异构的

In order to find the difference of the isotopic composition of different organic compounds before and after complexation, the autogamy standard sample is performed by molecular sieve adsorption to study the variation of the isotope compositions of n-alkanes, isoalkanes and cyclanes.

通过对自配标准样品进行S分子筛吸附试验，测定了用5分子筛吸附法分离前后正构烷烃、异构烷烃和环烷烃碳同位素值，探讨试验前后碳同位素值的变化。

In the case of ethane, then , there exist three conformational isomers or conformers, which are degenerate because they are congruent , have the same energy, and are, in all respects, indistinguishable.

在乙烷的话，那么，我们有三种异构体或构构，这是堕落，因为他们是一致的，具有相同的能量，并在所有方面，没有什么区别。

In addition, NBO analysis shows that it is hyperconjugation rather than repulsive forces that plays a key role in the relative stabilities of isomers.

此外， 通过NBO方法分析了分子的超共轭作用和立体排斥能对异构体稳定性的影响，结果表明超共轭作用是影响各异构体构型相对稳定性的主要因素。

In these solvents there is an equilibrium for 2-(2-mercaptophenyl)benzoxazole in the ground state between E1 and K, and the equilibrium shifts toward the tautomer K as the polarity of the solvent increases.

在溶液中，随着溶剂极性的增强，醇式异构体E1与K之间的反应平衡向K方向移动，在非极性溶剂环己烷中， E1为优势构型，而在强极性水溶液中， K为优势构型。

Each medicine used in the study totally has obivious effect on lens sodium-pump. Either on the molecular and cellular level or on the histological and organic level , they all have their distinctive demonstration. 1.Ouabain、Digoxine、DMSO decrease the expression of αsubunit of sodium pump on mRNA level , the cell morphology and ultramicroscopic structure demonstrated destructive effect,it indicates the cause of cataract of the medicines.2.D-thyroxine、Amphotericin B、Vitamin E increase the expression of αsubunit of sodium pump on mRNA level ,from the demonstration of the cell morphology and ultramicroscopic structure ,it indicates the medicines have protective or anti-distructive effect on lens.3.The medicines have isoform-specific action on lens sodium-pump,it indicates exploitting isoform-specific medicine has a promising clinical application.4. Lens sodium-pumps are inhibited probably lead to cataract, so in clinical medication, especially to the cardiovascular doctor, while he is using the sodium-pump inhibitors, he should pay more attention to adjust the dosage and duration of the drug therapy. 5. To creat the animal model of cataract through inhibiting lens sodium-pump, whether it can be a kind of classical method or not, it is worthy of further research.

本研究所选用的药物对晶状体钠泵均有明显的影响作用，在分子水平、细胞水平、组织器官水平均有特异的表现：1、哇巴因、地高辛、二甲基亚砜三种药物可降低晶状体钠泵α亚单位在 mRNA水平的表达，在细胞形态和超微结构上表现为损伤效应，提示了其潜在的导致白内障的可能。2、D甲状腺素、两性霉素B、维生素 E三种药物可升高晶状体钠泵α亚单位在 mRNA水平的表达，从细胞形态和超微结构上的表现，提示了其对晶状体有保护作用或抗损伤效应。3、药物作用于晶状体钠泵具有重整异构特异性，提示了开发出特异的具有重整异构作用的药物是极有临床应用前景的。4晶状体钠泵抑制后可能导致白内障的发生，故临床用药，尤其是心内科医生在使用这些钠泵抑制剂时应注意调整用药剂量及药物疗程。5 通过抑制晶状体钠泵来制作白内障动物模型能否成为一种经典的制作方法，还有待于进一步研究。

Based on the results of this report and the results of literature reports on the preferred conformation of enantiomeric 3-substituted-1, 4-benzodiazepines, a nucleophilically solvated C3 carbonium ion intermediate resulting from either a P or a M conformation is proposed to be an intermediate.

基於本文所报导的结果及文献所记述之对映异构性在C3位有取代基时的1，4-苯并二氮类的倾向构象，设想提出所观察之现象是由正或负构象所致的一个亲核性经溶剂化的C3阳碳离子为中间体。

In the first route, the isomerization process of α-isophorone into a β-isophorone requires high temperatures, and only about 4% of the conversion was obtained for the conjugate effect of α-isophorone.

在第一条路线中由于α-异佛尔酮的共轭效应，使得α-异佛尔酮异构化为β-异佛尔酮的过程中需要很高的温度，且仅有4%左右的转化率。

In order to supply basic thermodynamic data for the separation design of acetyl acetone from the isomerization reaction of isopropenyl acetate,vapor-liquid equilibrium data of isopropenyl acetate-acetyl acetone system under 101.3 kPa was measured using Ellis equilibrium still.

为了给乙酸异丙烯酯异构化生产乙酰丙酮工艺的产物分离设计提供基础热力学数据，用埃利斯平衡蒸馏器测定了101.3 kPa下乙酸异丙烯酯-乙酰丙酮体系的汽液平衡数据，结果表明，该二元体系未形成共沸物，实验数据通过了Herrington面积法的热力学一致性检验。

The results are in good agreement with available experimental results. The entropy effect on the Gibbs free energies of 6-thioxanthine base is very small and there is little significance for the tautomeric equilibria of the base.

计算结果同已有实验结果一致。6-硫代黄嘌呤异构化的熵效应小，对互变异构平衡几乎没有显著的影响，而焓变对互变异构产生了主要的影响。

This paper introduces the background knowledge of heterogeneous data integration, as well as the knowledge of data integration. On the basis of the above, The author develops an ontology-based Heterogeneous data Integration prototype system, expounds the main framework and essiontial technology. Then the paper introduces its work in detail: it explains the very significance of using ontology as an comon semantic description and an global query model ,and illustrates the reason fo adopting LAV method ; then it builds the formal representation of the mapping between ontology and data resources, applies OWL to describe the ontology and the mapping ; defines a query language named by DIQL to query on our integration system , and supply the detailed arithmetic of reolving partial binding of LAV method、locating of data sources and query rewriting,etc. Finally,the paper demostrates and proves the result of research by examples .

本文介绍了目前异构数据集成的研究现状以及数据集成和本体的相关背景知识，并在此基础上设计开发了一个基于本体的异构数据LAV集成原型系统，同时对原型系统的总体框架、关键实现技术分别做了讨论：首先阐述了将本体作为公共语义描述和全局查询模型的意义，给出了采用LAV集成方案的理由，然后规定了本体和数据源间映射的形式化表示方式，采用能结合描述逻辑和框架系统的优点、适合于半结构化环境的OWL表示本体和映射；其次定义了一种针对集成系统的查询语言DIQL，并在此基础上给出解决LAV部分绑定问题、数据源定位以及查询重写的算法；最后在原型系统的基础上，通过实例验证本文所提方法的可行性。

This one mode pays close attention to network credence foundation of the businessman very much.

这一模式非常关注商人的网络信用基础。

Cell morphology of bacterial ghost of Pasteurella multocida was observed by scanning electron microscopy and inactivation ratio was estimated by CFU analysi.

扫描电镜观察多杀性巴氏杆菌细菌幽灵和菌落形成单位评价遗传灭活率。