异戊烷

Linear solvation energy relation was firstly introduced in the paper, and the method and step of gaining the special parameters of solvent and solute were introduced in detail, and these special parameters were used to selection and optimization of extractive agent in extractive distillation. The model of predicting activity coefficient at infinite dilution was established by linear solvation energy relation. By the above theory, several candidate solvents were selected to separate C5 fraction, and by experiment of vapor-liquid phase equilibrium at atmosphere pressure, the mixture of N-methyl-pyrrolidone including 4% water was used extractive agent of separating C5 fraction. Then binary vapor-liquid phase equilibrium of the some compound in C5 fraction and N-methyl-pyrolidone were determined at atmosphere pressure and correlated by NRTL equation. Isoprene being objective compound, experiments were operated in the laboratory-scale column; the processes were simulated by RadFrac model in ASPEN PLUS. And by the combination of experiment and simulation, the new process of separation of C5 was established.

本文首先对线性溶剂化能关系进行了分析介绍，也介绍了采用溶剂化能关系得到溶质溶剂特性参数的方法步骤，并将这些参数用于萃取精馏萃取剂的选择与优化；也通过线性溶剂化能关系式建立无限稀释活度系数预测模型，取得了一定的预测精度；将通过上述方法初选的溶剂进行了常压汽液平衡的测定研究，通过实验研究选定含水4%的N-甲基吡咯烷酮溶液做为C5分离的萃取剂，测定了大量N-甲基吡咯烷酮与C5组分的二元平衡数据，并进行关联计算；以异戊二烯为目标产物在实验室规模的精馏塔内进行了C5分离的实验研究，取得大量塔内数据；通过选用合适的热力学模型，采用ASPEN中RadFrac模块对分离过程进行模拟研究，通过实验与模拟相结合，建立了C5分离的新工艺，为将来的工业化打下了坚实的基础。

For 2,2,4,4-tetrachloropentane,the energy of the conformer with gauche-gauche arrangement is lower; For 2,2,4,4,6,6-hexachloroheptane,the conformer with trans-gauche-trans-gauche arrangement is stable.

结果表明，对于2，2，4，4-四氯戊烷，采用gauche-gauche排列的旋转异构体的能量较低；2，2，4，4，6，6-六氯庚烷旋转异构体中，采用trans-gauche-trans-gauche排列的构象能量较低。

Results:Isoprene was significantly higher in the breath of schizophrenias than that in the control groups.

结果 ：精神分裂症组呼出气体中的异戊二烯高于情感性精神障碍组和正常对照组，但是并没有检测出戊烷和二硫化碳。

Objective:To describe a method for the determination of pentane,isoprene and carbon disulifide in human breath,which was useful in study of schizophrenia.

目的 ：检测呼出气体中的戊烷、异戊二烯和二硫化碳，为精神分裂症进行呼吸试验研究提供方法学依据。

Addition of small amount of inert solution, such as, pentane and isooctane, to the bulk polymerization system is helpful to remove the reaction heat.

向本体聚合体系中加入少量溶剂如戊烷、异辛烷有助于改善这一问题，使反应平稳地进行。

Such as pentane there are three isomers, Wang alkyl has 35, while containing 30 carbon atoms, the number of isomers of alkanes up to 411 × 109 Ge.

例如戊烷的异构体有3个，王烷有35个，而含30个碳原子的烷烃的异构体数目高达411×109个。

In comparison with the organic solvents as reaction medium, higher conversion was achieved the tert-ethyl valerate could be formed in the ionic liquid medium.

当反应体系中存在水时，有特戊酸生成。表明反应中2，2，4-三甲基戊烷首先发生β-断裂反应，生成叔丁基正碳离子和异丁烯。

To establish a method for determination of cyclopentadiene,dimethylformamide and N-methylpyrrolidone simultaneously in isoprene by GC.

用毛细色谱法建立异戊二烯中各组分定性分析方法及环戊二烯，N-甲基吡咯烷酮，N，N-二甲基甲酰胺的测定方法。

Breath Tests ; Schizophrenia ; Gas Chromatography-mass Spectrometry ; Pentene ; Isoprene ; Carbon Disulifide

呼吸试验；精神分裂症；气相色谱-质谱；戊烷；异戊二烯；二硫化碳

The esterification reaction was carried out in isooctane solvent at 50℃, with 0.15mol/L of substrate and 1:1.4 of acid-alcohol molar ratio.

研究了反应温度、溶剂、底物浓度、底物摩尔比、吸水剂用量等因素对酯化反应的影响，确定了正戊酸异戊酯的最佳合成条件为：反应温度为50℃，异辛烷为反应介质，底物浓度为0.15mol/L，酸醇摩尔比为1：1.4。

Do you know, i need you to come back

你知道吗，我需要你回来

Yang yinshu、Wang xiangsheng、Li decang,The first discovery of haemaphysalis conicinna.

1〕 杨银书，王祥生，李德昌。安徽省首次发现嗜群血蜱。