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异戊烯

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With a little judicious searching, Amyris thinks it has come up with isoprenoids that have the right characteristics to substitute for petrol.

阿米瑞斯公司认为,只要通过一番去伪存真,就会得到能够取代汽油的类异戊二烯。

The main results and conclusions are as follows:The trans-1,4 content of polybutadiene increased from 50%to 89%along with the increasing of Al/Li ratio;the trans-1,4 content of polyisoprene increased from 24%to 46%as well as 3,4 content along with the increasing of Al/Li ratio;the microstructure of polystyrene was invariable and atactic.

主要研究结果及结论如下:随着Al/Li的增加,聚丁二烯的反式结构含量从50%增加到89%;聚异戊二烯的反式-1,4-结构含量从24%增加到46%,并且其3,4结构含量也有所增加;聚苯乙烯的微观结构基本没有变化,为无规聚苯乙烯。

The main results and conclusions are as follows:The trans-1,4 content of polybutadiene increased from 50%to 89%along with the increasing of Al/Li ratio;the trans-1,4 content of polyisoprene increased from 24%to 46%as well as 3,4 content along with the increasing of Al/Li ratio;the microstructure of polystyrene was invariable and atactic.

加热器主要研究结果及结论如下:随着Al/L i的增加,聚丁二烯的反式结构含量从50%增加到89%;聚异戊二烯的反式-1,4-结构含量从24%增加到46%,并且其3,4结构含量也有所增加;聚苯乙烯的微观结构基本没有变化,为无规聚苯乙烯。

The biomarkers such as the n-Alkanes, the isoprenoids, the terpane, and cholestane were detected through GC-MS analysis. Based on the study of the biomarkers, the biological evolution during Permian and Triassic can be divided as three stages, namely, the mixing source stage of low biota such as thallose and advanced plant in late Permian (below bed 63), the stage of low biota such as thallose in the boundary transitional layer (bed 63-69) and the mixing source stage of advanced plant and low biota such as thallose in early Triassic (above bed 69). What's more, the second stage near the boundary transitional layer can be subdivided into 4 stages. The stages of biota evolution is close related with sedimentary environment changing and the boundary transitional layer.

利用GC—MS分析技术,在陆相地层中检测出正构烷烃、类异戊二烯烷烃、萜烷和甾烷类生物标志化合物并根据生物标志化合物和特征值研究,将二叠系—三叠系生物演化划分为三个大的阶段,即晚二叠世的菌藻类低等生物与高等植物混源阶段(63层以下),界线异常层的菌藻类低等生物阶段(63-69层)和早三叠世高等植物与菌藻类低等生物混源阶段(69层以上),界线附近异常层的第二阶段又进一步细分为4个次一级阶段,生物演化阶段与沉积环境变化及界线异常层具有非常密切关系。

Firstly, dicyclopentyldichlorosilane, a reaction intermediate, was prepared under the optimal conditions of a reaction pressure range of 1.0-1.2 MPa, a n/n of 1.16, a reaction temperature range of 85-95℃, a catalyst dosage of 1.2 g, an isooctyl alcohol dosage of 2.3 g and a reaction time range of 6-7 h. The conversion of cyclopentene and the yield of DCPDCS were 96.2% and 88.9%, respectively.

首先研究了合成DCPDCS的最佳工艺条件:反应压力1.0~1.2 MPa,n/n= 1.16/1.00,反应温度85~95 C,催化剂用量1.2 g,异辛醇用量2.3 g,反应时间6~7 h,环戊烯转化率可达96%以上,DCPDCS收率可达88%以上。

The poisoning effects of alkyl sulfur compounds on the reactivity of isoprene hydrogenation over supported Pd catalyst are more and more serious with the decrease of the molecular mass of alkyl thiols and dialkyl disulfides.

乙硫醇和二甲基二硫醚使Pd/树脂催化剂中毒的机理是,它们分别在催化剂上发生SH和S-S键断裂,并与Pd形成带烷基基团的S-Pd吸附络合物,致使催化剂上异戊二烯选择加氢活性降低。

The p-Isopropylbenzoic acid was synthesized by catalytic transfer dehydrogenation with 5% Pd/C using dihydrocumic acid as material and hydrogen offer, industrial dipentene as hydrogen acceptor and solvent, reacted directly under reflux condition.

采用5% Pd/C作为转移氢催化剂,原料二氢枯茗酸为氢给予剂,以工业双戊烯作为氢接受剂和溶剂,合成了对异丙基苯甲酸。

It was found that more branch-2 olefin and C5~C6 isoparaffin molecules existed in MIP naphtha. The cause of MIP naphtha having higher octane number and less octane loss during hydrotreating could be explained by the octane model of C6 hydrocarbons quantitatively.

通过对MIP和FCC汽油组成分析,发现MIP汽油组成含有较多的多支链烯烃、异戊烷和异己烷,基于碳六烃的辛烷值模型,可以定量地解释MIP汽油辛烷值高和加氢MIP汽油辛烷值损失低的原因。

The ozonolysis of isoprene has a significant contribution to atmospheric carbonyls, especially to formaldehyde and methylglyoxal.

异戊二烯臭氧氧化反应对大气羰基化合物特别是甲醛和丙酮醛具有重要贡献。

Some of the wild rubber, such as Malay gum, gutta percha, etc., its chemical composition To counter - polyisoprene, but little production.

某些野生橡胶如马来树胶、杜仲胶等,其化学成分为反-聚异戊二烯,但产量甚少。

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