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A series of polyurethane anionomers were synthesized from isophorone diisocyanate, polyneopentanediol adipate and dimethanol propionic acid.

用异佛尔酮二异氰酸酯、聚己二酸新戊二醇酯和二羟甲基丙酸合成了负离子型聚氨酯离聚体。

Three alicyclic dianhydrides, 1,2,3,4-cyclobutanetetracarboxylic dianhydride, 1,2,4,5-cyclopentanetetracarboxylic dianhydride, and 1,2, 4, 5-cydohexane tetracarboxylic dianhydride were polymerized with two aromatic diamines, 1,4-bis (4-amino-2-trifluoromethylphenoxy) benzene (6FAPB, a) and 4, 4'-bis(4-amino-2-trifluoromethyl phenoxy) biphenyl (6FBAB, b) respectively, via a two-step polycondensation procedure to afford two series of fluorinated semi-alicyclic polyimides.

分别将脂环族二酐单体1,2,3,4-环丁烷四酸二酐、1,2,4,5-环戊烷四酸二酐和1,2,4,5-环己烷四酸二酐与芳香族含氟二胺1,4-双(4-胺基-2-三氟甲基苯氧基)苯(6FAPB, a)和4,4'-双(4-胺基-2-三氟甲基苯氧基)联苯(6FBAB, b)反应制备两个系列的含氟半脂环族聚酰亚胺,研究了PI薄膜的热性能和光学性能。

Result s:10 μmol/L retinoids could inhibit the Bel-7402 proliferation and decrease the colony forming of liver cancer cells on soft agar significantly.So some biochemical markers indicating the proliferation status of liver cancer cells changed significant ly, including the significant activity increase of ornithine carbamyl transferase, tyrosine-α-ketoglutaric transaminase and alkaline phosphatase, the significant decrease α-fetoprotein secretion,γ-glutamyltranspetidase and aldolase activity.

结果:10μmol/L维甲酸显著抑制肝癌细胞增殖,并使肝癌细胞软琼脂集落形成率明显减少,使代表肝细胞分化的酶鸟氨酸氨基甲酰转移酶、酪氨酸-α-酮戊二酸转氨酶和碱性磷酸酶比活力明显升高,甲胎蛋白分泌量、γ-谷氨酰转肽酶和醛缩酶比活力明显下降。

Methods: The effects of the ratio of reactants, the amount of the catalyst used, the reaction time and the amount of an water-taking agent on synthesizing isoamyl cinnamate were investigated to obtain a suitable condition for synthesizing the ester.

考察了醇酸比、反应时间、带水剂用量等因素对合成肉桂酸异戊酯的影响,得到合成该酯的较适宜条件。结果:最佳反应条件为n:n=5:1,催化剂用量为肉桂酸用量的20%,反应时间2h,反应温度110~118℃,酯收率可达76.6%。

Furthermore, the important fragment which is composed of pentenyl cinnamic acid and D-Tyrosine, and the ester which is composed of L-N-methylated phenyl amino acid and diketopiprazine was synthesized with considerable yield The conjugation of the new DOPA analogue into the peptide in the total synthesis of Pepticinnamin E was investigatited

另外,本文作者还进一步合成了高收率的戊烯基肉桂酸衍生物与D-酪氨酸的缩合片段及L-N-甲基苯丙氨酸与哌嗪二酮的酯两个重要的结构组成部分;对新多巴衍生物片段嵌入肽链中的工作亦进行了有益的尝试。

Another aldonic acid, gluconic acid, is an intermediate in the pentose phosphate pathway.

抗坏血酸或维他命C是植物组织中普遍存在的重要醛酸,柑橘类植物果实中含量尤为丰富;另一个重要的醛酸,葡萄糖酸是戊糖磷酸途径的中间产物。

A process for the carbonylation of allylic butenyl ether (for example, methyl crotyl ether, 3-methoxybutene-1 and mixtures thereof) or mixture of butadiene and alcohol and production of beta-gamma unsaturated carboxylic acid esters (for example, methyl-3-pentenoate) utilizing a rhodium-containing catalyst for example, dicarbonylacetylacetonate rhodium(I or the like promoted with an iodide-containing compound (for example, HI, AlI3, SnI4, TiI4, CrI3, and CoI2 or the like).

一种将烯丙型丁烯基醚(如甲基巴豆基醚、3-甲氧基丁烯-1及其混合物)或者丁二烯与醇的混合物羰基化的方法,以及由含碘化物化合物(如HI、AlI3、SnI4、TiI4、CrI3和CoI2或等效物)促进,用含铑催化剂如二羰基乙酰丙酮酸铑(I或其等效物制备β-γ不饱和羧酸酯(如甲基-3-戊烯酸酯)的方法。

Ketoglutaric acid A five-carbon dicarboxylic acid that is an intermediate in the KREBS CYCLE.

酮戊二酸:一种五碳二羧酸,为三羧酸循环的中间产物。

The protic- or Lewis acid catalyzed ring-closure of divinyl ketones (and their acid-labile precursors) pentadienylic cations is known as the via Nazarov cyclization.

质子酸或路易斯酸通过戊二烯基阳离子催化二乙烯酮的环闭合(以及它们的酸不稳定前体)这个反应被称为Nazarov环化。

The result showed due to yeast fermentation process there were many new aroma components in jujube wine which were different from the juice: Isoamyl alcohol, Phenylethyl alcohol, Benzyl alcohol and so on; jujube juice hexadecanoic acid and other senior fatty acid composition obviously degradated; Alcohols and esters composition were sharply upward.

反映出发酵过程由于酵母的繁殖代谢产生了很多新成分,如异戊醇,丁酸乙酯,辛酸乙酯等;枣汁中十六酸等高级脂肪酸成分明显降解,苯乙醇,2,3-丁二醇,己二酸(2-甲基)丁酯,己二酸二异丙酯等醇类和酯类成分呈急剧上升的趋势。

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