异构体

The results showed that the dithione R is the most stable tautomer of all the tautomers in the form of isolated or hydrated isomers.

计算结果表明，2，6-二巯基嘌吟无论是孤立分子还是一水合物，其二硫酮式R是最稳定异构体。

Based on density functional theory and electronegativity equalization principle,applying an atom-bond electronegativity equalization σπ model,using a separated program,we calculated the charge distributions and dipole moments of guanine tautomers.

以密度泛函和电负性均衡原理为基础发展的原子-键电负性均衡方法的σπ模型。并结合自编程序，计算了鸟嘌呤五种异构体的电荷分布和偶极矩，计算结果表明，所计算出的电荷分布可以和从头算结果很好地关联。所计算的偶极矩与其它从头计算方法和力场方法相比总体趋势相同，进一步说明了ABEEMσπ模型的合理性

Results:The four stereoisomers of soman were well separated by the chiral capillary gas chromatographic column.

真正能实现梭曼 4个异构体分离测定的是手性毛细管柱的气相色谱或气质联用法。

A sensitive and credible gas chromatographic method for analysis of soman stereoisomers was established to observe its elimination in blood of rabbit after intoxicated with soman via vein.

建立梭曼手性异构体气相色谱分析方法以研究兔静脉染毒后血中游离梭曼的消除过程。

It should be emphasized that the manufacturing process is responsible for producing particular polymorphs or solvates; the control methods merely determine the outcome.

应该强调的是，生产工艺对生产特定的同质多形异构体或溶剂化物是直接相关的。控制方法只是决定结果。

Synthesis of such compounds from nonchiral materials results in equal numbers of the enantiomers, racemates.

使用非手性物料合成此类化合物导致等量的对映异构体和外消旋物。

In recent years, optically active polymers have attracted much attention because of their unique functions such as molecular recognition, optical resolution for racemates and catalytic activity in asymmetric transformations as well.

近年来，光学活性聚合物的合成与结构—性能研究深受国内外学者的高度关注，这是由于这些合成材料具有潜在的应用前景，如：光学活性聚合物可应用于外消旋混合物的对映异构体分离，即光学拆分过程；不对称吸附、手性诱导及许多有机化学反应过程中的不对称催化。

It should be emphasized that the manufacturing process is responsible for producing particular polymorphs or solates; the control methods merely determine the outcome.

应该强调的是，生产工艺对生产特定的同质多形异构体或溶剂化物是直接相关的。

Determination of Tyrosine in Urine Spectrophotometric Method;2. For chemical pre-extraction, MSTFA/TMSL derivatization reaction, GC/MS analysis, it is confirmed that two main metabolites (19-no-randrosterone and 19-noretiocholanolone) were found in nandrolone urine.

本文对合成的19-去甲雄烷醇酮的四个差向异构体混合物进行气相色谱分离，对诺龙和炔诺酮用药后，留取的人尿样通过化学预处理，MSTFA/TMSI衍生化反应，GC/MS分析，确证了尿样中诺龙的两个主要代谢产物为19-去甲雄酮和19-去甲原胆烷醇酮，炔诺酮的两个主要代谢物是四氢炔诺酮的两个形式，可能是3α-OH-5α-THINE和3α-OH-5β-THINE，在炔诺酮代谢前期，还发现有诺龙的上述两个代谢物存在。

However, there is little work reported on the separation ofα-olefins and other internal olefins.

对于不同烯烃之间的分离，特别是沸点相近的同分异构体烯烃之间的分离，国内外报道均不多。

With Death guitarist Schuldiner adopting vocal duties, the band made a major impact on the scene.

随着死亡的吉他手Schuldiner接受主唱的职务，乐队在现实中树立了重要的影响。

But he could still end up breakfasting on Swiss-government issue muesli because all six are accused of nicking around 45 million pounds they should have paid to FIFA.

不过他最后仍有可能沦为瑞士政府&议事餐桌&上的一道早餐，因为这所有六个人都被指控把本应支付给国际足联的大约4500万英镑骗了个精光。