成双的

Meanwhile, the isomer with a larger change of dipole moment has larger value of the first hyperpolarizability during the charge-transfer process.

5， 6， 7顶点双取代碳硼烷桥连分子受推拉电子基的影响，5， 6， 7顶点碳硼烷的构型发生一定变化，碳硼烷中两个C原子间的距离变长；同时碳硼烷中两个C原子取代位置的不同，影响了分子的稳定性和极化率，取代基团与碳硼烷中成键数较低的C原子相连的异构体，稳定性较好且具有大的极化率； 5，6，7顶点双取代碳硼烷桥连分子形成一维结构有利于分子内电荷转移，在电荷转移过程中偶极矩变化较大的体系，其二阶NLO系数也较大。

Mn-complexes in which Mn atom ligand with the N atom within ligand can stimulate the recovery of electron transfer and oxygen evolution. The trinuclear Mn-complex is extremely sensitive to the addition of CaCl2. It is suggested that there is an interaction between Ca2 and carboxyl within the trinuclear Mn-complex during photoactivation and this interaction benefits the ligation of Mn atom to the apo-WOC and form an active WOC. Binuclear MnMn complex shows slightly higher efficiency than binuclear MnMn complex in restoration of O2 evolution activity. It is suggested from our results that recovery of electron transport and O2 evolution with synthetic Mn-complexes is affected by different factors. Cl- can stimulate the reconstitution of WOC at the concentration of over 100mM;the maximal recovery of O2 evolution activity requires the presence of CaCl2 and 33 kDa protein polypeptide together. Bicarbonate can stimulate the reconstitution of WOC.

锰配合物中锰原子与配体中的氮原子配位连接时，能显著恢复电子传递活性和放氧活性；三核锰化合物在重组时对CaCl2的存在非常敏感，我们认为Ca2 与三核锰化合物中的羧基之间存在一定的相互作用，而这种作用有助于锰原子的光配位进而使三核锰化合物易于组装成有活性的水氧化复合物：双核锰化合物MnMn比双核锰化合物MnMn在恢复放氧活性方面更有效；影响锰化合物电子传递能力恢复的因素与影响锰化合物放氧活性恢复的因素不同；在锰蔟重组过程中，氯离子的浓度必须在100mM以上，才能有效进行光重组；最大光重组效率的获得必须有钙离子和33kDa多肽同时存在；碳酸氢根离子促进锰化合物与去锰光系统II的光组装。

The variation of pH and conductivity of various phosphate solution with the solution temperature were obtained based on the physical chemistry theory and ionization equilibrium theory in electrolytic solutions, and be testified experimentally under radiation of ultrasonic wave. The pH was a linear function with the reciprocal of thermodynamic temperature, and the conductivity was a linear function with the temperature in phosphate solution.

三、超声波对双水相系统组成物质、两相组成及溶质分配影响的研究根据物理化学原理和电解质溶液电离平衡理论分析推导和实验验证，揭示了超声波作用下不同组成磷酸盐溶液的pH值和电导率随溶液主体温度变化的规律：磷酸盐溶液的pH值与溶液主体绝对温度的倒数成线性关系，磷酸盐溶液的电导率与溶液主体温度成线性关系。

In the process of laboratory study, oxycodone was prepared by oxidating thebaine at 6,14-position under oxydol, hydrodeoxidizing 7,8-position double bond and 14-position ether under palladium catalyst. Furthermore, N-methyl of oxycodone was isolated byα-chloro-ethyl chloroformate under anhydrous condition and protection of 14-position hydroxyl to obtain noroxycodone, which was further converted into methylnaltrexone by N-alkylation in presence of cyclopropyl bromomethane, then by isolating 3-position methyl of methylnaltrexone under boron tribromide, becoming hydrochloride to prepare target compound, natrexone hydrochloride.

实验室工艺方面，本文首先用双氧水氧化蒂巴因的6-位和14-位、在钯炭催化下加氢还原7-8位双键和14-位醚合成羟考酮，然后提出并优化了在无水和14-位保护的情况下，用氯甲酸-α-氯乙酯脱去羟考酮的N-位甲基合成去甲羟考酮，再用环丙甲基溴将去甲羟考酮的N-位烷基化合成甲基纳曲酮，最后采用三溴化硼脱去甲基纳曲酮的3-位甲基和成盐酸盐合成盐酸纳曲酮。

Synthesis and liquid crystalline behavior of three recently reported mesogenic block-molecules,namely polyhydroxy 1-benzoylaminopropane-2,3-diols Ⅰ,star-shaped pentaerythritol tetrabenzoates Ⅱ and calamitic bolaamphiphiles with lateral chains Ⅲ which are constituted of anisometric block,amphiphilic block and alkyl or perfluorinated chains with different topologies are reviewed in this article.

这些分子由各向异性嵌段、两亲性嵌段和烷基链以不同的拓扑形式组合而成，其合成的关键步骤是Pd(0)催化下碘代全氟烷烃对双键的自由基加成反应以及Pd(0)催化的偶合反应。

Olefine, electrophilic or nucleophilic substitution of arenes, nucleophilic addition of carbonyl compounds stereochemistry in elimination reaction of double bond forming and the choosing of oxidants and reducing agents in redox system.

在化学反应方面重点是烯烃的亲电加成，芳香烃的亲电，亲核取代，羰基化合物的亲核加成，消除反应的双键定位和立体化学，氧化，还原反应中氧化还原剂的选择。

1 Heptane, it was revealed that the Cr〓/ Catsan and ZnCl〓 could catalyze the Michael addition of pyrrole with conjugate olefine at α-position of pyrrole to get mono- or bi-Michael addition product selectively under mild condition in good yield. Totally, forty-six new compounds, including thirty target compounds, were prepared.

在探索7-氮杂桥环母体的构建方法过程中，发现了Cr〓／Clay和ZnCl〓可有效地催化吡咯的α-位与多种共轭烯烃发生Michael加成反应，可在温和的条件下，以良好的收率选择性地得到单或双Michael加成产物。

But the grain growth, grain semiconduction and grain boundary insulation were influenced by many factors, such as the type and contents of dopants, sintering temperature and so on. Therefore, in this thesis the effect of the restore sintering temperature, the oxygenize temperature, the donor and acceptor dopant on the dielectric and varistor properties of devices were studied. With SEM, the microstructure of SrTiO3-based double function ceramic was analyzed.

而晶粒生长、晶粒半导化和晶界绝缘化受到多种因素的影响，诸如杂质的种类和含量、烧成温度等，因此本论文研究了还原烧成温度、中温氧化温度、施主和受主掺杂等对SrTiO_3基陶瓷的压敏和介电性能的影响，并借助于SEM分析对SrTiO_3基双功能陶瓷的微观结构进行了分析。

The DNG structure unit is composed of square split ring resonator and strip wire. The modified NRW method is used to extract the equivalent permittivity, permeability, and refractive index from the scattering parameters of the two-port waveguide with DNG structure. At the designed operating frequency, the refractive index approximates zero, which makes the nondirective electromagnetic wave tend to approximate plane wave along the normal direction of the superstrate and congregate the radiation energy.

以方形的SRR环和金属条带构成双负媒质结构单元，使用修正的NRW方法，通过放置双负媒质结构的二端口波导的散射参数，提取了等效的介电常数、磁导率和折射率，在所设计的工作频率，折射率接近于0，可以将原本发散的电磁波整理成趋近于覆层面法线方向的近似平面波，起到能量汇聚的功能。

The DNG structure unit is composed of square split ring resonator and strip wire. The modified NRW method is used to extract the equivalent permittivity, permeability, and refractive index from the scattering parameters of the two-port waveguide with DNG structure. At the designed operating frequency, the refractive index approximates zero, which makes the nondirective electromagnetic wave tend to approximate plane wave along the normal direction of the superstrate and congregate the radiation energy.

以方形的SRR环和金属条带构成双负媒质结构单元，使用修正的NRW方法，通过放置双负媒质结构的二端口波导的散射参数，提取了等效的介电常数、磁导率和折射率，在所设计的工作加热板频率，折射率接近于0，可以将原本发散的电磁波整理成趋近于覆层面法线方向的近似平面波，起到能量汇聚的功能。

She gently rebuff ed him, but agreed that they could be friends

她婉言拒绝了，但同意作为朋友相处。

If in the penal farm, you were sure to be criticized.

要是在劳改农场，你等着挨绳子吧！