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In conclusion, a catechol moiety is presumably to be essential for its activity and substitution of the p-hydroxybenzyl group at C-1 position with correct stereochemistry in the isoquinoline molecule makes a great contribution to the activation of beta adrenergic receptors.

本实验初步结果发现,对於去甲基乌药碱分子之药效,catechol基是必备无疑;而异喹啉环的碳-1位置上取代的p-hydroxybenzyl基对於药效有非常大的影响;至於其立体化学的配位是有立体选择性的。

In this study aldylencdithiomethylene Malonic acid acts as the main coordination agents and compound iron ion have been synthesized by the means of solution, As a result ,the 1D polymer is obtained.

本论文采用常规的溶液合成方法,首先设计合成了一个以含有二硫缩烯酮结构的丙二酸类配体和过渡金属铁离子的单核配合物,再以此单核配合物作为配体设计合成了三个异多核配合物和配位聚合物。

Another reaction of malonyl ginsenosides in red ginseng processing was decarboxyl...

在加工过程中达玛烷型人参皂苷主要发生20位糖苷键水解和异构化。

O-MNT、 p-MNT and m-MNT are got by mononitrating toluene, and the quantity of p-MNT and m-MNT that are needed is increased greatly, there is a great economic benefit to improve their ratioes , so the objective of this study is to improve the ratioes of p-MNT and m-MNT in the mononitration of toluene respectively through changing temperature and mixed acid composition in industrial way.

甲苯一硝化生成邻硝基甲苯、对硝基甲苯、间硝基甲苯,其中对硝基甲苯和间硝基甲苯的用量明显增加,提高它们在产物中比例的研究,具有十分可观的经济价值,所以本文从工业化的角度出发,通过改变温度和硝硫混酸的组成,分别对提高一硝基甲苯中对、间位异构体的比例进行研究。

The optimum reaction conditions were: at present of acetic anhydride, a stoichiometric quantity of nitric acid, at room temperature for 40 minutes. Nitration of chlorobenzene gave a,50% yield of mononitro compounds, and an ortho-para isomer ratio 0.20 in product distribution of chlorobenzene mononitration.

结果表明:硅钨酸催化性能较好,催化剂载体以纳米二氧化硅最好,反应条件中醋酸酐用量是主要影响因素;SiW_(12)O_(40)~(4-)/纳米SiO_2催化剂具有强对位选择性:在醋酸酐存在下,氯苯与等当量的硝酸室温下反应40分钟,氯苯一硝化产物中邻/对硝基氯苯异构体的质量比达0.2,产率可达50%。

In the paper, the multidentate carboxylic acid ligands were used to combine with Cd, resulting in the three dimensional MOCPs single crystals—C12H16CdN2O8, with a low temperature hydrothermal synthesis method. The sample was characterized with IR spectra to affirm the organic groups in the frameworks, single-crystal X-ray diffraction to determine the crystal structure and composition of the frameworks, N2 adsorption isotherms at low temperature to measure the specific surface area and pore size distribution, and with TGA/DGA analysis to scale the thermal stability. Furthermore, the dissolution property and the photocatalytic activity of MOCPs under the ultraviolet ray condition were explored.

本文用低温水热合成法,用多齿羧酸配体异烟酸和Cd配位合成出[Cd(C6H4O2N)2(H2O)4]∞三维晶体并进行了表征:采用红外光谱法确认骨架中的有机官能团;用单晶X射线衍射分析法测定MOCPs的晶体结构,并确定其骨架的组成;通过低温氮气吸附等温线测定了其比表面积和孔径分布;以热重分析和差热分析测定材料骨架的热稳定性;测定了晶体的溶解性能;最后以亚甲基蓝为目标降解物,对[Cd(C6H4O2N)2(H2O)4]∞的光催化活性及亚甲基蓝的氧化动力学进行了探索(来源:A2444BC论文网www.abclunwen.com)。

Nevertheless, the yield of pinacol was also strongly affected by the steric environment surrounding the carbonyl group. The pinacol coupling of aromatic aldehydes has been achieved with high yields under such a condition. However, the diastereose-lectivities of pinacols were not satisfying. Unfortunately, the ketones and most aliphatic aldehydes appeared inert under the same reaction conditions.

然而, 呐偶合反应的产率受到羰基周围环境的立体位阻影响较大,在此条件下,锌粉能有效地促进芳香族醛类化合物进行水相呐偶合反应,得到的呐醇产率高,但非对映异构体选择性差,而脂肪族醛类化合物得到的呐醇产率较低,在同样的条件下,酮类化合物不能顺利进行呐偶合反应。

Long {{IPA|}} and {{IPA|}} occur as allophones of {{IPA|/e/}} and {{IPA|/u, o/}} respectively before a following vowel:''waian''{{IPA|}}"to blow"(Dutch ''waaien'', German ''wehen''),''bauan''{{IPA|}}"to build"(Dutch ''bouwen'', German " bauen ", Swedish ''bo''"live"), also in Greek words ''Trauada''"Troad"( Gk.{{Polytonic|Τρ}}).

长的{{IPA|}}和{{IPA|}}在一个母音前面时,分别为{{IPA|/e/}}和{{IPA|/u, o/}}的同位异音,如''waian''({{IPA|}},意即「吹气,对应到荷兰语的''waaien''和德语的''wehen'')、''bauan''({{IPA|}},意即「建造」,对应到荷兰语的''bouwen''、德语的'' bauen ''和瑞典语转意为「生活」的字''bo'')等,在希腊语借词中亦是如此,如''Trauada''意即「特罗得(Troad」,希腊语作{{Polytonic|Τρ}}。

The mantle shear zone formed at lithospheric extensional setting of Meso-Tethys and reworked by serpentinization, cataclasis, and compressional deformation including deformed lens such as ophiolite, gabbro, and chronite, thrust faults, and folds produced during closure of the Meso-Tethys.

在南北向挤压导致海盆消亡的早期阶段,处于深层侵位环境的地幔橄榄岩由于物性的不均一性,变形分解作用产生不同尺度的透镜网络,如蛇绿岩体、辉长岩脉、纯橄岩异离体、豆荚状铬铁矿体、眼球状橄榄石、辉石残斑晶等。

Besides, my mother is able to foresee things which surprise the others and thus she is called a "spiritualistic" woman. I was also moved by her story of the hard times before liberation.

母亲对许多事情都有着异于常人的预见性,显示出未卜先知的异质禀赋,大家每每在惊奇之余,把母亲称为是一位&通神&之人。

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The split between the two groups can hardly be papered over.

这两个团体间的分歧难以掩饰。

This approach not only encourages a greater number of responses, but minimizes the likelihood of stale groupthink.

这种做法不仅鼓励了更多的反应,而且减少跟风的可能性。

The new PS20 solar power tower collected sunlight through mirrors known as "heliostats" to produce steam that is converted into electricity by a turbine in Sanlucar la Mayor, Spain, Wednesday.

聚光:照片上是建在西班牙桑路卡拉马尤城的一座新型PS20塔式太阳能电站。被称为&日光反射装置&的镜子将太阳光反射到主塔,然后用聚集的热量产生蒸汽进而通过涡轮机转化为电力