异氰酸

The prepared PU was an elastic solid,which could dissolved in ethanol,and it exhibited strong deep purple fluorescence at the peak of 365 nm along with a shoulder at 386 nm as a thin film. Obviously,the prepared PU also was a kind of uncommon ultraviolet-emitting polymer materials.2.A novel water-soluble rod-coil block copolymer was designed and prepared successfully via the facile isocyanic acid polycondensation method using polyfluorene as rod segment and polyethylene glycol as coil segment in the main chain for the first time.

所制备的聚氨酯是一种弹性固体，可以溶解在乙醇中，同时又显示出具有半导体性质的荧光性能——最大荧光发射峰在365 nm并且在386 nm处有一个小的侧肩峰，可见它又是一种非常难得的紫外发光聚合物材料。2、首次采用了简单的异氰酸酯反应，成功地将聚芴作为刚性链段和聚乙二醇作为柔性链段，以嵌段方式连结到聚合物分子主链上，从而形成了一种新型的具有刚性链—柔性链结构的嵌段共聚物。

Funds are needed. On the basis of local rich resources of raw material, the project adopts technology of straw smash and dustproof processing, emulsification of Isocyanic Acid Fat, accurately usage of agglutinant and viscidity-proof pattern. A production line of straw flakeboard with annual output of 100,000 cubic meters will be established.

拟引进资金，利用当地丰富的原料资源，采用麦秸细化精碎和防尘处理技术，异氰酸脂的乳化技术，精确施胶技术，防粘脱模技术，采用连续热压工艺设备，建设麦秸刨花板生产线，年产10万立方米麦秸刨花板。

By treatment of (4R)-carboxy-(2S)-phenylthiazolidine with isocyanic acid benzyl ester in CH_3COOH/(CH_3CO)_2O system,the reaction time is shortened from 17 h to 3 h,and the yield of (7aR)-3-phenyl-1H,3H-imidazo[1,5-c] thiazole-(6H, 7aH) 5,7-dione is raised from 75% to 93%.

改用异氰酸苄酯为关环试剂环化合成了(7aR) 3 苯基 6 苄基 1H，3H 咪唑并[1，5 c]噻唑 5，7 二酮，选用CH3COOH/(CH3CO)2O代替CH3COOH作溶剂，反应时间由17h缩短为3h，产率从75%提高到93%。

Using ab initio methods, three molecular reactions about Isocyanic acid were investigated in this thesis, that is :(1) HNCO+HCO→TS→NCO+CH2O (2) A:HNCO+CN→TS→NCO+HCN B:HNCO+CN→TS1→INT→TS2→HNCN+CO (3) HNCO+NO2→TS1→INT1→TS2→INT2→TS3→HNNO+CO2 The theoretical studies show that the reaction (2) may occur by two different reaction channels, A and B.

本论文采用量子化学从头算方法，研究了异氰酸下列三个反应的反应机理和速率常数。

Using ab initio methods, three molecular reactions about Isocyanic acid were investigated inthis thesis, that is :(1) HNCO+HCO→TS→NCO+CH2O (2) A:HNCO+CN→TS→NCO+HCN B:HNCO+CN→TS1→INT→TS2→HNCN+CO (3) HNCO+NO2→TS1→INT1→TS2→INT2→TS3→HNNO+CO2 The theoretical studies show that the reaction (2) may occur by two different reaction channels,A and B.

本论文采用量子化学从头算方法，研究了异氰酸下列三个反应的反应机理和速率常数。

The result indicated that, gathers in advance the emulsion water resistance and mechanics performance which in the body preparation method the one-stage process obtains is good, but two steps obtain the emulsion stability is good; The neutralizaing agent triethylamine amount used should enable to achieve neutral between x-y, to gathers in advance the body disperser and the emulsion stability only then is advantageous; The water affinity chain extendor DMPA content to the emulsion viscosity, stable and the emulsion cellophane water resistance has the remarkable influence, its amount used general control between x-y; Hard section isocyanogen diethylene glycol dinitrate primary control paint film degree of hardness, module, anti-avulsion, wear-resisting and so on performance, the soft section low-molecular polymer polyols primary control paint film elasticity, hydrolisis performance and so on bears the low temperature and bears

结果表明，预聚体制备方法中一步法得到的乳液的耐水性和力学性能较好，而两步法得到的乳液的稳定性好；中和剂三乙胺的用量应使中和度达到x-y之间，对预聚体的分散和乳液的稳定性才有利；亲水扩链剂DMPA的含量对乳液的粘度、稳定性及乳液胶膜的耐水性有着显著的影响，其用量一般控制在x-y之间；硬段异氰酸酯主要控制涂膜的硬度、模量、抗撕裂、耐磨等性能，软段低聚物多元醇主要控制涂膜的弹性、耐低温和耐水解等性能

The results showed that isocyanurate modified polyurethane elastomers exhibited better thermal propterty than that of general polyurethane elastomers.

结果显示，与普通聚氨酯弹性体相比，用异氰酸酯改性后的聚氨酯弹性体的热稳定性明显得到了提高。

Some affecting factors on properties of the adhesive were discussed, including relative molecular weight of polyester polyol, Chain-extender, isocyanurate index and water.

讨论了聚酯多元醇的相对分子质量、扩链剂、异氰酸酯指数、水分等对聚氨酯油墨连接料性能的影响。

In this part of dissertation, the cure reactions of PGA withhexamethylene diisocyanate isocyanurate were investigsted byFTIR, DSC and gel fraction.

本文用FTIR、DSC和凝胶含量的测定等方法，对聚丙烯酸环氧丙酯和六亚甲基二异氰酸酯三聚体的固化反应进行了研究。

The cure reactions of ternarysystem containing poly, poly and HDI isocyanurate, and the effect of the ratio ofPGA/POH on the thermal, mechanical and surface properties of curedresin have also been examined.

本文还研究了聚丙烯酸环氧丙酯、聚丙烯酸羟丙酯和六亚甲基二异氰酸酯三聚体的反应及三元反应体系中PGA／POH的不同比例对交联后树脂的热性能、力学性能及表面性能的影响。

The split between the two groups can hardly be papered over.

这两个团体间的分歧难以掩饰。

This approach not only encourages a greater number of responses, but minimizes the likelihood of stale groupthink.

这种做法不仅鼓励了更多的反应，而且减少跟风的可能性。