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The factors like temperature, kinds and content of adulterant, in SrCeO_3 basis high temperature proton conductor preparation whose construction and performance was influenced, were studied.

利用紫外可见光谱、红外光谱和拉曼光谱研究了SrCeO_3基系列高温质子导体的结构及性能随掺杂种类、掺杂量、烧结及不同气氛下的变化,佐证了掺杂SrCeO_3体系质子导体的形成机理。

It indicates that the PANI particles constituted films are ball like or ellipsoid like; the film takes on tertiary structure; HClO4 servers as both an acid medium and a dopant; the crystallizability of the film seems poor; the relationship between film thickness and acid concentration is not in linearity; the conductivity of the film is on a level with semiconductor, whose value depend more on film appearance than acidity of acid medium; the film starts dedoping at 67.3℃ and end at 277.2℃.

结果表明,构成薄膜的聚苯胺粒子呈球型或椭球型;薄膜具有三级结构特征;高氯酸不仅作为介质酸,同时作为掺杂剂;薄膜的结晶性能不佳;薄膜厚度与介质酸的浓度并非线性关系;薄膜的电导率处于半导体水平;电导率大小与无机介质酸的酸性强弱有一定关系,与表面形貌关系更为紧密;高氯酸掺杂聚苯胺薄膜在67.3℃时开始脱掺杂,在277.2℃脱除完全。

The results show that the compound conductive fiber has typical structure of sheath-core consists of black greened polyaniline electric conductive deposition as the skin and the white polypropylene matrix fiber as the core, which makes the compound fiber preferable physical mechanical property. The intensity and the elongation ratio of the electric conductive fiber are decreased but the thermal stability is enhanced after modified. The compound fiber has the good acid resistance but poor base resistance. The thermal stability of the compound fiber prepared by 4-methyl-benzene sulfonic acid is better than that prepared by hydrochloride acid. Moreover, the compound fiber can be re-doped by other organic or inorganic acid after freed from the adsorbed acid. Furthermore, the electric conductivity of the compound fiber decreases with the temperature increasing but hardly changed with the humidity. The adsorptive ability and therefore the content of the polyaniline, the constant of electric conduction, and the durability of the compound fiber can be enhanced by thinning the diameter, section heteromorphosis, section heteromorphosis and plasma treatment of the surface or blending with COPET of the fiber.

结果表明:复合纤维是聚丙烯与聚苯胺的共混体系,具有典型的皮芯型结构,皮层为墨绿色的聚苯胺沉积层,形成连续的导电通道,芯层为白色的聚丙烯基质纤维,提供物理机械性能;导电改性后纤维的强度、强力和伸长率均有下降,但热稳定性得到提高;复合纤维的耐酸性比耐碱性好,以对甲苯磺酸做掺杂酸比盐酸掺杂聚苯胺热稳定性好,脱掺杂后的复合纤维,可用其它无机酸或有机酸进行再掺杂;复合导电纤维的电导率随温度升高降低幅度较大,但几乎不受湿度影响;基质纤维细旦化、截面异形化、表面等离子体处理或共混COPET等改性处理均能提高纤维的吸附性,进而提高复合纤维表面聚苯胺含量、电导率和耐久性。

Alternate outgrowthprocess is firstly used to form over 1.0μm thickArsenic heavily doped inner polysilicon layer and slightly doped outer polysilicon layer.T-shaped edge field emitters are fabricated with the HHC etchant.

首次采用"交替生长"技术生长内层厚度超过1.0μm重掺杂砷和外层轻掺杂砷的双层多晶硅薄膜,利用氢氟酸、硝酸、冰醋酸腐蚀液对不同掺杂浓度多晶硅选择性腐蚀的特点成功制备T形横向边缘场致发射阴极阵列。

All crystalline structrue has been investigated by XRD, on the basis of which the relationship between dopant dose and lattice constant and the size effect of phase transformation were discussed.

利用XRD研究了掺杂钛酸铅纳米晶的晶体结构,以此为基础讨论了掺杂量与晶格常数变化的关系以及相变的尺寸效应,并研究了掺杂纳米晶的相组成和晶胞参数。

Said lead tungstate crystal comprises tungsten oxide, lead monoxide, ytterbium oxide and zinc oxide; the molar ratio between tungsten oxide and lead monoxide is 1: 1, the doping amount of ytterbium oxide is 50 -300 ppm of the total weight of tungsten oxide and lead monoxide, the doping amount of zinc oxide is 50 -1050 ppm of the total weight of tungsten oxide and lead monoxide.

Yb和Zn双掺杂钨酸铅晶体由氧化钨、氧化铅、氧化镱和氧化锌制成;氧化钨与氧化铅的摩尔比为1∶1,氧化镱的掺杂量为氧化钨和氧化铅总质量的50~300ppm,氧化锌的掺杂量为氧化钨和氧化铅总质量的50~1050ppm。

According to the radius of doping metal ions and lattice parameter of doping samples, it was confirmed that doping metal ions replaced the Mn〓 of spinel LiMn〓O〓.

根据掺杂阳离子的半径和掺杂对尖晶石LiMn〓O〓晶格常数的影响规律确定了掺杂阳离子是进入到原来Mn〓占据的位置。

Finally, the relationship between the performance of doped a-Si: H and process conditions is discussed, which includes the deposition of n〓-a-Si: H and p〓-a-Si: H, the relationship between dark conductivity, photoconductivity of boron light-doped a-Si: H and process conditions, and the relationship between the stability of LCLV and S-W effect of a-Si: H.

最后讨论了掺杂a-Si:H的性能与工艺条件的关系,包括重掺杂n〓、p〓非晶硅的制备,硼轻掺杂a-Si:H的暗态电导率与工艺条件的关系,硼轻掺杂a-Si:H的光电导与工艺条件的关系,以及液晶光阀的稳定性与a-Si:H的S-W效应。

It is indicated that none of the three dopants had effects on thegeometric properties of the T-grain.

随着掺杂量和掺杂位置的不同,掺杂后基本乳剂的感光度有不同的变化。

For example, when there is only an alcohol as dopant, fiber-shaped nanostructure polyaniline is easily formed; when there is only a metallic ion as dopant, sphere-shaped nanostructure polyaniline is easily formed; when alcohol and metallic ion coexist, fibrous and sphere-shaped nanostructure polyaniline are formed at the same time.

如仅有醇类掺杂剂存在下,苯胺易于聚合成纤维状纳米结构的聚苯胺;仅有金属离子掺杂剂存在下,苯胺易于聚合成球形纳米结构的聚苯胺;在醇和金属离子掺杂剂共存时,苯胺能同时聚合成纤维状和球形纳米结构的聚苯胺。

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It has been put forward that there exists single Ball point and double Ball points on the symmetrical connecting-rod curves of equilateral mechanisms.

从鲍尔点的形成原理出发,分析对称连杆曲线上鲍尔点的产生条件,提出等边机构的对称连杆曲线上有单鲍尔点和双鲍尔点。

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血精的原因很,以良性病变为主。