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They were eucalyptol, bicyclo[2.2.1]heptan-2-one,1,7,7-trimethyl-,(1R)-, borneol, 1-methyl-2-(1-methyl ethenyl)-(1R-cis)-cyclobutaneethanol, limonene, 1-hydroxymethyl-7,7-dimethy lbicyclo[2.2.1]heptan-2-one,-spathulenol, 3,7,11,15-Tetramethyl-2-hexadecen-1-ol, isocitronellol,-9-Octadecenoic acid, heneicosane, respectively.

阿给中共有11个阿给炭没有检测出的成分,包括桉油精、D-樟脑、冰片、(1R-cis)- 1-甲基-2-(1-甲基乙烯基)环丁基乙醇、二戊烯、1-羟甲基-7,7-二甲基-双环[2.2.1]庚-2-酮、-匙叶桉油烯醇、3,7,11,15-四甲基-2-十六碳烯-1-醇、异香茅醇、-9-十八碳烯酸和廿一烷。

A process for the carbonylation of allylic butenyl ether (for example, methyl crotyl ether, 3-methoxybutene-1 and mixtures thereof) or mixture of butadiene and alcohol and production of beta-gamma unsaturated carboxylic acid esters (for example, methyl-3-pentenoate) utilizing a rhodium-containing catalyst for example, dicarbonylacetylacetonate rhodium(I or the like promoted with an iodide-containing compound (for example, HI, AlI3, SnI4, TiI4, CrI3, and CoI2 or the like).

一种将烯丙型丁烯基醚(如甲基巴豆基醚、3-甲氧基丁烯-1及其混合物)或者丁二烯与醇的混合物羰基化的方法,以及由含碘化物化合物(如HI、AlI3、SnI4、TiI4、CrI3和CoI2或等效物)促进,用含铑催化剂如二羰基乙酰丙酮酸铑(I或其等效物制备β-γ不饱和羧酸酯(如甲基-3-戊烯酸酯)的方法。

Using W-HMS molecular sieve synthesized from the tungsten source of (NH4) 2WO4 as catalyst and hydrogen peroxide as oxidant, the effects of reaction time, temperature, dosage of catalyst, solvent type and volume, and oxidant concentration on the catalytic oxidation of cyclopentene to glutaraldehyde were investigated.

对以(NH4)2WO4为钨源合成的W-HMS分子筛为催化剂,过氧化氢为氧化剂,环戊烯合成戊二醛的多相催化反应进行了研究,考察反应时间、反应温度、催化剂用量、溶剂种类和用量以及氧化剂浓度等因素对戊二醛收率的影响。

Diels-Alder reaction between β-myrcene and maleic anhydride catalyzed by SO(superscript 2- subscript 4)/TiO2-ZrO2 solid superacid was investigated.

研究了SO(上标 2-下标 4)/TiO2-ZrO2型固体超强酸催化剂的制备及其催化β-月桂烯与马来酸酐的Diels-Alder反应,通过GC、GC-MS和红外分析,确定其主产物为4-(4-甲基-3-戊烯基)-4-环己烯-1,2-酸酐。

Synthesis and Structural Analysis of New Monoterpene Derivatives from β-myrcene ;2. Diels-Alder reaction between β-myrcene and maleic anhydride catalyzed by SO2-4/TiO2-ZrO2 solid superacid was investigated.

研究了SO42-/TiO2-ZrO2型固体超强酸催化剂的制备及其催化β-月桂烯与马来酸酐的Diels-Alder反应,通过GC、GC-MS和红外分析,确定其主产物为4-(4-甲基-3-戊烯基)-4-环己烯-1,2-酸酐。

That 1,4-addition reactions of Grignard agent made from 1-bromo-3-triphenylmethoxyl-1-octene and organozinc agent made from 1-iodo-3-trimethysiloxy-1-octene with 2-(6-methoxylcarbonylhexyl)-4-(2- tetrahydro-pyranyloxy)-2-cyclopentenone both gave prostaglandin 〓 methyl ester statethat prostaglandin E compounds can be prepared by 1,4-addition reaction oforganozinc agent.

最后,研究了溴化-3-三苯甲氧基-1-辛烯基镁和碘化-3-三甲硅氧基-1-辛烯基锌与2-(6-甲氧羰己基)-4-(2-四氢吡喃氧基)-2-环戊烯酮通过1,4-加成反应合成〓甲酯的方法,结果表明,用有机锌试剂通过1,4-加成反应来合成PGE类化合物是可行的。

And 27.87%, 41.54%, 14.43% in the total volatile compounds of the abdominal and dorsal muscle. Sciaenops ocellatus has the fishy, specific grassy, fatty and melon-like odor. Hexanal and1-Penten-3-ol contribute to the form of fishy smell most greatly, also the environment and the cooperative or accumulative effects of other volatile compounds have certain impacts. Compared withthe dorsal muscle, the abdominal muscle is fishier (F0.01). 1-Octen-3-ol, 4-Heptenal and benzaldehyde have close relations to the form of characteristic flavor.

美国红鱼具有以腥臭味、青草味、脂香和瓜果类香气等混合的气味;己醛和1-戊烯-3-醇对美国红鱼腥味的形成贡献最大,环境以及其它挥发性风味组分的协同或累加作用对腥味的形成也有一定影响;与背肉相比,腹肉腥味明显(F0.01); 1-辛烯-3-醇、4-庚烯醛、苯甲醛等物质与美国红鱼特征风味的形成密切相关。

This makes Ni-W-P powder more suitable for partial hydrogenation of dienes. The kinetic results suggest there are some different between the active sites of Ni-P and Ni-W-P powder. DSC, XRD and EXAFS results suggest that the tungsten codeposition makes Ni-W-P powder more amorphous than Ni-P powder.

动力学结果表明在两种合金微粒上,不仅环戊二烯与环戊烯的相对配位能力不同,而且它们各自的反应速率常数也不一样,表明非晶态Ni-P、Ni-W-P合金微粒的催化活性中心存在着一定的差异。

Plant polyprenols, which have similar structure and biological activity to dolichols in human body, are lipids of polymer with isoprenyl units. However, dolichols are key carriers in biosynthesis process of glycosyl derivatives with protein.

植物聚戊烯醇是一类异戊烯基结构聚合体的类脂化合物,与人体内多萜醇具有相似的结构特征和生理活性,而多萜醇是糖基与蛋白质生物合成的关键载体。

ResultsCTX,PDD were adminstered alone and in combination with polyprenols respectively , the inhibination of Heps nodule was raised from 42.25% and 45.04% to 56.49% and 54.96% resp...

结果聚戊烯醇分别与CTX、PDD合用,对肝癌Heps的抑瘤率分别从4 2 。2 5 %、4 5 。0 4 %提高到 5 6 。4 9%、5 4 。96 %;聚戊烯醇分别联合CTX、5 Fu用药,对艾氏腹水瘤EC的抑瘤率分别从37.6 4 %、39.89%提高到 6 2 。92 %、5 3.37%。

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