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A one-step method for the synthesis of aromatic indolizine derivatives byintramolecular 1,5-dipolar cyclization reaction of 2-(2-arylethenyl)pyridinium N-ylidesin the presence of an oxidant has been studied for the first time. In the presence ofelectron-deficient olefins, however, 2-(2-phenylethenyl)pyridinium N-ylides underwent1,3-dipolar cycloadditions and then aromatized in situ by TPCD to produce indolizinederivatives, indicating 1,3-dipolar cycloaddition proceed more readily than 1 ,5-dipolarcyclization in these conditions. Pyridinium disubstituted N-ylides, readily obtainedfrom corresponding pridinium and β-chlorovinyl ketone, underwent thermalintramolecular 1,5-dipolar cyclization to give indolizine derivatives easily.Indolizinecarbaldehyde derivatives were synthesized starting from 2-pyridinecarbaldehyde in four-steps involving 1,3-dipolar cycloaddition reaction.
本文首次研究了2-(2-芳基乙烯基)吡啶N-叶立德在氧化剂存在下的分子内1,5-偶极环化反应,采用一锅法合成了中氮茚衍生物;研究了这些N-叶立德的1,5-偶极环化和1,3-偶极环加成反应的选择性,发现当有缺电子烯烃存在时,优先进行1,3-偶极环加成反应,而不再发生分子内1,5-偶极环化反应;由β-氯乙烯酮方便地得到了烯丙基N-叶立德,他们在加热时进行分子内1,5-偶极环化反应而得到中氮茚衍生物;由2-吡啶甲醛为起始原料,通过1,3-偶极环加成反应等四步反应,得到了重要的中氮茚甲醛衍生物,这些反应都具有条件温和和操作简便的特点,是合成中氮茚衍生物的新方法。
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I've been changing channels and I don't see them on the tv shows Where'd all the good people go? We got heaps and heaps of what we sow They got this and that with a rattle a tat Testing one, two man whatcha gonna do Bad news misused give me some truth You got too much to lose Whose side are we on today, anyway Okay, whatever you say Wrong and resolute but in the mood to obey Station to station desensitizing the nation Going, going, gone
我们得到了堆和许多我们播种的他们得到这了和那与一使一嘎嘎响梭编测试的,二为将要做的 whatcha 配备人手误用的坏消息给我一些事实你得到太多失去在今天,我们是谁的边,无论如何好,无论你说什么错误和坚决的除了在心情服从安置安置减感光性国家去,去,离去
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The growth relationship between spectrum parameter and fetch were studied, from which three parameters and overshot phenomenon that appears during wind wave spectra developing were tested, and an equation describing the growth of three-parameter spectra with wind wave was obtained With the equation, the spectra of wind waves were obtained at zero-dimensional fetches of 300, 500, 2000, 5500, 10000, and 15000, and the overshot was described more clearly. However, the overshot does not exist in the whole process of wind wave spectrum development as stated previously by Hasselmann, but in the early stage of the development only, extenuates with wave growth and then disappears when the wave fully grows.
基于已得到的谱参量随风区的变化关系,对三参量风浪频谱以及风浪频谱成长过程中存在的&超射&现象作深入的研究,得到三参量风浪频谱随风区的成长关系:在此基础上,得到无因次风区:300、500、2000、5500、10000、15000下,风浪频谱的谱线,从而直观地描述了风浪频谱成长过程中的&超射&现象,并认为在风浪频谱的成长过程中确实存在着&超射&现象,但是该现象并不如Hasselmann等提出的理论中阐述的那样存在于风浪频谱成长的全过程,而是仅存在于风浪频谱成长的初期。
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Lithium perfluoroalkylphosphonate was synthesized by LiF and perfluoroalkylphosphonate acid obtained by electrochemically fluorinating chlorodiisopropylphosphine. Some properties of a kind of electrolyte that was made from dissolving the lithium perfluoroalkylphosphonate in the mixed solvent with ethylene carbonate and dimethyl carbonate mass ratio 1∶1 were investigated, such as conductivity, stability toward hydrolysis and oxidative decomposition potential, and so on.
选取氯代二异丙基膦(C6H14PCl)为原料,利用电化学氟化方法,得到全氟烷基膦酸[(C3F7)2PF3],(C3F7)2PF3与氟化锂反应得到全氟烷基膦酸锂Li[(C3F72PF4],将其溶于碳酸乙烯酯和碳酸二甲酯质量比为1∶1的混合溶剂中得到电解液,考察电解液的电导率、抗水性及氧化分解电位。
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I griped my hair, because of the hot weatherI smiled at everybody, but that is purely a politenessHere where I am is terrible, constraining though will make our future better
这是一个幸福的游戏,完成游戏者会得到大家的祝福,要遵守游戏规则,好好玩下去,希望自己能得到幸福,希望延续下去的朋友能得到幸福
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In order to probe the relationships between wave equation offset domain common image gathers/angle domain common image gathers with migration velocity, we quantitatively derive the changes of ODCIGs and ADCIGs along with migration velocity on the assumption of uniform velocity medium with a horizontal reflector. We come to conclusion that ODCIGs are hyperbolas with half offset; on the contrary, they are ellipses. Combined with the results of depth focusing analysis, we find the apparent incident angles in ADCIGs are larger than the real incident angles when the migration velocity is larger than the true one and vice versa. With lower migration velocity, the residual moveout on ADCIGs is an ellipse with the tangent of apparent incident angle; otherwise, it's a hyperbola.
为了得到波动方程偏移距域共成像点道集和角度域共成像点道集与偏移速度的关系,在匀速单层水平反射情况下,对ODCIGs和ADCIGs随偏移速度的变化进行了定量的推导,得到偏移速度偏小时ODCIGs与半偏移距成双曲关系,反之成椭圆关系;结合深度聚焦分析,得到偏移速度偏大时ADCIGs中视入射角大于真入射角,反之,小于真入射角;在速度偏小时,ADCIGs上剩余时差与视入射角的正切值成椭圆关系,反之成双曲关系。
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You may be ready to show your work to the world at this eclipse, and if so, you certainly will be seen and buzzed about, and others will likely be lauding your work.
如果这样你会得到赞赏的。如果你是创业人士,你会得到一个重要部属或者得知你得到某人的庇护。
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To culture antibiotic overproducing strains, the study include using different physical and chemical factors to induce Streptomyces thermocarbonxydus var shandaensis to mutation. After original strain were mutagensised by UV combined LiCl、~(60)Co、 DES, 9 high-yield strains were obtained.
通过紫外线加氯化锂复合诱变得到高产菌株UV—18、UV—19、UV—20,其中菌株UV—19的发酵上清液抑菌圈直径是原种的1.875倍;通过~(60)Co诱变得到高产菌株Co—22、Co—36、Co—38,其中菌株Co—38的发酵上清液抑菌圈直径是原种的1.68倍;通过硫酸二乙酯诱变得到高产菌株DES—21、DES—31、DES—37,其中菌株DES—21的发酵上清液是原种的1.52倍。
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Project activities included a nationwide survey on the driver's safety belt use rate of the passenger car, the test-driving of COROLLA of TOYOYA, which have equipped with the SBR system and the questionnaire form the drivers in the test. Base on the data, we get the effectiveness of the SBR system to the people of different classification, such as age, income and education etc. The results indicated that the most effective and acceptable safety-belt reminder system concept was one that was adaptive, that is, one that changes its signal type and presentation modality depending on belt use behavior over some metric. Ultimately, base on the fatal data of passenger car driver in the traffic accident of our country and the relationship of the safety belt use rate between the dead driver and the rate in our research, we got the number of life that can be saved in the traffic accident when the SBR system was used, and then the economic losing related was calculated.
首先,通过实地拍摄得到了国内乘用车的安全带佩戴率数据;其次,通过对安装了安全带提醒装置的丰田花冠试验车的试驾调查,得到了安全带提醒装置对安全带使用的提高率,然后,利用Visual Basic对试驾问卷数据进行了处理,全面分析了安全带提醒装置对各类人群的不同效果;最后,以我国道路交通事故中轻、微型车辆驾驶员死亡人数为基础,参考交通事故中死亡驾驶员佩戴率与实际调查佩戴率之间的拟合关系以及使用安全带后驾驶员的存活率,得到了安全带提醒装置对减少国内交通事故中死亡人数的效果,然后基于所能挽救生命数量,对安全带提醒装置在降低国内交通事故中的经济损失方面的效果进行了分析。
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The result of those of insufficient understanding is temporary; the votaries of the demigods obtain the demigod; but My devotees obtains Me.
没有完全了悟真理的人,得到的结果是有限的,短暂的。信仰半人神的人就会得到半人神,而&我&的奉爱者就会得到&我&。
- 推荐网络例句
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On the other hand, the more important thing is because the urban housing is a kind of heterogeneity products.
另一方面,更重要的是由于城市住房是一种异质性产品。
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Climate histogram is the fall that collects place measure calm value, cent serves as cross axle for a few equal interval, the area that the frequency that the value appears according to place is accumulated and becomes will be determined inside each interval, discharge the graph that rise with post, also be called histogram.
气候直方图是将所收集的降水量测定值,分为几个相等的区间作为横轴,并将各区间内所测定值依所出现的次数累积而成的面积,用柱子排起来的图形,也叫做柱状图。
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You rap, you know we are not so good at rapping, huh?
你唱吧,你也知道我们并不那么擅长说唱,对吧?