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异氰酸

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Methods: In alkaline condition, reaction between amino acids and phenylisothiocyanate formed a derivant of phenylisothiocyanate-amino acid. For RP-HPLC, the Diamonsil C18 column 250 mm×4.6 mm,5 μm) and binary gradient elution were used. The mobile phase A was 0.1 mol/L sodium acetate solution-acetonitrile (93∶7) and the mobile phase B was acetonitrile-water(80∶20). The detecting wavelength was 254 nm.

在碱性条件下,氨基酸与异硫氰酸苯酯反应,生成异硫氰酸苯–氨基酸的衍生物,采用 Diamonsil C18色谱柱(250 mm×4.6 mm,5 μm),用二元梯度洗脱方式,流动相A为0.1 mol/L乙酸钠–乙腈(93∶7),流动相B为乙腈–水(80∶20),检测波长254 nm。

Isocyanurate was qualitatively identified by infra-red absorption spectroscopy analysis, the quantity of isocyanurate was calculated according to mass fraction of NCO measured by di-n-butylamine method, the thermal stability of prepared elastomers was characterized by thermogravimetric analysis.

用红外光谱法证实了产物中异氰脲酸酯的存在,根据用二正丁胺法测得的NCO基团的质量分数可计算出异氰脲酸酯的质量分数,用热重法分析了产物的热稳定性。

Tri (2-hydroxyethyl) isocyanurate was used as the curing agent to synthesize the polyurethane elastomer modified by isocyanurate.

以三(2-羟乙基)异氰脲酸酯为固化剂,用异氰脲酸酯环合成改性聚氨酯弹性体。

HBPSi to join after, HBPSi of epoxy groups can triazine ring into isocyanuric acid ester, isocyanuric acid ester and then with epoxy to form one oxazoline (see signal-1a), To reduce the stiffness of the resin network.

加入HBPSi后,HBPSi的环氧基团可使三嗪环转化为异氰脲酸酯,异氰脲酸酯进而与环氧基反应生成噁唑啉酮(oxazolidinone rings(见示意式1a),降低了树脂网络的刚性。

It indicates that the raw materials can be stored in temperature of 0-4℃ for 60 days, they must be immersed in clean water for more than one hour before processing, and peeling be carried out in flowing water; that color preserving solution should be 1.0% NaCl+0.2% citric acid+0.5% Vitamin C+110ppm dichloro isocyanuric acid sodium; that combined browning inhibiting solution is conspicuously effective, and immersion time better be around 20 minutes; that sterilization solution ought to be 200ppm dichloro isocyanuric acid sodium+0.5% ascorbic acid+0.3 citric acid, and 10 minutes' immersion will achieve the effect of sterilization and inhibiting browning; and that after 20-21 minutes of quick-freezing in temperature of -31℃~-32℃, the products can be preserved under -18℃ for a whole year.

通过对速冻牛蒡加工过程中原料储存、削皮方法、护色、浸泡时间、无热杀菌、包装形式等参数进行研究表明:原料0-4℃可储存60天,加工前用清水浸泡1小时以上,削皮时在流水中进行,护色液筛选的1.0% NaCl+0.2%柠檬酸+0.5%维生素C十110ppm二氯异氰脲酸钠;复合褐变抑制溶液在抑制褐变方面有显著的效果,浸泡处理时间为20分钟为宜;杀菌液为200ppm二氯异氰脲酸钠+0.5%抗坏血酸+0.3柠檬酸,浸泡10分钟即可达到灭菌和抑制褐变的作用;经-31℃~-32℃温度下速冻20~21分钟,产品在-18℃条件下可储存一年。

Benzyl isothiocyanate and phenethyl isothiocyanate, are derived isothiocyanates from cruciferous vegetable, including watercress, broccoli and cabbage.

苯甲基异硫氰酸酯和苯乙基异硫氰酸酯是来自於十字花科蔬菜的衍生物,常见的十字花科蔬菜包含了花椰菜、甘蓝菜、芥菜…等。

A reversed-phase high performance liquid chromatographic method was established for determination of isothiocyanates in human urine , which used the reaction of propyl isothiocyanate with 1,2-benzenedithiol as reference instead of the synthesis of 1,3-benzodithiole-2-thione.

省去合成1,3 苯二硫杂环五烯 2 硫酮这一步骤,直接用异硫氰酸丙基酯与1,2 苯二硫酚反应作标准,建立了尿液中异硫氰酸酯的反相高效液相色谱测定方法。

Benzyl isothiocyanate and phenethyl isothiocyanate induced apoptosis of DU-145 cells which also were confirmed by DAPI staining and DNA gel electrophoresis.

除此之外,苯甲基异硫氰酸酯和苯乙基异硫氰酸酯也会造成人类前列腺癌细胞株DU-145粒线体膜电位的改变,活性氧化物质和钙离子的释放以及造成DNA的损伤。

Western blotting show that benzyl isothiocyanate and phenethyl isothiocyanate treatment gradually decreased the level of anti-apoptotic proteins, but increased the level of pro-apoptotic proteins.

接著,由西方点墨法的结果发现苯甲基异硫氰酸酯和苯乙基异硫氰酸酯会造成人类前列腺癌细胞株DU-145凋亡蛋白的增加和Caspase活性的上升。

Besides, benzyl isothiocyanate and phenethyl isothiocyanate also decreased the levels of mitochondria membrane potential, induced reactive oxygen species and calcium ion production in examined DU-145 cells.

由结果显示,苯甲基异硫氰酸酯和苯乙基异硫氰酸酯确实会造成人类前列腺癌细胞株DU-145细胞周期停滞以及诱导细胞凋亡的产生。

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