异氰酸

The reactions of ethylenedinitrourea with ethylenediamine or with polyether were studied.

根据乙撑二硝基脲降解生成乙撑二异氰酸酯中间体的性质，研究了它与乙二胺的反应，并进行了硝化反应研究。

For example, cyanuric acid 〓 is added to the exhaust gas in the RAPRENOx process.

烯酮自由基在消除大气中的NOx过程中具有与异氰酸相似的作用。

Teflubenzuron was synthesized from 2,4-difluoronitrobenzene and 2,6-dichlobenil as starting reagent through six-step reaction with the yield of 75.3%.3,5-Dichloro-2,4-difluoroaniline was synthesized by chlorination,reduction reaction from 2,4-difluoronitrobenzene,the yield was 84.5%;2,6-difluorobenzamide with the yield of 87.7% was synthesized by fluoridation and hydrolysis from 2,6-dichlobenil.

以2，4-二氟硝基苯和2，6-二氯苯腈为起始原料，经过6步反应合成伏虫隆，总收率为75.3%。以2，4-二氟硝基苯为原料，经过氯化、还原反应合成3，5-二氯-2，4-二氟苯胺，产率为84.5%；以2，6-二氯苯腈为原料，经过氟化和水解，制得2，6-二氟苯甲酰胺，产率为87.7%；将Ⅱ与二碳酸酯酰化，合成2，6-二氟苯甲酰异氰酸酯，产率为91.3%；Ⅲ与Ⅰ加成，得到杀虫剂伏虫隆，产率为95%。

Using the MP2 method at the 6-311G level, the geometries of the reactants, transition state and products of the hydrogen abstraction reaction of isocyanic acid with formyl radical have been optimized. Changes of bond lengths of interacting molecules and the stationary point structures were discussed along the minimum energy paths.

在 UMP2/6-311G计算水平上，优化了标题反应的反应物、过渡态、产物的几何结构，沿最小能量途径讨论了异氰酸和甲酰自由基发生氢转移反应位能面上驻点的结构以及相互作用分子结构变化。

Isocyanic acid ; Hydrogen abstraction reaction ; ab initio ; Formyl radical ; Rate constant

异氰酸；氢转移反应； abinitio ；甲酰基自由基；速率常数

The Catalyst used for preparation of carbodiimide from condensation of isocyanate were reviewed in this paper, including phosphorus-containing heterocycle compounds, phosphonate,organic metal compounds and polymer-grafting solid catalysts.

综述了异氰酸酯缩合生成碳化二亚胺催化剂的开发现状，包括磷杂环化合物、磷酸酯类化合物、金属有机化合物、聚合物接枝固相催化剂4大类。

One-pot reactions of 4 with isocyanates, triphenyl phosphine, hexachloroethane and triethylamine produced 2-anilino-5-arylidene-1-aryl-4,5-dihydroimidazo[1,2-b]-1',2',4'-triazol-4-ones 6 (or 7) in good yields.

而后用4与芳基异氰酸酯、三苯基膦、六氯乙烷和三乙胺"一锅"反应，得到4，5-二氢咪唑并[1，2-b]-1'，2'，4'-三唑-4-酮衍生物6或7。

The analysis proves that bonding agents can act as the liner of CL-20 and a bonding agent containing hydantoin and tripolyisocynate,which is defined as 22~#,is the best liner of CL-20 owing to its cyclic structure and polar groups.

结果表明，键合剂可以作为CL-20的包覆剂；由于海因和三聚异氰酸酯键合剂(22#)的环状结构以及具有较多的极性基团，对CL-20的包覆性最好。

Inulin has been modified by carbamoylation in organic solvents.

菊糖与十八烷基异氰酸酯在有机溶剂中发生甲氨酰化反应，生成的氨甲基菊糖具有表面活性。

OBJECTIVE: To study the synthesis of β-phenylethyl isocyanate.

目的：研究β-苯乙基异氰酸酯的合成。

The split between the two groups can hardly be papered over.

这两个团体间的分歧难以掩饰。

This approach not only encourages a greater number of responses, but minimizes the likelihood of stale groupthink.

这种做法不仅鼓励了更多的反应，而且减少跟风的可能性。