nm)/Alq3(30 nm):rubrene:DCJTB(6.1 nm)/Alq3(30nm)/LiF(1nm)/ Al(100nm),(其中x=2、3.7、4.2、5nm,rubrene的掺杂比例为1.1%、2.1%、2.3%、2.8%)的红光OLED器件和结构为ITO/CuPc(150 nm)/NPB(500 nm)/ADN(300 nm):TBPe(30 nm)/Alq3(350 nm)/RbF(20 nm)/Al(1,000 nm)的蓝光OLED器件;讨论了红光OLED器件的发光机理,以及rubrene的掺杂浓度对发光效率等性能的影响;从蓝光器件的设计和制备入手,摸索出了一套完整而可行的制作方案,分别对器件的电压-亮度特性、电压-发光效率特性及发光光谱等特性进行了测试与讨论。

R peak of BNT-BKT ceramics doped with Nd_2O_3 became wider than the basic ceramics without Nd_2O_3. All the ceramics are relaxor ferroelectrics proved by Curie-Weiss law measured at 10 kHz. Otherwise, d_(33) and K_p took on increasing trend and then decreasing trend.

Nd_2O_3掺杂后的陶瓷介电常数整体趋势随Nd_2O_3掺杂量的增高而降低,介电峰呈现更加宽化的趋势,并且从10kHz下的居里-外斯关系图得出在研究范围内所有陶瓷样品均为驰豫铁电体;随Nd_2O_3含量的增加,d_(33)和K_p呈先升高后下降的趋势。

The results show that perfect anatase nanocrystalline TiO2 can be obtained by SGRTSE method and the photocatalytic activity of TiO2 can be improved by doping and surface treatment. In the experimental system, the addings of proper salts are beneficial to the photocatalytic degradation of DBSNa. The pH value of solution, adding amount of TiO2, flow rate of air, and initial concentration are the main influence factors for the photocatalytic degradation of methyl orange, and the apparent reaction order is pseudo-first-order, which could be described by Langmuir- Hinshelwood equation.

结果表明:sol-gel法结合室温溶剂蒸发诱导可制备出晶型良好的锐钛型纳米TiO_2;过渡元素和稀土元素杂原子掺杂,贵金属掺杂和表面酸化处理是有效提高TiO_2光催化活性的途径;试验体系中,在DBSNa的降解过程中加入适量的盐,可以大大加速降解效果;光催化降解水中有机物,溶液pH值,TiO_2投加量,曝气速率,被降解物起始浓度等是影响降解效果的重要因素;对起始浓度较低的有机物光催化降解过程可利用简化的Langmuir-Hinshelwood动力学方程进行描述,反应级数为拟一级。

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然而,正如其名字所指出的那样,CD盘不能写,也不能用任何方式改变其内容。

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