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The catalyst also showed very good activity to the isomerization of n-pentane and esterification of phthalic anhydride with butanol.

用正戊烷的异构化反应和苯酐/正丁醇酯化反应作为探针,考察了SO〓/Zr—HMS的催化性能。

The studies of the electronic structure of small-saturated hydrocarbon molecules have received much interest, this is because these molecules are prototypes of larger hydrocarbons. In thesis, the structure of the isobutane and cyclopentane were studied by using Hartree-Fock and density function theory with the Gauss basis set, the experimental ionized energy data of the isobutane were analyzed.

有机分子结构的研究是复杂有机系统研究的基础,论文用Hartree-Fock方法和密度泛函理论研究了异丁烷和环戊烷分子的电子结构,并对异丁烷分子的实验电离能谱进行了分析。

Secondly, comparative experiments were carried out in different phase regions to probe the influence of pressure and the phase behavior of the mixed solvents on the tautomerism.

将紫外光谱及热力学方法相结合,测定了CO〓+乙醇、CO〓+正戊烷混合流体中EAA的异构化平衡常数,研究了超临界区、临界区和亚临界区EAA的异构化平衡常数随压力等因素的变化规律。

CH3OH could attack the phosphor atom in 1,3,2-dioxaphopholane of compiound (1) to give O-methyl O-hydroxyethyl-O-phthalimidoethyl thiophosphate in 85% yield; in the presence of potassium hydroxide aryl selenol could attack the carbon atom in 1,3,2-diox-aphopholane of the cyclic phospholipid conjugate of N^1-(2-furanidyl)-N^3--5-fluorouracil to give the corresponding product of ring-opening in high yields.

在室温下,以异丙醇作溶剂,苯硒酚与化合物2不反应。在氢氧化钾存在下,以异丙醇/水作溶剂(体积比20:1,在室温下,硒酚可以有效地进攻中化合物2中1,3,2-二氧磷杂环戊烷中的碳原子生成相应的开环产物。按照这一反应条件,顺利实现了硒酚对N^1-(2-呋喃基)-N^3-羟烷基-5-氟脲嘧啶硫代环甘油磷脂缀合物的亲核开环,生成甘油骨架的端碳原子上带有芳硒基新颖的磷脂核苷缀合物。

The biomarkers such as the n-Alkanes, the isoprenoids, the terpane, and cholestane were detected through GC-MS analysis. Based on the study of the biomarkers, the biological evolution during Permian and Triassic can be divided as three stages, namely, the mixing source stage of low biota such as thallose and advanced plant in late Permian (below bed 63), the stage of low biota such as thallose in the boundary transitional layer (bed 63-69) and the mixing source stage of advanced plant and low biota such as thallose in early Triassic (above bed 69). What's more, the second stage near the boundary transitional layer can be subdivided into 4 stages. The stages of biota evolution is close related with sedimentary environment changing and the boundary transitional layer.

利用GC—MS分析技术,在陆相地层中检测出正构烷烃、类异戊二烯烷烃、萜烷和甾烷类生物标志化合物并根据生物标志化合物和特征值研究,将二叠系—三叠系生物演化划分为三个大的阶段,即晚二叠世的菌藻类低等生物与高等植物混源阶段(63层以下),界线异常层的菌藻类低等生物阶段(63-69层)和早三叠世高等植物与菌藻类低等生物混源阶段(69层以上),界线附近异常层的第二阶段又进一步细分为4个次一级阶段,生物演化阶段与沉积环境变化及界线异常层具有非常密切关系。

The leftover from bamboo processing was comminuted into bamboo fine powder, which was surface-treaded with a coupling agent of ethenyl tri (β-methoxyethoxy) silane; and then in the presence of initiator dicumyl peroxide, the powder was compounded with styrene-isoprene block copolymer/bromobutyl rubber blend to prepare a crosslinked vibration-absorbing rubber composite material.

将竹加工的边角料粉碎并用乙烯基三硅烷偶联剂处理,再与苯乙烯-异戊二烯嵌段共聚物和溴化丁基橡胶的共混物进行复合,在过氧化二异丙苯引发剂的作用下制得交联型橡胶吸振复合材料。

METHODS: In fed rats, the effects of pentobarbital,isoflurane, sevoflurane, ketamine-medetomidine-atropine, and sufentanil-propofol-morphine on the cardiaccellular localization of hexokinase and levels of plasmaglucose and insulin were determined and compared with valuesobtained in nonanesthetized animals.

测定戊巴比妥、异氟烷、七氟烷、氯胺酮-美托咪定-阿托品和苏芬太尼-丙泊酚-吗啡麻醉下人工饲养大鼠心肌细胞己糖激酶定位和血浆葡萄糖及胰岛素浓度,并将之与未麻醉大鼠的对应参数作对比。

Hydroesterification of tert-butyl alcohol with ethanol catalyzed by transition metal triphenylphosphine complexes were investigated in room temperature ionic liquids as reaction medium at 100-140℃ and 3-6MPa of CO.

首次在超强酸氯铝酸离子液体中实现了饱和烷烃的羰化反应。发现2,2,4-三甲基戊烷可直接与CO反应,产物叔丁基异丁基酮,叔丁基异丁烯基酮和3,3,5-三甲基环己酮。

Geometries and energies of various low-energy conformers of the stereoisomers of 2,2,4, 4-tetrachloropentane and 2,2,4,4,6,6-hexachloroheptane were determined at the MP2 level with a 6-311++G** basis set.

在MP2/6-311++G**水平下,对2,2,4,4-四氯戊烷与2,2,4,4,6,6-六氯庚烷旋转异构体构象进行几何优化和能量计算。

Ethane> toluene>1, 3, 5-trimethylbenzene>methyl isobutyl ketone>1, 4-Dioxane>isoprene> 1, 2, 4-trimethylbenzene>cyclohexane>1, 3-Butadiene>methyl butyl ketone were the most reactive VOC species in PRD.

化学活性排名前十位的化合物为:乙烯>甲苯>1,3,5-三甲苯>甲基异丁基酮>1,4-环氧乙烷>异戊二烯>1,2,4-三甲苯>环己烷>1,3-丁二烯>甲基丁基酮。

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