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强碱

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The macro conjugated molecule fluorene derivative has 2, 3, 6, 7-tetraamino-9, 9'-dialkyl fluorene as a raw material which is added to an organic solvent respectively together with phenanthrenequinone, acenaphthene quinone or bis-carbonyl pyrene derivatives and strong base; under the protection of inert gas, reflux reaction is carried out to the materials, so as to prepare a series of trapezoidal conjugated molecules containing fluorine structures.

本发明涉及一类含大共轭分子的芴衍生物及其制备方法,大共轭分子芴衍生物是将原料2,3,6,7-四氨基-9,9'-二烷基芴,分别与菲醌、苊醌或二羰基芘的衍生物以及强碱加入到有机溶剂中,在惰性气体的保护下,回流反应制得一系列含有芴结构的梯形共轭分子。

The results show that there are serious water phase trapping, serious alkali sensibility, serious acidulous sensibility, middle to serious stress sensibility in this area.

研究区具有强盐敏、强碱敏、强酸敏,中-强应力敏感性、强水相圈闭损害。

With the wet and dry air is not working, do not dissolve in acid, and even aqua regia does not dissolve, only soluble in molten alkali, ground and carbonates such as sodium oxide.

与干湿空气都不起作用,不溶于酸,甚至王水都不溶,仅溶于熔融的强碱、地氧化钠和碳酸盐等。

To restore the ability of chromium can be dissolved in sulfuric acid, hydrochloric acid and High-FE acid and release hydrogen, but also of pure chromium with aqua regia does not work, when there is the presence of halogen ions in the acid can not be long-term stability, high temperature with alkali, hydrogen sulfide, sulfur steam, phosphorus, ammonia, such as carbon monoxide and water vapor reaction of the corresponding compounds, in the high temperature reaction of silicon into the silicide also chromium, chromium alloys with many metals generate a wide range of industrial applications, such as chromium-manganese stainless steel is used extensively for chemical plants.

铬的还原能力强,能溶于硫酸、盐酸和高FE氯酸而放出氢气,但纯铬连王水也不起作用,当有卤素离子存在时,在酸中不能长期稳定,高温时能与强碱、硫化氢、硫蒸汽、磷、氨、一氧化碳和水蒸汽等反应生成对应的化合物,在高温下还能与硅反应成硅化铬,铬能与许多金属生成合金广泛在工业上应用,如铬锰不锈钢大量用于化工设备。

A.The highly corrosive media refer to all organic and inoragnic and inorganic acid media that can almost completely ionize in the water solution,apart from hydrofluoric acid,hot aquafortis and strong base.

a。强腐蚀介质——指除氢氟酸,热浓磷酸,强碱外的在水溶液中几乎能全部电离的各种有机、无机酸性介质。

But in the process of ion exchange, xylose molecular is easily converted into arabinose because of catalytic isomerization, which results in the decrease of its purity and difficulty of crystal.

木糖是一种在化工、食品等领域有着广泛用途的五碳糖,工业生产是用稀强酸将玉米芯中含有的大量多缩戊糖分解为单个的木糖分子,然后通过离子交换除盐、脱色,精制提取,但在强碱离子交换柱中,木糖分子容易被部分催化异构转化为阿拉伯糖,使得木糖纯度下降,结晶困难。

The results showed that both increasing the KMnO4 concentration and using acidic or alkaline solution promoted the removal of Hg^0. The reasons are that H2SO4 in solution facilitates the adsorption of Hg^0 on MnO2, and that free radical OH produced in alkaline solution can oxidate Hg^0. High temperature has a negative effect on the removal of Hg^0, and the effect of Hg^0 initial concentration can be neglected.

研究结果表明,高猛酸钾初始浓度的增加、强酸或强碱条件均有利于Hg^0的去除,H2SO4的存在促进了Hg^0在MnO2上的吸附,而强碱水溶液中产生的OH间接氧经了Hg^0;反应温度的升高抑止了Hg^0的去除,而Hg^0初始质量浓度对反应的影响可忽略;KMnO4。

For the synthesis reaction of chalcone, cyclohexanone aldolization and biodiesel,γ-Al_2O_3-NaOH-Na solid superacid has a satisfactory catalytic activity. With hypnone and phenylaldehyde as raw material, amount of catalyst 7.5% wt% of material, mole ratio of hypnone and phenylaldehyde 1:1.1, reaction temperature 40℃, after 3 hours, the yield of chalcone can be up to 96.88%. With cyclohexanone as raw material, amount of catalyst 10% wt% of material, reaction temperature 190℃, after 3 hours, dimmer of cyclohexanone can be up to 85.66%.

将该固体超强碱催化剂应用于查尔酮、环己酮自缩合以及生物柴油的合成反应中,该改性固体超强碱催化剂表现出了良好的催化活性:以苯乙酮和苯甲醛为原料,反应温度为40℃,催化剂用量为反应物总质量的7.5%,苯甲醛与苯乙酮摩尔比为1:1.1,反应3h查尔酮产率可达96.88%;以环已酮为原料,催化剂用量为原料总质量的10%,反应温度为190℃,反应3h,二聚物的总收率可达85.66%;以动物油和甲醇为原料,醇油摩尔为9:1,催化剂用量为动物油质量的2%,反应温度为70℃,反应3h后,生物柴油的收率可达91.8%。

The change of agglutinating activity in different temperature and pH indicated that PML had no hemagglutinating activity at 80℃. The effect of chemical modification of amino acid residues upon hemagglutination was investigated. There was a definite decrease of fluorescence intensity which corresponds to the oxidation of tryptophan.

研究了不同温度、pH和变性剂对PML凝血活性的影响和荧光光谱的变化,当温度达80℃时,活性完全丧失;pH为4—9对活性影响不大,pH低于2和pH高于12时,大黑花芸豆凝集素的凝血活性大部分丧失;高温和强碱对荧光光谱有较大影响,表明PML对高温,强碱的耐受性不强。

The results suggested that chitinhad a good solubility in the new solvent when its at -30℃and below, but the solubilityof chitin no longer increasesd notable as the temperature reduced; The joined of urea, incertain degree, strengthened the solvency of alkali solvent to chitin. When theconcentration of sodium hydroxide is 8%~12%, Chitin had a good solubility, and theapparent viscosity of chitin solution could up to 4000 mpa·s~5000mpa·s at roomtemperature; In addition,the solubility of chitin in new solvent was high when therefrigerated time was three days and above, but the refrigerated time could not too long,otherwise, the deacetylize degree of chitin got more bigger. The properties of chitin solution were tested by revolving viscosimeter, FT-IR,X-RD and so on.

结果表明,在-30℃及以下甲壳素能很好的溶解于新溶剂中,但甲壳素的溶解度不再随温度的下降而有所增大,而是基本保持不变;尿素的加入,在一定程度上强化了强碱溶剂对甲壳素的溶解,当新溶剂中NaOH浓度为8%~12%时,甲壳素在试验温度下可以获得较好的溶解度,所得溶液在室温下的表观黏度达4000 mpa·s~5000mp·s;冷冻时间为3 d及以上时,有利于甲壳素的溶解,超过3 d,甲壳素的溶解度变化不大,另外,冷冻条件下,甲壳素在强碱溶剂中仍会发生脱乙酰化反应,冷冻时间不宜太长。

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