戊醚

This paper studied the synthesis and models about the etherification reaction from isoamylene to the tert-amyl methyl ether synthesis.

分析了异戊烯醚化生成甲基叔戊基醚的反应机理及相关的反应动力学模型，以甲醇和乙烯裂解碳五为原料进行醚化反应，分别求得R-E模型、L-H模型的动力学参数。

Rats were anesthetizedwith pentobarbital and then randomized into four groups: control,ISO-control (pretreatment with 30 min of 1.4% ISO), lipopolysaccharide(LPS; 10 mg/kg IV), and ISO-LPS.The mesentery was prepared for intravital videomicroscopy.

大鼠戊巴比妥麻醉后随机分为四组：对照组、异氟醚组（吸入1.4%的异氟醚30分钟）、脂多糖组（ LPS ；10mg/kg IV ）、 ISO-LPS 组（先吸入异氟醚后使用 LPS ）。

Result and Conclusion The optimal concentration of 2 nonyl 1,3 dioxolane for higher percutaneous absorption of diclofenac gel was 2.0%,suggesting that 2 nonyl 1,3 dioxolane is a potent penetration enhancer.

结果 壬代环戊双醚含量在2.0％时透皮吸收最好。结论壬代环戊双醚具有较好的促渗作用，是较好的新型促渗剂。

Mission:"equality and mutual benefit, reputation first, unity and cooperation and friendship between the long-term" supply products: ethylenediamine; diethylamide; triethylamine; Diethylenetriamine; three ethylene diamine; three ethylene amines 40; 40 Five ethylene amines; five ethylene amines 6; caprolactam; DMF; allyl amine; N, N dimethylaniline; propylamine; are butylamine; are TOA; 3 Poly Cyanamide; 1,2 c diamine; ethanolamine; diethanolamine, triethanolamine; potassium iodide, potassium hydroxide, potassium permanganate, toluene, xylene, toluene of chlorine ; Acetone, butanone; acetylacetone; ethyl acetate, butyl acetate; Y-butyrolactone; DMC; acetyl of methyl acetate; Sanfu acetyl acid; Sanfu acetyl B Ethyl; methanol, ethanol, isopropanol; propylene glycol; glycerol; propargyl alcohol; 1.3 propylene glycol; xylitol; acetic acid; have acid; mercaptoacetic acid; vary Bitterness; adipic acid; trifluoroacetic acid; oxalic acid, the amino acid; o-amygdalin acid; DL-Acid; anhydrous piperazine; six non-piperazine, furfural, castor oil, ethylene Aldehyde; glutaraldehyde, multi-POM; isopropyl ether; anisole; tetrahydropyrrole; pure pyridine; 1.2 dichloroethane; methylene chloride, chloroform, carbon tetrachloride; hydrazine hydrate; Nonylphenol;-m-cresol; Se phenol; phenol; the tert-butyl phenol; Titanium Dioxide; iron; full Tangfen; Bisphenol A; azo two different nitrile; sodium azide; sodium carbonate ; Sodium chloride; iron oxide; cuprous chloride; thionyl chloride; D4; sodium bicarbonate; ammonia, potassium chloride; anhydrous sodium sulphite; ammonium persulfate; glycol Dingmi; B Glycol ether; calcium chloride; cyclohexanone; cyclohexane, methyl tertiary butyl ether, potassium carbonate, ferric chloride, potassium nitrate; Linsuansanna; zinc oxide; sodium nitrite; antimony oxide; Tartrate; OP-10; TX-10; tablets base; AES; sodium benzoate, sodium citrate; partial sodium silicate, sodium perborate, a sodium carbonate, sodium benzene; Asia sodium chlorate; Wuluo Care products; urea; hydrochloric acid, sulfuric acid, lactic acid; amino acid, hydrogen peroxide, ammonium bicarbonate

公司宗旨："平等互利，信誉至上，团结合作，友谊长久"乙二胺；二乙胺；三乙胺；二乙烯三胺；三乙烯二胺；三乙烯四胺；四乙烯五胺；五乙烯六胺；己内酰胺；二甲基甲酰胺；烯丙基胺；N，N二甲基苯胺；正丙胺；正丁胺；正辛胺；三聚氰胺；1，2丙二胺；一乙醇胺；二乙醇胺；三乙醇胺；碘化钾；氢氧化钾；高锰酸钾；甲苯；二甲苯；对氯甲苯；丙酮；丁酮；乙酰丙酮；醋酸乙酯；醋酸丁酯；Y-丁内酯；碳酸二甲酯；乙酰乙酸甲酯；三伏乙酰乙酸；三伏乙酰乙酸乙酯；甲醇；无水乙醇；异丙醇；丙二醇；丙三醇；丙炔醇；1.3丙二醇；木糖醇；冰醋酸；己醛酸；巯基乙酸；异辛酸；己二酸；三氟乙酸；乙二酸；对氨基苯乙酸；邻氯苦杏仁酸；DL-扁桃酸；无水哌嗪；六无哌嗪；糠醛；蓖麻油；乙二醛；戊二醛；多聚甲醛；异丙醚；苯甲醚；四氢吡咯；纯吡啶；1.2二氯乙烷；二氯甲烷；三氯甲烷；四氯化碳；水合肼；壬基酚；纯间甲酚；硒酚；苯酚；对叔丁基苯酚；钛白粉；铁粉；全糖粉；双酚A；偶氮二异丁腈；叠氮化钠；碳酸钠；氯化钠；三氧化二铁；氯化亚铜；氯化亚砜；D4；碳酸氢钠；氨水；氯化钾；无水亚硫酸钠；过硫酸铵；乙二醇丁醚；乙二醇乙醚；氯化钙；环己酮；环己烷；甲基叔丁基醚；碳酸钾；三氯化铁；硝酸钾；磷酸三钠；氧化锌；亚硝酸钠；氧化锑；酒石酸；OP-10；TX-10；粒碱；AES；苯甲酸钠；柠檬酸钠；偏硅酸钠；过硼酸钠；过碳酸钠；苯磺酸钠；亚氯酸钠；乌洛托品；尿素；盐酸；硫酸；乳酸；氨基磺酸；双氧水；碳酸氢铵

In this paper, a series of 4,5-dithiacrown ether annulated 1,3-dithiole-2-thiones 8a~8d were prepared via condensing 4,5-bis-1,3-dithiole-2-thione (7) with 1,ω-dimercapto polyglycol derivatives in high dilution. The obvious template effect was found during the synthesis of 8c-8d.

在高度稀释条件下，经4，5-二溴甲基-1，3-二硫杂环戊烯-2-硫酮(7)和多缩乙二醇的1，ω-二巯基衍生物的缩合反应，方便地合成了4，5-位带二硫杂冠醚残基的2-硫代-1，3-二硫杂环戊烯的衍生物8a~8d，中间体硫杂冠醚8c~8d的合成中有明显的&模板效应&。

In this paper, a series of 4,5-dithiacrown ether annulated 1,3-dithiole-2-thiones 8a~8d were prepared via condensing 4,5-bis-1,3-dithiole-2-thione (7) with 1,ω-dimercapto polyglycol derivatives in high dilution. The obvious template effect was found during the synthesis of 8c-8d.

在高度稀释条件下，经4，5-二溴甲基-1，3-二硫杂环戊烯-2-硫酮(7)和多缩乙二醇的1，ω-二巰基衍生物的缩合反应，方便地合成了4，5-位带二硫杂冠醚残基的2-硫代-1，3-二硫杂环戊烯的衍生物8a~8d，中间体硫杂冠醚8c~8d的合成中有明显的&模板效应&。

The chapter two was focused on the samarium diiodide promoted organic reactions and their applications in organic synthesis, firstly, a new synthesis of highly substituted cyclopentadienes from a,β-alkynone promoted by samarium diiodide was investigated and the highly substituted cyclopentadienes were prepared in moderate to good yields under mild conditions. Secondly, the Michael addition and Michael-aldol tandem reaction of diorganyl diselenides or diorganyl disulfides with α,β-alkynones mediated by samarium diiodide were studied and a series of alkenylsulfides and alkenylselenides were prepared in good yields. Then the highly regioselecfive nucleophilic addition of the allylsamarium bromide to α,β-alkynones were explored. We found that the allylsamarium bromide reacts with α,β-alkynones to afford regiospecificly 1. 2-nucleophilic addition products in good yields under mild condition. At last we studied the coupling reaction of aryl halides promoted by NiCl〓/PPh〓/Sm〓.

第二章 研究了二碘化钐、金属钐促进的有机反应：1、二碘化钐促进下α，β-炔基酮的偶联环化反应，提供了一种制备多取代环戊二烯的新方法；2、二碘化钐促进下的二硫醚、二硒醚与α，β-炔基酮的Michael加成反应，为高产率地制备多取代的烯基硫或烯基硒化合物提供了方便可靠的新方法；3、二碘化钐促进下的二硫醚、二硒醚与α，β-炔基酮和醛、酮的Michael—aldol串联反应，提供了一种一锅法高产率地制备多取代的含硫的烯丙基醇或含硒的烯丙基醇类化合物的方便可靠的原子经济性的新方法；4、烯丙基溴化钐与α，β-炔基酮的高度区域选择性的1，2-亲核加成反应；5、NiCl〓/PPh〓/Sm〓促进的卤代芳烃的偶联反应-一种从各种卤代芳烃制备联苯类化合物的有效方法。

Professional sales companies operating bromide products: sodium bromide, sodium bromide, potassium bromide, potassium bromate, Tetrabromobisphenol A, Deca-BDE, ten PBDEs, DBDPE, hexabromodiphenyl Central dodecane, dibromo neopentyl glycol, neopentyl bromide three alcohols, three bromine phenol, octabromodiphenyl ether, brominated polystyrene, bromide, calcium bromide, dibromo succinic acid, dibromo-D ene glycol, bromide surfactants series: Dodecyl trimethyl ammonium bromide, tetradecyl trimethyl ammonium bromide, cetyltrimethyl ammonium bromide, octadecyl trimethyl ammonium bromide dodecyl trimethyl ammonium chloride, tetradecyl trimethyl ammonium chloride, cetyl trimethyl ammonium chloride, octadecyl trimethyl ammonium chloride, tetrabutyl ammonium bromide wholesale sales: dimethylolpropionic acid, DL-malic acid, isophthalic acid PIA, glycolic acid, adipic acid.

公司专业经营销售溴化物系列产品：溴化钠、溴酸钠、溴化钾、溴酸钾、四溴双酚A、十溴二苯醚、十溴联苯醚、十溴二苯乙烷、六溴环十二烷、二溴新戊二醇、三溴新戊醇、三溴苯酚、八溴醚、溴化聚苯乙烯、溴化铵、溴化钙、二溴丁二酸、二溴丁烯二醇、溴化表面活性剂系列：十二烷基三甲基溴化铵、十四烷基三甲基溴化铵、十六烷基三甲基溴化铵、十八烷基三甲基溴化铵、十二烷基三甲基氯化铵、十四烷基三甲基氯化铵、十六烷基三甲基氯化铵、十八烷基三甲基氯化铵、四丁基溴化铵批发销售：二羟甲基丙酸、DL-苹果酸、间苯二甲酸 PIA、羟基乙酸、己二酸。

The contact angle of glassfiber epoxy resin fluoridized by 3-(1H, 1H, 5H-Octafluoropentyloxy)-1, 2-Propenoxide hasincreased from 51.3°to 75.3°, and the surface tension has reduced from 36.5mN/m to25.5mN/m accordingly.

同时经过环氧丙基八氟戊醚处理的环氧玻璃钢表面对水的接触角也由原来的51.3°增大到75.3°，其表面张力由36.5mN／m减小到25.5mN／m，达到一定的疏水疏油效果。

It is found that compared with the untreated glass fiber reinforced unsaturated polyester, the fluoridized FRP"s property of anti-water and anti infirm-acid has enhanced, while theproperty of anti- strong acid, anti-strong alkali and anti-organic solvent hasn"t changed much.The property of anti-acid and anti-alkali of the glass fiber reinforced epoxy resin fluoridizedby 3-(1H, 1H, 5H-Octafluoropentyloxy)-1, 2-Propenoxide has a corresponding increase, but theproperty of anti-organic solvent hasnt changed much.

研究发现，经G-02、G-04处理后的聚酯玻璃钢的与未处理的聚酯玻璃钢相比，其耐水性增强，耐弱酸性也有所增强，但耐强酸性、耐碱性、耐有机溶剂的腐蚀性变化不大；而经环氧丙基八氟戊醚处理后的环氧玻璃钢其耐酸耐碱性都有相应的增强，但是其耐有机溶剂的腐蚀性无太大变化。

Finally, according to market conditions and market products this article paper analyzes the trends in the development of camera technology, and designs a color night vision camera.

最后根据市场情况和市面上产品的情况分析了摄像机技术的发展趋势，并设计了一款彩色夜视摄像机。

Only person height weeds and the fierce looks stone idles were there.

只有半人深的荒草和龇牙咧嘴的神像。