异构的

For 2,2,4,4-tetrachloropentane,the energy of the conformer with gauche-gauche arrangement is lower; For 2,2,4,4,6,6-hexachloroheptane,the conformer with trans-gauche-trans-gauche arrangement is stable.

结果表明，对于2，2，4，4-四氯戊烷，采用gauche-gauche排列的旋转异构体的能量较低；2，2，4，4，6，6-六氯庚烷旋转异构体中，采用trans-gauche-trans-gauche排列的构象能量较低。

1H NMR spectroscopic analysis of aromatic protons combined with theoretical analysis of molecular structures proved the existence of two rotational isomers at 300 K, as well as a rapid interconversion equilibrium at 330 K for both compounds Ⅰ and Ⅱ. However, only one conformer exists for compound Ⅲ and puerarin containing 7-phenolic hydroxyl instead of propyl in A-ring as the case of compounds Ⅰ and Ⅱ. Based on UV-Visible absorption data of neutral and basic solutions, and on the density function calculations, the 7-phenolic hydroxyl group in A-ring was found to be more acidic than the 4'-phenolic hydroxyl group in B-ring. The mechanism of derivation reaction and the structure-reactivity relationship of puerarin as an antioxidant were further discussed.

其中7-丙基葛根素Ⅱ属于新型取代衍生物；变温1H NMR和理论计算结果表明，在300 K时，葛根素和4'-丙基葛根素以单一构型存在；而7，4'-二丙基葛根素和7-丙基葛根素则存在两种核磁可分辨的旋转异构体，当温度升至330 K时，两种异构体可以相互转化；通过对比分析葛根素及其衍生物脱质子产物的紫外可见吸收光谱并结合理论计算，确定了A环上7位酚羟基比B环上4'位酚羟基先脱去质子，并由此进一步阐明了葛根素衍生化反应机理以及在抗氧化作用中可能的活性位点和结构活性关系。

In chapter 6, seven pairs of diastereoisomers of podophyllum lignans at C4-position, including three pairs of spin labeled compounds, were separated by MEKC with 20mM sodium tetraborate-30mM SDS-10％ 2-propanol (pH=9.5-9.7) within 20min.

第六章：首次利用胶束电动毛细管色谱分离了七对抗癌药物鬼臼类木脂素在C4位的差向异构体，该方法可用来鉴定分析物的纯度、确定自旋标记化合物C4-H的构型等，为研究差向异构体不同的抗癌机制提供检测手段。

In addition nC〓, nC〓, two isomers of C〓 sterene and three isomers of C〓 isoprenoid hydrocarbons were also identified from aliphatic fraction of pyrolyzed product at 200℃. After pyrolyzed at 300℃, the main aliphatic hydrocarbons were normal alkanes ranged from C〓 to C〓, with C〓 as the main peak and C〓 as the second main peak. Meanwhile, pristane, phytane and C〓 sterane were also detected. In the pyrolysates at 400℃ and 500℃, the content of saturated hydrocarbons decreased, the range of normal alkanes distribution became narrow and the main peak was nC〓. Low concentration of C〓-C〓 steranes was detected and the content of C〓-C〓 increased more.

在200℃热模拟产物饱和烃馏分中除检测出两种长链烯烃外，还检测到正十九碳单烯烃、正三十五碳双烯烃、两个碳二十八甾烯的同分异构体和三个C〓类异戊二烯烷烃化合物同分异构体。300℃模拟产物饱和烃主要为正烷烃，正烷烃的碳数分布范围为C〓-C〓，以C〓为主峰、C〓为次主峰；另外，样品中还检出姥鲛烷、植烷和C〓甾烷等化合物。400和500℃热模拟产物中的饱和烃含量下降，正烷烃系列碳数分布范围变窄，主峰碳后移至C〓，检测到低浓度的C〓-C〓甾烷系列化合物，另外，C〓-C〓藿烷系列化合物含量进一步增加。

Second, using DBU as the base for enolization of propargylic esters of unsaturated acids 18e-k, we developed a tandem Ireland-Claisen rearrangement /isomerization reactions. It has been shown that the reaction sequence affords triene molecules 42a-b and 43a-b in moderated to high yields. Interestingly, with allyl hexa-3,5-dienoates 18i-j as the substrate, the rearranged products underwent further aromatization to give uniquely substituted benzyl acids 44a-b.

其次，以含有活泼质子的烯酸炔丙酯18e-k为底物，在DBU为烯醇化碱、TMSCl为硅试剂的条件下，底物18e-h发生了Ireland-Claisen重排/异构化串联反应，得到完全共轭的三烯类化合物42a-b及43a-b；而以己二烯酸炔丙基酯18i-j为底物时，重排/异构化后的产物进一步发生电环化等反应最终得到芳构化产物——取代苯甲酸类化合物44a-b。

Analyzed the relative stability and isomerization, it was found that Ni3BPsuperscript (3 was thermodynamically the most stable one. In addition, Ni3BPsuperscript (1, Ni3BPsuperscript (1 with singlet state and Ni3BPsuperscript (3, NiPsuperscript (3 with triplet state are kinetically stable ones.

分析各异构体的相对稳定性及异构化过程得出：Ni3BP上标(3是单、三重态中热力学最稳定的异构体；单重态的Ni3BP上标(1、Ni3BP上标(1和三重态的Ni3BP上标(3、Ni3BP上标(3具有一定的动力学稳定性。

Heterogeneous distributed systems have different processors and each processor has different capability and robusticity.

研究了基于异构分布式系统的实时容错调度算法，同构分布式系统中的处理机完全相同，而在异构分布式系统中各个处理机均不相同，各个处理机有不同的处理能力和不同的健壮性。

The catalytic performance of the synthesized molecular sieves, modified by Pd or Pt, for isomerization and dehydroisomerization of n butane was investigated. Pd/SAPO 11 catalyst showed the highest selectivity in...

结果表明，载 0 3%Pd的SAPO 11分子筛催化剂具有最高的丁烷异构化选择性，而在丁烷一步异构脱氢反应中，含金属杂原子的催化剂具有更高的异丁烯选择性。

Master the structures, isomers, conformations, namenclature of alkanes; alkyl groups, homology; physical and chemical properties of alkanes, radical reaction; namenclature of cycloalkanes, cis-trans isomerism in cycloalkanes; chemical properties of cycloalkanes.

掌握烷烃的结构，构造异构，构象，系统命名；烷基、同系物；烷烃的化学性质，自由基反应；脂环烃的命名，顺反异构；化学性质。

He analysis of the category and function of TCB stress inducible proteins showed that different groups of proteins were induced by 5 mg L^(-1) TCB stress. They are detoxification enzymes (including esterase, aldo/keto reductases, and glutathione S-transferase), cell wall compound metabolism related enzymes (including UDP-glucose protein transglucosylase and GDP-mannose 3,5-epimerase 1), phytohormone metabolism and regulation related enzymes or proteins (including aci-reductone dioxygenase 4, beta-glucosidase, two members of pathogenesis-related proteins from family 10), primary and secondary metabolism regulative enzymes (including translational elongation factor Tu, cytosolic orthophosphate dikinase, triosephosphate isomerases, alanine aminotransferase, and isoflavone reductase).

CB胁迫能诱导根系内不同类型蛋白质的表达，它们是：解毒酶（包括脂酶、醛／酮还原酶、谷胱甘肽－硫转移酶），细胞壁物质代谢相关酶（包括蛋白转葡萄糖基酶、GDP-甘露糖－3，5-异构酶1），激素代谢或调节相关酶（包括酸式－还原酮二加氧酶、β-葡萄糖苷酶、病程相关蛋白家族10中的2个不同蛋白），原初或次生代谢相关酶（包括转录延长因子、细胞质磷酸丙酮酸双激酶、磷酸丙糖异构酶、丙氨酸氨基转移酶和异黄酮还原酶）。

This one mode pays close attention to network credence foundation of the businessman very much.

这一模式非常关注商人的网络信用基础。

Cell morphology of bacterial ghost of Pasteurella multocida was observed by scanning electron microscopy and inactivation ratio was estimated by CFU analysi.

扫描电镜观察多杀性巴氏杆菌细菌幽灵和菌落形成单位评价遗传灭活率。