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异氰酸苯酯

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The main photoproducts in dioxane and hexane are 2-chloro benzamide and 4-chlorophenyl isocyanate.

在二氧六环及正己烷中的主要光解产物为邻氯苯甲酰胺和对氯苯基异氰酸酯。

Teflubenzuron was synthesized from 2,4-difluoronitrobenzene and 2,6-dichlobenil as starting reagent through six-step reaction with the yield of 75.3%.3,5-Dichloro-2,4-difluoroaniline was synthesized by chlorination,reduction reaction from 2,4-difluoronitrobenzene,the yield was 84.5%;2,6-difluorobenzamide with the yield of 87.7% was synthesized by fluoridation and hydrolysis from 2,6-dichlobenil.

以2,4-二氟硝基苯和2,6-二氯苯腈为起始原料,经过6步反应合成伏虫隆,总收率为75.3%。以2,4-二氟硝基苯为原料,经过氯化、还原反应合成3,5-二氯-2,4-二氟苯胺,产率为84.5%;以2,6-二氯苯腈为原料,经过氟化和水解,制得2,6-二氟苯甲酰胺,产率为87.7%;将Ⅱ与二碳酸酯酰化,合成2,6-二氟苯甲酰异氰酸酯,产率为91.3%;Ⅲ与Ⅰ加成,得到杀虫剂伏虫隆,产率为95%。

New compounds of the type of N--N'-(2,4-dichlorophenyloxyacetyl)-semicarbazides were synthesized by a series of reactions of preparing organic isocyanates by Curtius rearrangement with 2,4- dichloro aryloxyacetic acid hydrazide using one-pot procedures.

以芳香取代酸为原料,用Curtius重排的方法合成异氰酸酯,直接与2,4-二氯苯氧乙酰肼作用,一锅法合成了4种N-取代芳基-N'-(2,4-二氯苯氧乙酰基)氨基脲类化合物。

A method for the preparation of microcellular elastomeric polyurethane foams from a reaction mixture comprising a polyisocyanate component containing at least 85% by weight of 4,4'-diphenylmethane diisocyanate or a variant thereof, a polyol composition comprising at least one polyoxyalkylene polyol having an average nominal hydroxyl functionality of from 2 to 6, an average hydroxyl equivalent weight of at least 1300 and an average oxyethylene content of between 50 and 85% by weight, water, a chain extender having an average hydroxyl equivalent weight of from 15 to 250 and optionally a crosslinking agent, the hardblock-content being more than 45% by weight.

本发明是有关一种制备微孔弹性聚氨基甲酸酯泡沫体的方法,其反应混合物包括:一种含至少85重量%的4,4′-二苯甲烷二异氰酸酯或其变体的聚异氰酸酯组分,一种多元醇组合物,其包含至少一种平均标称羟基官能度从2至6、平均羟基当量至少1300且平均氧乙烯含量介于50至85重量%之间的聚氧亚烷基多元醇,水,一种平均羟基当量为15至250之增链剂,以及视需要使用的交联剂,该硬性嵌段-含量(hardblock-content)大于45重量%。

The isocyanate-terminated polyurethane prepolymer was also synthesized form polytetramethylene glycol and 4,4'-diphenylmethane diisocyanate in N,N-Dimethylformamide.

另外,将聚醚双醇与量之4,4'-二苯甲基二异氰酸酯行预聚合反应,形成具-NCO末端基之聚氨基甲酸酯预聚合体。

The recent advances in the main clean processes to synthesize diphenylmethane diisocyanates are reviewed, such as BTC method, condensation of aniline, reductive carbonylation of nitrobenzene, oxidative carbonylation of aniline, methoxycarbonylation of aniline, alcoholysis of N,N'-diphenyl urea and the coupling process.

回顾了清洁合成二苯甲烷二异氰酸酯的几种主要方法,如BTC法、苯胺缩和法、硝基苯还原羰基化法、苯胺氧化羰基化法、碳酸酯法、二苯基脲法和反应耦合法等合成路线。

In this article, we have been investigated that synthesizing and properties of shape memory polyurethane. The shape memory polyurethane was synthesized from PCL diol, MDI(4, 4'-diphenylmethane diisocyanate) and BDO (1,4-butanediol) in this experiment. We analyzed that the effect of differential mole ratio of monomers to synthesized SMPU. Besides, the various concentrations of Nano-silver were mixed with SMPU. Mechanical properties and shape memory behavior of SMPU nanocomposite films were investigated.

本研究目的为藉由改变4,4'-二苯甲基二异氰酸盐(4,4'-diphenylmethane diisocyanate, MDI)/聚己内酯二元醇(polycaprolactone diol, PCL diol)/1,4-丁二醇(1,4-butanediol, BDO)等不同莫耳比制备形状记忆型聚氨基甲酸酯(Shape Memory Polyurethane, SMPU);并探讨改变不同单体莫耳比及添加不同浓度奈米银溶液对其物性及形状记忆性的影响。

A series of 3,5-disubstituted chiral hydantoins were prepared from D-amino acid and phenyl isocyanate in mixed solvent, and the catalyst was then supported on macroporous adsorption resins.

摘 要:以混合溶剂法由D 氨基酸和异氰酸酯制备一系列3,5 二取代手性海因,用大孔吸附树脂作载体,制成固载型手性催化剂,并考察了不同结构手性海因化合物在3 苯氧基苯甲醛氰醇化反应中的催化活性。

Kinetics of hydroxyl-terminated polybutadiene/ phenyl isocyanate, bonding agent (BA-5)/PI and antioxidant H/PI were studied in toluene/dimethyl sulphoxide solution. The rate constants and the activation parameters were calculated. The results show that the reactionary rate of these three active hydrogen components decreased in same condition.

分别对端羟基聚丁二烯/苯异氰酸酯,键合剂(BA-5)/PI和防老剂H(N,N'-二苯基对苯二胺)/PI在甲苯/二甲基亚砜混合溶液体系中进行了反应动力学研究,计算了相应体系的反应速率和活化能。

In this study, Japanese cedar, Ma bamboo and Makino bamboo were liquefied in polyethylene glycol/glycerol co-solvent with H2SO4 or HCl as catalyst. The liquefied woody materials were blended with PMDI (4,4'-Diphenylmethane diisocyanate;MDI) to prepare the PU foams. The effects of preparation conditions of PU resin on the properties of PU foams were investigated.

中文摘要本研究将柳杉(Cryptomeria japonica; Japanese cedar)、麻竹(Dendrocalamus latiflorus; Ma bamboo)及桂竹(Phyllostachys makinoi; Makino bamboo)等木质材料以聚乙二醇及丙三醇之混合液为溶剂,H2SO4及HCl为催化剂进行液化处理,并将其液化木质材料与4,4'-二苯甲烷二异氰酸酯反应制造聚胺基甲酸酯发泡体,探讨PU树脂调配条件对PU发泡体性质之影响。

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但我们并不在乎沙场中的显露。

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啊!不用提了。提到肉,真是糟透了。

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