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The effects of DCPD and adipic acid content on product properties are investigated and the properties of DCPD-type-UPR and 191# UPR are cont rasted.

考察了双环戊二烯、己二酸加入量对双环戊二烯型不饱和聚酯树脂性能的影响,并与通用191#树脂的性能进行了比较。

To improve water solubility of betulin, two acyl groups were introduced at C-3 and C-28 hydroxy groups of betulin. 3, 28-di-O-glutaryl-betulin was synthesized with pyridine as solvent and DMAP as catalyst from betulin and glutaryl anhydride.

为了增强桦木醇的亲水性,对桦木醇的C-3位、C-28位羟基进行修饰,在吡啶作溶剂、二甲基氨基吡啶作催化剂的条件下,与戊二酸酐反应合成桦木醇戊二酸酯。

Meanwhile, the optimum operation conditions obtained by orthogonal experiment are as follows: microwave power is 585 W, irradiation time is 30min, the amounts of catalyst is 1.5% of feed stock, mole ratio of alcohol to acid is 1.5:1, the yield of isoamyl chloroacetate is 93.2% Comparing with conventional heating method, the heating time under microwave irradiation is less than 1/14 of the former.

最佳工艺条件为:微波功率585W,加热时间为25min,催化剂用量为2.0%,醇酸比为1.5:1,此条件下氯乙酸异戊酯的产率为93.2%。对比实验结果表明,微波辐射加热法合成氯乙酸异戊酯的反应速度至少是常规加热法的14倍。

It could be synthesized by a key intermediate 2-pentylidene cyclopentanone formed a condensation starting from cyclopentanone and n-valeraldehyde, followed by isomerization, Michael addition and a selective decarboxylation.

本文研究了以正戊醛和环戊酮为基本原料,经缩合反应、异构化反应、Michael加成反应和脱羧反应等制备二氢茉莉酮酸甲酯的化学合成方法和工艺。

The present invention belongs to the field of chemical technology, and is a kind of supported tungstic acid catalyst for multiphase catalytic oxidation and synthesis of glutar aldehyde from cyclopentene.

本发明属于化工技术领域,是一种新型的环戊烯多相催化氧化合成戊二醛的负载型钨酸催化剂。

Under the optimum conditions of a cyclopentene amount of 1.0 mol, a molar ratio of cyclopentene to water of 0.25, a reaction temperature of 120 ℃, a reaction time of 4.0 h, a main catalyst dosage of 4.0 g and a cocatalyst dosage of 0.8 g, the yield of cyclopentanol reached 68.6%.

确定适宜的反应条件为:环戊烯1.0 mol,n﹕n=1﹕4,反应温度120 ℃,反应时间4.0 h,硅胶负载铌酸主催化剂用量4.0 g,三(3,6-二氧杂庚基)胺助催化剂0.8 g。在此反应条件下,环戊醇收率68.6%。

Cyclopentanol was synthesized from cyclopentene and water through hydration reaction using HNb3O8·H2O/SiO2 as main catalyst and tris(dioxa-3,6-heptyl)amine (TDA-1) as cocatalyst.

在以硅胶负载铌酸为主催化剂、三(3,6-二氧杂庚基)胺为助催化剂的作用下,以环戊烯和水为原料,通过水合加成反应合成了环戊醇。

A spectrophotometric simultaneous determination of glutaraldehyde and ethanal based on the reaction between gluaradehyde or ethanal and thiobarbituric acid in acetic acid solution is described.

在醋酸介质中,硫代巴比妥酸与戊二醛及乙醛分别可生成2∶1及1∶1的缩合产物,这两种缩合产物在可见光区具有不同波长的最大吸收,籍此可同时测定戊二醛及乙醛。

The optimum reaction conditions of the synthesis of isoamyl acetate with Nafion NR50 resin membrane as catalyst were studied.

以全氟磺酸树脂膜为催化剂得到冰乙酸和异戊醇反应合成乙酸异戊酣适宜的反应条件。

Isoamyl acetate was synthesized with acetic acid and isopentyl alcohol by using Ca(p-CH3C6H4SO3) 2 as catalyst.

以乙酸和异戊醇为原料、对甲苯磺酸钙为酯化催化剂合成乙酸异戊酯,研究影响酯化率的因素。

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