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Covalent modification of four isolated alkannin derivatives (alkannin, acetylalkannin,β,β dimethylacrylalkannin and β acetoxyisovalerylalkannin, respectively) on rabbit muscle latate dehydrogenase and yeast Alcohol Dehydrogenase has been studied.

为研究紫草萘醌类化合物的细胞毒性作用机制,从新疆软紫草根中分离出四种紫草萘醌类化合物β,β二甲基丙烯酰阿卡宁(1),乙酰阿卡宁(2 ),β乙酰氧基异戊酰阿卡宁(3)和阿卡宁(4)。

The rate of formation of the four acyl-L-serine anilide was studied.

比较了四种酰基-丝氨酸的酰苯胺合成的速度。N-苯甲氧羰酰-L-丝氨酸酰苯胺最快;N-苯甲酰-,N-正己酰-其次;N-异戊酰-最慢。

Finally the reaction of isoprene with OH radical in the presence of NO x was discussed brieflly.

最后对NOx存在下的异戊二烯/OH自由基反应进行了简略讨论。

Studies on the reactions of isomerized products of butaduene and isoprene iron complexes with triphenyl phosphine and triphenyl phosphite

丁二烯-和异戊二烯二羰基铁配合物的异构化产物与三苯膦和亚磷酸三苯酯的反应研究

The biosynthesis of coenzyme Q10 in microorganism has two pathways: the quinoid nucleus biosynthesis and the isoprenoid side chain biosynthesis.

辅酶Q10在微生物体内的合成分为芳香环的合成和异戊烯基侧链的合成。

The auxiliary can be recovered in high yield (81%) only by filtering and recrystallization. Besides, some other aldehydes have been chosen to test the enantioselectivity of N,N\'-dibenzyl tartamide, in comparison with two other allylaborates reagents developed previously by Roush and Brown, respectively. The results show that %e.e. of homoallylic alcohol is superior to that of the former, and approaches the Brown reagent.

产物经S_N2反应得瑞格列萘中间体-甲基烯丙基-2-氯苯基-叠氮甲烷(17);同时,将筛选出的新型手性配体N-苄基酒石酸二酰胺用于其他几种醛(正丁醛,异戊醛和环己醛)的不对称烯丙基化反应,并与广泛应用的Roush配体(22)和Brown配体(27)相比较,发现其立体选择性优于Roush配体,并接近Brown配体,但明显具有可回收利用的优势。

Trifluoromethyl-3-heptadfluoroisopropyl-2-perfluoropentene-4-(N',N'-dimethylamino propyl) imino was prepared by the reaction of hexafluoropropene timer with N,N-dimethyl propanediamine in the molar ratio 1:1.0 at room temperature for 8h, and the structures of VIII were identified by IR and NMR spectra.

以六氟丙烯三聚体与N,N-二甲基丙二胺为原料合成叔胺2-三氟甲基-3-七氟异丙基-2-全氟戊烯-4-(N',N'-二甲胺丙基)亚胺,利用红外光谱和核磁共振确定其结构,并通过对合成条件的考察得其最佳合成条件:乙醚为溶剂,碳酸钠为缚酸剂,摩尔投料比为1:1.0,在室温下反应8小时。

The leftover from bamboo processing was comminuted into bamboo fine powder, which was surface-treaded with a coupling agent of ethenyl tri (β-methoxyethoxy) silane; and then in the presence of initiator dicumyl peroxide, the powder was compounded with styrene-isoprene block copolymer/bromobutyl rubber blend to prepare a crosslinked vibration-absorbing rubber composite material.

将竹加工的边角料粉碎并用乙烯基三硅烷偶联剂处理,再与苯乙烯-异戊二烯嵌段共聚物和溴化丁基橡胶的共混物进行复合,在过氧化二异丙苯引发剂的作用下制得交联型橡胶吸振复合材料。

The results indicated isoprene was soon consumed under the condition of excess ozone. During the reaction, the major carbonyl products formed were methyl vinyl ketone, methacrolein, methylglyoxal, and formaldehyde. Formic acid, CO and CO2 were also among the products.

在反应温度(294±2)K,压力为1.01×10^5Pa空气,O3过量的条件下,异戊二烯很快反应完全,反应中生成的羰基产物主要包括甲基丙烯醛、甲基乙烯基酮、丙酮醛和甲醛;产物中还包括甲酸、一氧化碳和二氧化碳。

Extracted DNA by CTAB, in proportion to the additions of PVP and β-mercap toethanol to the extraction buffer were capable of preventing browning from taking place in the extraction, Tris-Phenol (Stabilized with 0.1M Tris, pH 8.0)/Chloroform/isoamyl alcohol were used to remove protein and impurity in the second extraction, during crude DNA used to Isopropanol DNA and deterged by DNA detergent, without using RNase remove RNA, we detected the quality and concentration of DNA respectively for normal leaves and drought stress leaves by Agarose gel electrophoresis of genomic DNA and ultraviolet spectrometry photo.

用20%聚乙二醇(polyethylene glycol,PEG6000)模拟干旱,采取CTAB提取缓冲液,按一定比例加入PVP和β-巯基乙醇,用Tris平衡酚-氯仿-异戊醇除去蛋白质及杂质,在粗提时用异丙醇沉淀DNA,并用DNA洗液(10mmol/L醋酸铵,75%乙醇)洗涤DNA,在纯化时用乙醇沉淀DNA,且没有加入RNase去除RNA的方法,分别提取2个品种正常和干旱胁迫的苹果属叶片总DNA,并对提取的DNA进行琼脂糖凝胶电泳和紫外分光光度计检测。

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