掺加物

The Diels-Alder cycloadditions of [60] fullerene for preparation of optical limitingmaterials are discussed in chapter 3 and 6. Soluble cycloaddition derivatives of 〓aresynthesized by the reaction of 〓 with indene,1,1'-biindene andcyclopentadiene derivatives.〓Particular, the Diels-Alder cycloaddition of 〓 with1,1'-biindene under controlled conditions affords the stable monoadduct 〓〓of novel structure, which was confirmed by HPLC, FTIR, FD-MS,〓NMR,〓 NMR, HMQC and HMBC spectra, Its two bridgehead cage carbons resonate at70.91ppm, The 〓 NMR spectra showed 38 lines consistent with the 〓 symmetryassociated with [6,6] addition. The 〓 shows similar optical limitingproperties to that of 〓 in toluene for 8ns laser at wave length 532nm. Moreover, thehigh solubility of this adduct in polar solvents such as THF, acetone enables itsincorporation into sol-gel glass matrix. The thin films prepared via the sol-gel methodshow improved OL behaviour compared to those of 〓. The langmuir-Blodgett filmformation and uv-visible absorption of 〓 are also investigated. LBmonolayer of this compound is prepared on the air-water interface at 〓 mol/l. In chapter 4, three water-soluble derivatives of [60] fullerene: fullerol(1), theaddition product (2)of fullerol (1)with polyvinylpyrrolidone and fumaric acidderivative of 〓(3) are synthesized and characterized.

通过Diels-Alder环加成反应，用茚〓和1，1'-联茚〓及取代茂合成了一系列可溶性的〓环加成衍生物，发现可控制反应条件，使1，1'-联茚与〓反应，并高产率地得到具有新颖结构的单加成物，用HPLC、FTIR、FD-MS 及〓、HMQC、HMBC等多种波谱技术对其结构进行表征，测得它的两个〓杂化的桥头碳的化学位移为〓ppm，证明生成的衍生物为6∶6闭式环加成，〓NMR谱中共给出38个信号，表明〓联茚衍生物分子具有〓对称性；在波长532nm，脉冲宽度8ns的激光下，〓联茚衍生物的甲苯溶液的光限幅性能与〓的甲苯溶液相近，由于〓联茚单加成衍生物熱稳定性好，在四氢呋喃，丙酮等极性溶剂中溶解性好，能分别均匀地掺入溶胶-凝胶中，已发现它的溶胶(so1)光限幅性能优于纯〓的光限幅性能；使用Langmuir-Blodgett技术将〓联茚衍生物在空气和水的界面进行了LB单层膜和多层膜实验以及UV-Vis吸收谱研究，通过等温压缩曲线测试，证明浓度为〓〓时，〓联茚衍生物能够形成单层膜。

This kind of adglutinate mixed with U expansion admixture can grip anchor bolts tightly even underwater, as can be seen from the pull-out type tests for anchor bolts when the mortar age is over 10 days.(2) The author lays the supporting piles as a arched shape.

将掺加了U型微膨胀剂的砂将作为锚杆水下胶结物，由锚杆龄期10天的抗拔试验结果可以看出，这种胶结物的握裹效果很好。

When feeding with undecylenic acid by fed-batch culture, there was a lag time when microorganism using undecylenic acid as a new carbon source. The molar fraction of unsaturated monomer could be achieved by 37.39% at 73 hr cultivation. We can see the property of PHA become flexible with cultivation time by the lower of Tg.

发酵槽馈加十一烯酸培养实验，产物为PHO与PHU(poly-3-hydroxy-8-noneneoate为主)所形成之混掺物，且双键所占比例随时间增加，培养第73小时可得到双键比例37.39%；随培养时间增加，玻璃转移温度(Tg， glass transition temperature)由-34.03℃下降至-42.40℃，显示PHA性质变得更加柔韧具有弹性。

Methods: The content of hydroxyproline can be determined by hitachi L-8800 high speed amino acid analyzer, and the content of hydrolyzed animal proteins in adulterated milk was then calculated by HYP content.

通过日立L-8800型氨基酸分析仪测得羚脯氨酸的含量，由测得的HYP含量换算得出牛乳中掺加的动物蛋白水解物的量。

The split between the two groups can hardly be papered over.

这两个团体间的分歧难以掩饰。

This approach not only encourages a greater number of responses, but minimizes the likelihood of stale groupthink.

这种做法不仅鼓励了更多的反应，而且减少跟风的可能性。