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戊醇

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A process for the carbonylation of allylic butenyl ether (for example, methyl crotyl ether, 3-methoxybutene-1 and mixtures thereof) or mixture of butadiene and alcohol and production of beta-gamma unsaturated carboxylic acid esters (for example, methyl-3-pentenoate) utilizing a rhodium-containing catalyst for example, dicarbonylacetylacetonate rhodium(I or the like promoted with an iodide-containing compound (for example, HI, AlI3, SnI4, TiI4, CrI3, and CoI2 or the like).

一种将烯丙型丁烯基醚(如甲基巴豆基醚、3-甲氧基丁烯-1及其混合物)或者丁二烯与醇的混合物羰基化的方法,以及由含碘化物化合物(如HI、AlI3、SnI4、TiI4、CrI3和CoI2或等效物)促进,用含铑催化剂如二羰基乙酰丙酮酸铑(I或其等效物制备β-γ不饱和羧酸酯(如甲基-3-戊烯酸酯)的方法。

The main products are formic acid, propionic acid, methyl acetate, morpholine, imidazole, methyl chloroformate, 1,2-pentanediol, nylon and engineering plastic.

代理BASF和HONEYWELL优质产品散水化工品:甲酸,丙酸,醋酸甲酯中间体:吗啉,咪唑,氯甲酸甲酯,1,2-戊二醇,尼龙和工程塑料。

Methods:GroupⅠ:fresh bovine pericardium was acellularized with Courtman's method and fixed with glutaraldehyde;GroupⅡ:first treated as GroupⅠ,then was modified with2,3-butanediol.

方法Ⅰ组新鲜牛心包片经Courtuman法脱细胞后用戊二醛(GA固定;Ⅱ组脱细胞及固定方法同Ⅰ组,随后用2,3丁二醇改性。

The emphasis was on chemical properties,application,main production methods,market,and prospects of main deriva- tives of acetaldehyde such as ethyl acetate,pentaerythritol,glyoxal,peracetic acid, crotonaldehyde and pyridine.

介绍了国内外乙醛及其主要衍生物的生产技术发展及其市场供需状况,尤其对乙醛主要衍生物乙酸乙酯、季戊四醇、乙二醛、乙醛酸、丁烯醛、吡啶的化学性质与用途、主要生产方法、市场供需状况及开发前景作详细介绍和分析。

The main compositions of LPs include shorter chain carboxylic acid derivatives, furan derivatives, cyclopentanone, phenol derivatives, benzene derivatives, cinnamic acid derivatives, longer chain carboxylic esters and sterides.

秸秆在亚/超临界醇中液化产生的LPs的主要组成成分包括短链脂肪酸衍生物、呋喃衍生物、环戊酮衍生物、含有取代基的肉桂酸衍生物、芳醛或酮衍生物、苯酚衍生物、苯衍生物,长链脂肪酸衍生物和甾族化合物。

Firstly, dicyclopentyldichlorosilane, a reaction intermediate, was prepared under the optimal conditions of a reaction pressure range of 1.0-1.2 MPa, a n/n of 1.16, a reaction temperature range of 85-95℃, a catalyst dosage of 1.2 g, an isooctyl alcohol dosage of 2.3 g and a reaction time range of 6-7 h. The conversion of cyclopentene and the yield of DCPDCS were 96.2% and 88.9%, respectively.

首先研究了合成DCPDCS的最佳工艺条件:反应压力1.0~1.2 MPa,n/n= 1.16/1.00,反应温度85~95 C,催化剂用量1.2 g,异辛醇用量2.3 g,反应时间6~7 h,环戊烯转化率可达96%以上,DCPDCS收率可达88%以上。

Experimental results have shown that if pentaerythritol or starch are used as coking reagent,and if the proportion of deaquation catalyst to coking reagent to bubbling reagent is 5∶1 5∶3 5 and the ratio of blending stock to basic paint material is 7∶3,the fire retardant paints will relatively achieve its best fire resistant properties.

实验发现,采用季戊四醇、淀粉作为成炭剂,脱水成炭催化剂∶成炭剂∶发泡剂= 5∶1.5∶3.5、填料∶漆基料重= 7∶3时,涂料的防火性能较佳。

In a similar way, using N,N\'-dibenzyl tartamide as auxiliary,-(2-methyl)allyl-2-chloro-phenyl-methyl azide, a vital intermediate of Repaglinide, can be prepared via asymmetric allylation of o-chlorobenzaldehyde in

产物经氧化和碘加成内酯化反应得到阿伐他汀中间体(3R,5S)-3-羟基-5-碘甲基戊内酯(10);将N-苄基酒石酸二酰胺用于邻氯苯甲醛的不对称烯丙基化反应以较高光学收率得-甲基烯丙基-2-氯苯基-甲基醇

According to thermal characteristics of single component, dilative action was analyzed for mixture from the viewpoint of thermal effect.

通过对典型膨胀体系(即聚磷酸铵、三聚氰胺、季戊四醇)中单一活性物质及其混合物的DSC分析,探讨了不同组分之间热效应的叠加现象和相互作用,从热效应角度分析了膨胀反应,初步探索了复杂膨胀现象中物理化学变化的热特征。

Ni-P-mCMC/mCS bipolar membrane was prepared from carboxymethyl cellulose modified with phosphorylated agent as a cation exchange layer and chitosan modified with glutaraldehyde as an anion exchange layer. The electrolysis cell was constituted by Ni-P-mCMC/mCS BPM as a septum for electrogenerating furfural alcohol and furoic acid.

以磷酸化试剂改性羧甲基纤维素钠制备了阳膜层,以戊二醛改性壳聚糖制备了阴膜层溶胶,将阴膜层溶胶流延于阳膜层上,制备了P-mCMC/mCS双极膜,而后以化学镀方法在阳膜层表面镀镍,制备了Ni-P-mCMC/mCS双极膜,并应用于成对电合成糠醇、糠酸。

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