接枝法

Maleic anhydrite was grafted onto polypropylene by melt grafting method, and the effects of the amounts of monomers and initiator on the grafting rate were discussed.

采用熔融接枝法，考察了单体和引发剂用量对聚丙烯/马来酸酐接枝物接枝率的影响。

In this paper,the synthesis of Talc/PMMA graft copolymer is studied,and the apparent kinetic test conducted by dilatometer. The effects of the initiator's concentration, the monemor's content, the talc's content and the reaction temperature on polymerization rates were investigated,and the apparent activation energy was determined.

文章主要研究了滑石粉／PMMA接枝物的合成和表观动力学测试，采用膨胀计法研究了接枝聚合反应表观动力学，探讨了引发剂浓度、单体用量、无机微粒滑石粉用量及反应温度等对反应速率的影响，并且测定了反应的表观活化能。

Caprolactam grafted carbon fibre could improve the initial crystallization temperature and the crystallization rate more obviously than ungrafted carbon fibre. The crystallization of nylon 6 was determined by nucleation. The nonisothermal crystallization dynamics was well coincident with the rule of both of Jeziorny and Liu equation. isothermal crystallization dynamics fitted to Avrami equation.

用广角X射线衍射法对晶型结构进行研究，表明碳纤维使原生态的样品中α晶型的含量降低，结晶度下降，其中接枝聚己内酰胺链段的碳纤维／MC尼龙6原位复合材料中α晶型的含量比未接枝的碳纤维／Me尼龙6原位复合材料的多，结晶度也较大：样品淬火时，碳纤维有利于基体尼龙6结晶时形成γ型晶体，接枝聚己内酰胺链段的碳纤维更有利于基体尼龙6结晶时形成γ型晶体；淬火后的样品在200℃下退火2个小时后γ晶型完全转变为α晶型。

On the basis of the former results, Miscibility of unseparated reaction solution with varied resins were investigated by means of co-solvent method and the glossiness of the film method. The miscibility of 344# acrylic resin with the mixture was better than others, when the ratio of the mixture to 344# acrylic resin was one to ten, the miscibility attained best, and the glossiness of the film was 100 percent.The effect of miscibility and molecular weight on delaminating rate were investigated by the co-solvent method.

在聚马来酸醉溶解性能、相容性测定的基础上，通过共溶剂法、溶液涂膜法和溶解度参数法，考察了反应液不分离直接和不同树脂复配的情况。344#短油度醇酸树脂和接枝物的相容性较好，在接枝物：短油度醇酸树脂=1：10时，相容性达到最好，涂膜光泽值达到100%。

The graft polymerization of acrylonitrile on Crosslinked polyvinyl alcohol microspheres CPVA microspheres was performed by using cerium ammonium sulfate as initiator, and grafted microspheres CPVA-g-PAN were prepared. Subsequently, the grafted PAN was converted into poly via amidoximation reaction with hydroxylamine hydrochloride as reagent, resulting in the functional microspheres CPVA-g-PAO. The chemical structure and physicochemistry characters were adequately characterized with infrared spectrum, scanning electron microscope and determining Zeta potential. The effects of main factors on the amidoximation transform reaction of the grafted PAN were researched with emphasis, and the adsorption property of the functional microspheres CPVA-g-PAO for some biomolecules was examined preliminarily with uric acid as a model biomolecule.

以硫酸铈铵为引发剂，实施了丙烯腈在交联聚乙烯醇微球表面的接枝聚合，制备了接枝微球CPVA-g-PAN，然后以盐酸羟胺为试剂，通过偕胺肟化转变，将接枝的PAN转变为聚偕胺肟，制得了接枝有聚偕胺肟的功能微球CPVA-g-PAO，采用红外光谱法、扫描电子显微镜及Zeta电位测定等法，对功能微球CPVA-g-PAO的化学结构及物理化学特性进行了表征，重点考察了各主要因素对接枝PAN的偕胺肟化转变反应的影响，也以脲酸为模型分子，初探了功能微球CPVA-g-PAO对生物分子的吸附性能。

The effect of initiator content on the viscosity and conversion rate of PUA was studied as key point.

通过接枝法制备了丙烯酸改性聚氨酯乳液，重点研究引发剂用量对PUA黏度和转化率的影响。

Graft copolymerization of acrylic acid and acrylic amide onto chlorinated polyethylene by the oil-swellable suspension graft copolymerization technique was studied, benzoyl peroxide was used as the free radical initiator and ethyl acetate as the sweller.

采用溶胀悬浮接枝共聚法，将水溶性单体丙烯酸、丙烯酰胺接枝到疏水性氯化聚乙烯大分子链上，合成双亲性接枝共聚物。

In this paper,NBR was modified by fluorinating with XeF2 and the reaction kinetics of fluorination was studied by FT-IR spectrometry.The apparent reaction order of 1.5 was suggested,which seemed to become less for long reaction time.

目前报道的高分子表面氟化改性的方法很多，主要的方式有：辐射接枝法、等离子体活化法[1，2]、静电喷涂法、离子注入法及氟化剂表面化学反应法[3—7]等。

The featuresof this method are obtained, i.e. the degradation of PP is not avoided, MAHcan be reacted inside the PP particles by diffusion, grafted polymer has higherpyrolytic degradation temperature than pure PP, the sizes of crystallite ingrafted polymer are smaller than those of pure PP.

在接枝聚合中，选用低能耗、低环境污染的固相法制备PP-g-MAH，探讨了固相法的特点：PP降解不可避免；MAH能渗透进PP粒子进行反应；得到的接枝物具有较高的耐热温度；接枝物的微晶尺寸比纯PP的小。

The structure and graft rate of the graft polymer were determined by means of IR spectra and acid-base titrations, the effect of content of POE, MAH, DCP and reaction temperature on graft rate were studied in detail.

通过红外光谱确定了接枝物的结构，采用酸碱滴定法测定了产物的接枝率，详细研究了POE、MAH、DCP用量及反应温度等对接枝率的影响规律。

I didn't watch TV last night, because it .

昨晚我没有看电视，因为电视机坏了。

Since this year, in a lot of villages of Beijing, TV of elevator liquid crystal was removed.

今年以来，在北京的很多小区里，电梯液晶电视被撤了下来。