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All the compounds are characterized by IR and elemental analysis.we design and prepare a bipyridinium supramolecular compound and six coordination compounds, which are also characterized by IR, elemental analysis and X-ray structure analysis. According to X-ray structure analysis, hydrogen bonds and n-n stocking interactions participate in the architecture of three-dimensional framework [H2L1 (NO3)2 (H2O)2]n; one-dimensional zigzag coordination polymer [Hgl21.5CH3OH]n; binuclear metallamacrocycle (HgI2L2)2 3H2O; helical double-stranded one-dimensional coordination polymer [Co2(L2)2-2CH3OH]n; double-stranded one-dimensional coordination polymer [Co2(L3)2-CH3OH-CH3CN]n; and three-dimensional compound [Cu(C5H4NCOO)2(H2O)2]-H2O with hydrogen bonds, three-dimensional coordination polymer {[Cd(C5H6NCOO)2H2O]-DMF}n, which are indirectly obtained from the precursor ligand L3 through metal ion induced the hydrolysis of diamide and self-assembled with the hydrolyzate.

我们首次合成了一个双吡啶鎓超分子化合物和六个过渡金属配合物,并通过IR谱,元素分析和X-ray晶体衍射分析对它们进行了表征。X-ray晶体结构分析表明:超分子化合物[H_2L1·(NO_3)_2·(H_2O)_2]_n是由多种氢键和芳香环间的π-π堆积作用构建的三维无限结构;[HgI_2(L1)·1.5CH_3OH]_n是一维锯齿状配位聚合物;(HgI_2L2)_2·3H_2O是双核金属大环化合物;[Co_2(L2)_2·2CH_3OH]_n是具有一维双螺旋结构的配位聚合物;[Co_2(L3)_2·CH_3OH·CH_3CN]_n为一维双链结构的配位聚合物;以及由非直线形配体L3在金属离子Cu和Cd的诱导作用下发生水解,并且金属离子与水解产物——异烟酸根离子自组装,形成了三维氢键超分子化合物[Cu(C_5H_4NCOO)_2(H_2O)_2]·H_2O和三维配位聚合物{[Cd(C_5H_6NCOO)_2H_2O]·DMF}_n。

The influence of each condition on the reaction speed and yield was studied, and the optimal conditions were: the ratio of the amount of substance of aromatic amine and heptafluoro-isopropyl iodine was 1:1.1~1.5, the amount of substance of sodium dithionite, sodium bicarbonate, aniline compounds were respectively 1.1~1.3, the amount of substance of phase transfer catalyst TBAB and aniline compounds was 0.05~0.1, the concentration of aniline compound was 0.5~1.0 mol/L, reaction temperature was 10~20 ℃, and the solvent was aether.

最佳结果为:芳胺与七氟异丙基碘的物质的量比1:1.1~1.5,连二亚硫酸钠、碳酸氢钠与苯胺的物质的量分别为1.1~1.3,相转移催化剂四丁基溴化铵与苯胺的物质的量比在0.05~0.1,溶剂总用量使苯胺浓度在0.5~1.0 mol/L;反应温度10~20℃;溶剂采用乙醚。取代基供电子性越强,反应时间越短,产率越高;氨基的对位优先反应,氨基的邻位较难发生反应;且七氟异丙基总是优先取代在芳环电子云密度较高的位置上。

On the same catalyst, the adsorption velocity and quantity between the isobutane and butene has great differences, which results in the very low isobutane/butene adsorption ratio in the micro-pore of the catalyst, especially at higher temperature.

利用原位红外对异丁烷和丁烯的吸附和反应历程研究结果表明,异丁烷和丁烯在催化剂不同活性位上的吸附反应过程差别很大。

For each data bit sent or received,the high order bit of the current remainder is XORed with the data bit and then the remainder is shifted left one bit and the low-order bit set to zero.

对于每个被发送或者被收到的数据位,当前余项的最高一位和数据位进行异或,然后,余项是左移1位,并且,最低一位置零。

A series of study methods which can not research in this field begin to exert important affection. On the basis of the previous research, the following major innovative work was carried out in this dissertation.(1) Several methods including fluorescence spectra, CD and FT-IR specta methods were used to study the interaction of isoquinoline alkaloid、isoflavones and Rhein with serum albumin, and the results from every method was in good agreement;(2) The binding constants、the numbers of binding site、the binding region and the interaction force involving in the interaction of drugs and serum albumin were confirmed by Scatchard equation and Vant Hoff equation.

基于研究生物大分子与小分子相互作用具有极其重要的意义,本博士论文在前人工作的基础上,主要进行了以下几方面的创新性研究:(1)利用荧光光谱法、圆二色谱法、红外光谱法以及分子模拟等多种方法相结合研究了异喹啉类生物碱,异黄酮类化合物以及大黄酸与人血清白蛋白的相互作用,获得了准确一致的信息;(2)根据Scatchard方程和Vant Hoff方程详细研究计算了异喹啉类生物碱以及大黄酸与蛋白质结合机理包括结合常数、结合位点数、结合区域、结合力。

The content of five free-anthraquinones (aloemodin, rhein, emodin, chrysophanol, physcion) in Alc95% active part were simultaneously determined by HPLC method.

其中7,3'-二羟基-5'-甲氧基异黄酮是自然界中罕见的B环为间位二取代的异黄酮类化合物,为新化合物。

For a disubstituted complex, MA4B2, the planar arrangement gives three isomers, the familiar ortho, meta, and para arrangement s of organic chemistry.

对于双取代络合物MA4B2,其平面排列有三个异构体,常见的为有机化学中的邻位、间位和对位排列。

For a disubstituted complex, MA4B2, the planar arrangement gives three isomers, the familiar ortho, meta, and para arrangements of organic chemistry.

对于双取代络合物 MA4B2,其平面排列有三个异构体,常见的为有机化学中的邻位、间位和对位排列。

The results showed that the shape selective effect of the faujasite is obvious, and the thermodynamic balance exists between 2,6 DTBN and 2,7 DTBN.

结果表明,八面沸石对该反应过程有较好的择形催化作用,两种异构化产物(2 ,6 二叔丁基萘和 2 ,7 二叔丁基萘)之间存在着热力学平衡,即两种异构化产物可在酸性中心位上相互转化。

In order to disclose the adaptive strategies and capacity of Potaninia mongolica Maxim, acquired during its evolution history, the whole response system, which was composed of individual morphology plasticity response, organs anatomy structure response, physiological function response of anti-arid and anti-hotness, activities of protective enzymes response, endogenous hormone adjustment response, sexual reproduction strategies response of seeding, dispreading, sprouting and renewing, asexual reproduction strategies response of clonal growth patterns, clonal growth architectures, clonal growth architectures plasticity, heterogeneous resources utilization strategies, endogenous hormone distribution in clonal organs, foraging behavior, risk-spreading, and resource sharing, individual density allocation patterns response, niche differentiation response, species connection response, allelopathy response and biodiversity components response of the plant was profoundly explored in this paper.The studies come to at least four important results:(1) Taking the sensitive response and evading strategy to adapt to environment stress, Potaninia mongolica Maxim is a successful species has lived through the long-term evolution. Nevertheless, it is narrow climate and soil niche and characteristic of vegetation reproduction which has made the plant a rare and endangered species.

本论文通过对绵刺环境胁迫下个体形态可塑性响应、器官解剖结构响应、抗旱性和抗热性生理功能响应、保护酶系统激活响应、内源激素调控响应,有性繁殖对策中结实、扩散、萌发、更新等生活史过程响应,无性繁殖对策中克隆生长格局响应、克隆生长构型响应、克隆生长构型可塑性响应、克隆生长构型与资源异质性响应、内源激素调控克隆生长构型响应、克隆器官结构与功能响应、觅食行为响应、风险分摊响应、资源共享响应,种群中格局配置响应、生态位分异响应,群落中种间关联、异株克生响应、生物多样性组成响应等内容进行研究,揭示绵刺在进化过程中的适应对策和适应能力,为绵刺保护提供理论依据。

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But we don't care about Battlegrounds.

但我们并不在乎沙场中的显露。

Ah! don't mention it, the butcher's shop is a horror.

啊!不用提了。提到肉,真是糟透了。

Tristan, I have nowhere to send this letter and no reason to believe you wish to receive it.

Tristan ,我不知道把这信寄到哪里,也不知道你是否想收到它。