异构的

By employ those techniques,the energy thresholds for conformational isomerization in a given reactant-product conformer pair(e.g.tryptamine) are directly determined.

文中还简要介绍了一种新的应用于构象异构动力学研究的光谱方法，即激励辐射泵浦-注孔和激励辐射泵浦-布居转移。

Synthesis and Structure of 1-(m-Methoxyphenyl)-2- cyclohexanol

对反应的立体化学进行了分析，并用13CNMR谱确定了顺反异构体的构型。

The results of density functional calculations indicate that the enol form E1 is the most stable tautomer at the ground state.

研究结果表明，醇式异构体E1为2-(2-巯苯基)苯并噁唑的优势构型；在E1向K转变过程中，存在一个较小的能垒；当考虑零点振动能后，逆向能垒消失。

Based on the above, the paper puts forward the architecture for accessing the distributed isomorphic or heterogeneous database based on Web Service technology.

通过集团公司的案例实践，本文提出了利用Web服务整合同构或异构分布式数据库的原型系统。

Paraffin consists of n-alkane,short p-alkane,naphthene and aromatic, minimal amount of compounds containing elements S,N,O.

石蜡主要是由正构烷烃组成，还有较少的异构烷烃、环烷烃和芳烃，以及含微量S、N、O的化合物。

Hydroisomerization reactions of n-paraffins with double-function catalysts have been developed as one of the most important clean method to improve the octane number of the gasoline.

将正构烷烃在氢溢流条件下使用双功能催化剂催化为异构反烷烃是提高汽油辛烷值的最重要的绿色方法。

After prolonged heating 15h, 120° of the origina lly isolated stereoisomer B (melting C point mp: 157° Diels and Alder obtained two new stereoisomers E (mp: 153° and F C), C (mp: 163° Equilibration of B with a catalytic amount of a strong base at 25° ga ve a C).

在比原始分离异构体 B (熔点： 157°C)的方法延长加热时间之后(15h， 120°C)， Diels and Alder 获得了两个新的异构体 E(熔点：153°C)和 F(熔点：163°C)。

Triose phosphate isomerase was prepared and purified from chicken breast muscle. The equilibrium unfolding of TIM induced by guanidine hydrochloride was investigated by following the changes in intrinsic fluorescence, circular dichroism and second-derivative spectroscopy.

从鸡胸肌中纯化出磷酸丙糖异构酶(triose phosphate isomerase， TIM)，通过蛋白质内源荧光，圆二色性，紫外吸收二阶导数光谱等多种研究溶液构象的方法，对TIM被盐酸胍和热变性过程进行了详细的研究。

Treatment of dials with N-tert-butanesulfinamide, all biaryl dials were successfully converted into the corresponding bis-imines which were then treated with samarium diiodide to afford diamine products. The absolute configurations of all the intramolecular coupling products were determined by X-ray crystallography.

轴手性二醛与N-叔丁基亚磺酰胺缩合得到相应的亚胺，其为一对非对映异构体。N-叔丁基亚磺酰亚胺在二碘化钐条件下得到的偶联产物，经X-衍射也确定了其立体构型。

In the gas phase,Pt_2CH_2~+ has only one most stable structure whereas PtAuCH_2~+ has two isoenergetic isomers.

Pt_2CH_2~+在气相中只有一种能量最稳定的构型，而PtAuCH_2~+却存在两种能量相近的异构体。

This one mode pays close attention to network credence foundation of the businessman very much.

这一模式非常关注商人的网络信用基础。

Cell morphology of bacterial ghost of Pasteurella multocida was observed by scanning electron microscopy and inactivation ratio was estimated by CFU analysi.

扫描电镜观察多杀性巴氏杆菌细菌幽灵和菌落形成单位评价遗传灭活率。