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Performance comparisons of hydroisomerization dewax base oil and solvent refining base oil are conducted, and problems in the applications of hydroisomerization dewax base oil are discusse

对加氢异构脱蜡基础油与溶剂精制基础油的性能进行了对比,讨论了加氢异构脱蜡基础油在应用中所存在的问题。

The main gluconeogenic precursor in kidney is thought to be lactate; however, less is emphasized enantiomerically. L-lactate is a glycolysis end-product, but D-lactate is formed after detoxification of methylglyoxal, which is the main source of advanced glycation end-products.

乳酸为肾脏糖质新生的主要来源,其含有一不对称碳,故具有D-、L-乳酸两种镜相异构物,而D-、L-乳酸两者之生成相当不同,L-乳酸是糖解作用之终产物,D-乳酸为体内一醣化终产物(advanced glycation end-products)─甲基乙二醛进行去毒化反应所生成,目前缺乏对乳酸镜像异构物与肾脏糖质新生间相关的探讨。

According to the evaluate and the sift through light paraffine isomerization catalyst,It showsthat preparated Pt-SO_4~(2-)/ZrO_2-Al_2O_3 catalyst achieved superior activity under the condition thatthe calcination temperature is 650°C、 concengtration of SO_4~(2-) is 0.5mol/L、 the content ofAl_2O_3 is 30% and content of Pt is 5%.

通过对轻质烷烃异构化催化剂的评价与筛选,表明所制备的 Pt-SO_4~(2-)/ZrO_2-Al_2O_3 催化剂在焙烧温度为 650°C 、SO_4~(2-)浓度为 0.5mol/L、第二金属氧化物组分 Al_2O_3含量为 30%,金属 Pt 含量为 0.3%时,该催化剂用于异构化反应效果最佳。

The law of thermo isomeric changes of the pimaric,ellioti pimaric, levopimaric,longifolic,dehydropimaric,abietic and neoabietic acids in the oleoresin of Pinus elliottii were studied in a comparison with those of resin acids in the oleoresin of Pinus massoniana .

本文研究湿地松松脂中海松酸、湿地松酸、左旋海松酸、长叶松酸、去氢枞酸、枞酸、新枞酸受热异构变化规律,并与马尾松松脂中的树脂酸热异构变化进行对比,为湿地松松脂的生产提供理论依据。

Diltiazem is an important coronary vasodilating drug and contains two chiral centers while only the (2S, 3S)-isomer has the desired activity.

地尔硫卓是重要的心血管药物,在其分子结构中含有2个手性中心,可产生4个立体异构体,其中只有(2S, 3S)-异构体具有药理活性,因此其立体选择性合成具有很大的挑战性。

This requirement may be satisfied by the submission of information such as the following: name (generic name, chemical name, code number); Chemical Abstracts Service number if available; description (e.g., appearance, color, physical state); molecular formula and molecular weight; structural formula (including ionic state if applicable); stereochemistry identifying chiral centers, cis-trans isomerism, etc.

该要求可以通过提供下述信息来满足:名称(通用名、化学名、编码等)、化学摘要服务编码、性状描述(如:外观、颜色、物理状态)、分子式和分子重量、结构式、立体化学(找出手性中心、顺式反式异性等)、对映结构体比率(如:外消旋物、规定的异构体、对映异构物和固态形式的混合物)、溶解度概况、分配系数、溶液 pH 值、解离常数、熔点或沸点、折射率、比重。

This requirement may be satisfied by the submission of information such as the following: name (generic name, chemical name, code number ); Chemical Abstracts Service number if available; description (e.g., appearance, color, physical state ); molecular formula and molecular weight; structural formula (including ionic state if applicable ); stereochemistry identifying chiral centers, cis-trans isomerism, etc.

有的话、描述(如:外观、颜色、物理状态)、分子式和分子重量、结构式、立体化学(找出手性中心、顺式贯穿异性等)、对映结构体或固态形式比率(如:外消旋物、规定的异构体、对映异构物和固态形式的混合物)、溶解性档案、分隔系数、溶液pH值、解离常数、熔点和沸点、拆射率、精确重力。

The order of relative stability of the PCPX congeners was theoretically proposed based on the relative magnitude of their Δf .

根据异构体标准生成自由能的相对大小,从理论上求得异构体的相对稳定性。

Thirdly, the acrylic rosin was synthesized by the addition reaction from gum rosin andacrylic acid. The levo-pimaric acid was converted into acrylic pimarie acid throughDiels-Alder addition with acrylic acid. The abietic-type acids in the gum rosin were inisomerization balance under high temperature, and the abietic acid and palstric acid would beconverted into levo-pimaric acid and reacted in the later type.

第三,通过脂松香与丙烯酸加成合成了丙烯酸松香,该反应是左旋海松酸与丙烯酸发生Diels-Alder加成反应生成丙烯海松酸,由于脂松香中的枞酸型树脂酸在高温下处于异构化平衡状态,因此随着反应的进行枞酸、长叶松酸等会异构化为左旋海松酸参与反应。

Adduct G is isomerized by F. The isomerization energies are relatively high (in the gas phase: 244.77 kJ/mol; in solvent of water: 234.83 kJ/mol), which is consistent with the experiment that adduct F is the primary alkylation product.

加合物G由F异构形成,且有相对高的异构化能(气相:244.77 kJ/mol;水溶剂中:234.83 kJ/mol),这与实验上得到加合物G是主要癌变物的结果一致。

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