异烟酸

The wastewater from gum benzion production contains benzaldehyde, cyanide, gum benzoin and ethyl benzoate. When the cyanide is determined by isonicotinic acidpyrazalon method, the ethyl benzoate is distilled and goes into NaOH absorption liquid with cyanide in the process of predistillation, because its boiling point is low. Thus the absorption liquid produces a great deal of foam and feculence.

摘要］有机化工产品安息香生产废水中含有苯甲醛、氰化物、安息香和苯甲酸乙酯，在用异烟酸吡唑啉酮法对其进行氰化物测定时，由于油酯类的沸点较低，在预蒸馏过程中被蒸出和氰化物一起进入NaOH吸收液，使得吸收液产生大量泡沫和沉淀，严重干扰后续比色测定。

All the compounds are characterized by IR and elemental analysis.we design and prepare a bipyridinium supramolecular compound and six coordination compounds, which are also characterized by IR, elemental analysis and X-ray structure analysis. According to X-ray structure analysis, hydrogen bonds and n-n stocking interactions participate in the architecture of three-dimensional framework [H2L1 (NO3)2 (H2O)2]n; one-dimensional zigzag coordination polymer [Hgl21.5CH3OH]n; binuclear metallamacrocycle (HgI2L2)2 3H2O; helical double-stranded one-dimensional coordination polymer [Co2(L2)2-2CH3OH]n; double-stranded one-dimensional coordination polymer [Co2(L3)2-CH3OH-CH3CN]n; and three-dimensional compound [Cu(C5H4NCOO)2(H2O)2]-H2O with hydrogen bonds, three-dimensional coordination polymer {[Cd(C5H6NCOO)2H2O]-DMF}n, which are indirectly obtained from the precursor ligand L3 through metal ion induced the hydrolysis of diamide and self-assembled with the hydrolyzate.

我们首次合成了一个双吡啶鎓超分子化合物和六个过渡金属配合物，并通过IR谱，元素分析和X-ray晶体衍射分析对它们进行了表征。X-ray晶体结构分析表明：超分子化合物[H_2L1·(NO_3)_2·(H_2O)_2]_n是由多种氢键和芳香环间的π-π堆积作用构建的三维无限结构；[HgI_2(L1)·1.5CH_3OH]_n是一维锯齿状配位聚合物；(HgI_2L2)_2·3H_2O是双核金属大环化合物；[Co_2(L2)_2·2CH_3OH]_n是具有一维双螺旋结构的配位聚合物；[Co_2(L3)_2·CH_3OH·CH_3CN]_n为一维双链结构的配位聚合物；以及由非直线形配体L3在金属离子Cu和Cd的诱导作用下发生水解，并且金属离子与水解产物——异烟酸根离子自组装，形成了三维氢键超分子化合物[Cu(C_5H_4NCOO)_2(H_2O)_2]·H_2O和三维配位聚合物{[Cd(C_5H_6NCOO)_2H_2O]·DMF}_n。

Measurement of cyanide ; isonicotinic acid-pyrazolone colorimetric method ; experimental condition

氰化物测定；异烟酸—吡唑啉酮比色法；实验条件

It presents the mechanism to Abstract total cyanide by using phosphoric acid-EDTA and the conditions to measure cyanide by using isonicotinic acid-pyrazolone colorimetry.

文章对17种含氰废水处理方法的主要原理和优缺点作了对比说明，阐述了用磷酸———EDTA提取总氰化物的机理以及用异烟酸———呲唑啉酮比色法测定氰化物的条件

It presents the mechanism to Abstract total cyanide by using phosphoric acid-EDTA and the conditions to measure cyanide by using isonicotinic acid-pyrazolone colorimetry.

阐述了用磷酸———EDTA提取总氰化物的机理以及用异烟酸———呲唑啉酮比色法测定氰化物的条件。

Reaction of α,α,α,α-tetra (o-aminophenyl) porphyrin with isonicotinic acid yields the ligand 1b bearing two coordination sites whose structure has been verified by IR、UV-Vis、〓H NMR and MS spectra.

以α，α，α，α-四卟啉为母体，经过与异烟酸缩合反应得到具有两个配位位置的配体1b，配体的结构经过IR、UV-Vis、〓H NMR、MS验证。

The lower detection limit was 0.0006 mg/L Conclusion: Compared with the conventional isonicotinic acid 3-methy-1-pheny 1-5-pyrazolone spectrophotometry method, the advantages of the method are auto-sampling, rapid analysis speed and lower reagent consumption, etc.

与传统异烟酸－吡唑啉酮分光光度法相比，该方法具有自动进样、分析速率快、试剂耗量低等优点，可应用于大批量常规地表水分析。

In searching for novel and high active fungicides with pyridyl moiety, with Dimethomorph as a model compound and isonicotinic acid as the main starting material, twenty-seven title compounds were designed and synthesized through chlorination, Friedel-Crafts acylation, Wittig-Horner reaction and other steps. All the target structures were confirmed via 1H NMR and elementary analysis.

为了寻找具有高活性的含吡啶杂环杀菌剂，以烯酸吗啉为模板化合物，以异烟酸为起始原料，通过卤代反应、Friedel-Crafts酰基化反应、Wittig-Homer反应等，将吡啶－4-基或2-氯吡啶－4-基引入到模板结构中，设计合成了27个4-［3-（吡啶－4-基）－3-取代苯基丙烯酰］吗啉类化合物，其结构通过1H NMR和元素分析确证。

The objective of this work was to evaluate effects of 2,6-dichloroisonicotinic acid on the quality of harvested mango fruit (Mangifera indica L. cv. 'Zihua').

为了研究2，6 二氯异烟酸处理对芒果果实贮藏品质及抗病性的影响，将绿熟芒果（Mangifera indica L。

In the paper, the multidentate carboxylic acid ligands were used to combine with Cd, resulting in the three dimensional MOCPs single crystals—C12H16CdN2O8, with a low temperature hydrothermal synthesis method. The sample was characterized with IR spectra to affirm the organic groups in the frameworks, single-crystal X-ray diffraction to determine the crystal structure and composition of the frameworks, N2 adsorption isotherms at low temperature to measure the specific surface area and pore size distribution, and with TGA/DGA analysis to scale the thermal stability. Furthermore, the dissolution property and the photocatalytic activity of MOCPs under the ultraviolet ray condition were explored.

本文用低温水热合成法，用多齿羧酸配体异烟酸和Cd配位合成出[Cd(C6H4O2N)2(H2O)4]∞三维晶体并进行了表征：采用红外光谱法确认骨架中的有机官能团；用单晶X射线衍射分析法测定MOCPs的晶体结构，并确定其骨架的组成；通过低温氮气吸附等温线测定了其比表面积和孔径分布；以热重分析和差热分析测定材料骨架的热稳定性；测定了晶体的溶解性能；最后以亚甲基蓝为目标降解物，对[Cd(C6H4O2N)2(H2O)4]∞的光催化活性及亚甲基蓝的氧化动力学进行了探索(来源：A2444BC论文网www.abclunwen.com)。

The split between the two groups can hardly be papered over.

这两个团体间的分歧难以掩饰。

This approach not only encourages a greater number of responses, but minimizes the likelihood of stale groupthink.

这种做法不仅鼓励了更多的反应，而且减少跟风的可能性。