戊烯

The preparation method comprises monomer synthesis and polymer synthesis. The polymer synthesis is that cyclopentadienyl sodium monomer is added into metallic cobalt complex-triphenyl phosphorus cobalt chloride under strict oxygen-free and water-free conditions, and then double inner alkyne or outer alkyne conjugate monomer is added in, and after reaction, the precipitation, filtering, abstersion and vacuum-drying are carried out, the large molecules polymer containing cyclopentadienyl cobaltocenium organometallic cobalt is obtained.

制备方法，包括单体合成和聚合物的合成，聚合物的合成是在严格无氧无水条件下，在金属钴配合物三-三苯基磷氯化钴，加入环戊二烯钠单体，随后加入双内炔或双外炔共轭单体，反应后沉淀，过滤，洗涤，真空干燥，得到含环戊二烯茂钴有机金属钴的大分子聚合物。

The crosslinked rubber with dicyclopentadienecrosslinkage was prepared by the reaction between the chlorohydrin rubberand the cyclopentadienyl sodium.

以环戊二烯基钠与氯醇橡胶反应，制得了含CPD侧基和双环戊二烯交联的聚合物。

Isoprenoid:Class of organic compounds made up of two or more structural units derived from isoprene.

类异戊间二烯化合物：由两个或多个异戊间二烯单元组成的一类有机化合物。

Typically around a quarter of each tyre is made from isoprene derived from petrochemicals, and about 60% of worldwide isoprene production is used by tyremakers.

通常一个轮胎中所含的来自石油化工产品的异戊二烯约为25%，全世界近60%的异戊二烯产品都供给轮胎制造商。

The effects of DCPD and adipic acid content on product properties are investigated and the properties of DCPD-type-UPR and 191# UPR are cont rasted.

考察了双环戊二烯、己二酸加入量对双环戊二烯型不饱和聚酯树脂性能的影响，并与通用191#树脂的性能进行了比较。

The chapter two was focused on the samarium diiodide promoted organic reactions and their applications in organic synthesis, firstly, a new synthesis of highly substituted cyclopentadienes from a,β-alkynone promoted by samarium diiodide was investigated and the highly substituted cyclopentadienes were prepared in moderate to good yields under mild conditions. Secondly, the Michael addition and Michael-aldol tandem reaction of diorganyl diselenides or diorganyl disulfides with α,β-alkynones mediated by samarium diiodide were studied and a series of alkenylsulfides and alkenylselenides were prepared in good yields. Then the highly regioselecfive nucleophilic addition of the allylsamarium bromide to α,β-alkynones were explored. We found that the allylsamarium bromide reacts with α,β-alkynones to afford regiospecificly 1. 2-nucleophilic addition products in good yields under mild condition. At last we studied the coupling reaction of aryl halides promoted by NiCl〓/PPh〓/Sm〓.

第二章 研究了二碘化钐、金属钐促进的有机反应：1、二碘化钐促进下α，β-炔基酮的偶联环化反应，提供了一种制备多取代环戊二烯的新方法；2、二碘化钐促进下的二硫醚、二硒醚与α，β-炔基酮的Michael加成反应，为高产率地制备多取代的烯基硫或烯基硒化合物提供了方便可靠的新方法；3、二碘化钐促进下的二硫醚、二硒醚与α，β-炔基酮和醛、酮的Michael—aldol串联反应，提供了一种一锅法高产率地制备多取代的含硫的烯丙基醇或含硒的烯丙基醇类化合物的方便可靠的原子经济性的新方法；4、烯丙基溴化钐与α，β-炔基酮的高度区域选择性的1，2-亲核加成反应；5、NiCl〓/PPh〓/Sm〓促进的卤代芳烃的偶联反应-一种从各种卤代芳烃制备联苯类化合物的有效方法。

Our main products category has chloride (pivaloyl chloride, acetyl chloride, Propionyl chloride, methyl acryloyl chloride, butyl chloride, 2 - furyl chloride already chloride, acryloyl chloride, is amyl chloride, etc.) and acids (positive acid, pivalate, propionate, acetic acid, methyl acrylate, 2 - furoic acid, etc.) and so on dozens of products.

我公司主要生产的产品有酰氯类（特戊酰氯、乙酰氯、丙酰氯、甲基丙烯酰氯、正丁酰氯、2-呋喃甲酰氯、己酰氯、丙烯酰氯、正戊酰氯等）和酸类（正丁酸、特戊酸、丙酸、乙酸、甲基丙烯酸、2-呋喃甲酸等）等几十种产品。

In order to decrease copolymerization loss of isoprene during thermal dimerization of cyclopentadiene in C5-fraction,the effect of three inhibitors,diethylhydroxylamine,p-tert-butylcatechol and o-nitrophenol,on dienes' polymerization in the process was investigated by experiment with sealed glasstube.

为减少C5馏分环戊二烯热二聚过程中异戊二烯的聚合损失，采用封管实验方法考察了添加阻聚剂二乙基羟胺、对叔丁基邻苯二酚、邻硝基苯酚对热二聚过程中各二烯烃组分聚合程度的影响。

Synthesis of tricyclopentadiene Two methods of polymerization were analyzed in the synthesis of TCPD: thermal polymerization of DCPD, Diels-Alder reaction of DCPD and cyclopentadiene.

三环戊二烯的合成采用两种方式对TCPD的合成进行了研究：DCPD直接热聚法、DCPD与环戊二烯双烯加成法。

This dissertation is concerned with the approaches to a new high density liquid fuel, tetrahydrotricyclopentadiene, which can be synthesized with dicyclopentadiene as raw materials by three steps: Diels-Alder reaction, separation and hydrogenation. The main points of the paper are listed as follows.

本文以双环戊二烯为原料，通过双烯加成、分离、加氢反应得到目的产物——新型高密度液体燃料四氢三环戊二烯，主要研究内容包括： 1。

For a big chunk of credit-card losses; the number of filings (and thus charge-off rates) would be rising again, whether

年美国个人破产法的一个改动使得破产登记急速下降，而后引起了信用卡大规模的亏损。

Eph. 4:23 And that you be renewed in the spirit of your mind

弗四23 而在你们心思的灵里得以更新