异位

The result is: out of 187 cases of azoospermia, 77(41.18%)patients with abnormal chromosome(number and structural aberration); heteromorphic chromosome(Y chromosome polymorphisms and pericentric inversion of 9) and 46,XX sex reversal. Out of 30 cases of severe oligospermia, 4 patients with abnormal chromosome(structural aberration and 46,XX sex reversal).

发现187例无精症患者中检出异常核型77例（41.18%）（其中46，XY，t(6；14)(p21；p13)，46，XY，t(8；12)(p21；q24)为世界首报核型），主要涉及染色体异常；染色体异态（Y染色体异态和9号染色体臂间倒位）及46，XX性反转；30例严重少精症患者中检出异常核型4例（13.33%）（结构异常和46，XX性反转）。

On the same catalyst, the adsorption velocity and quantity between the isobutane and butene has great differences, which results in the very low isobutane/butene adsorption ratio in the micro-pore of the catalyst, especially at higher temperature.

利用原位红外对异丁烷和丁烯的吸附和反应历程研究结果表明，异丁烷和丁烯在催化剂不同活性位上的吸附反应过程差别很大。

For Nitro derivatives of methylbenzenes, the pyrolysis initial reaction is an isomerization reaction. It means the alpha C-H bond in methyl rupture, then the Hydrogen atom transfer to the Oxygen atom in nitryl to form isomer.

甲苯的硝基衍生物的热解引发反应为异构化反应——α_中的C-H键断裂，氢原子转移到邻位硝基(-NO_2)中的氧原子上，生成新的异构体化合物。

Nitro derivatives of phenols, the pyrolysis initial reaction is an isomerization reaction It meansthe O-H bond in hydroxide rupture, then the Hydrogen atom transfer to the Oxygen atom in nitryl to form isomer.

苯酚的硝基衍生物的热解引发反应为异构化反应——酚羟基中的氢氧键断裂，氢原子迁移到邻位硝基(-NO_2)中的氧原子上，形成新的异构体化合物。

In chapter 6, seven pairs of diastereoisomers of podophyllum lignans at C4-position, including three pairs of spin labeled compounds, were separated by MEKC with 20mM sodium tetraborate-30mM SDS-10％ 2-propanol (pH=9.5-9.7) within 20min.

第六章：首次利用胶束电动毛细管色谱分离了七对抗癌药物鬼臼类木脂素在C4位的差向异构体，该方法可用来鉴定分析物的纯度、确定自旋标记化合物C4-H的构型等，为研究差向异构体不同的抗癌机制提供检测手段。

Three heteronuclear uranyl complexes were obtained via hydrothermal reaction, too.

另外，在水热条件下，还利用这些芳香有机酸合成了三个铀的异核金属配位聚合物，这为铀的异核金属配合物家族增添了新的成员。

For a disubstituted complex, MA4B2, the planar arrangement gives three isomers, the familiar ortho, meta, and para arrangements of organic chemistry.

对于双取代络合物 MA4B2，其平面排列有三个异构体，常见的为有机化学中的邻位、间位和对位排列。

They are:In the third chapter, the crystal structures of these new dca complexes are described anddiscussed in detail. Besides two mononuclear complexes, 1 and 2, complexes 3～15 arecoordination polymer with novel and interesting structural characteristics. 3, 6, 7, 8, 9 are 1Dpolymers, 4 and 5 are of 2D extending structure, while 10, 11, 12, 13, 14, 15, 16, 17 form thefirstly reported series heteronuclear dca coordination polymer, in which (except 10) differentbuilding blocks, with different metal ions in them, construct interesting architecture, like α-and β-type 〓 chains, ladder chain 〓, scaffold structure of 12, and "sandwich"layer structure in 15 and 16, etc..

这些配合物是：第三章中，我们详细描述讨论了这些新型的二氰胺配合物的晶体结构，除两个单核配合物1和2之外，其余十五个为配位聚合物并具有新颖和有趣的结构特征。3，6，7，8，9是一维配位聚合物，4和5则呈现二维扩展结构，而10，11，12，13，14，15，16，17属于首次报道的一系列的二氰胺异金属配位聚合物，其中(除10外)含有不同金属离子的构造&砌块&可构建出有趣的结构，如α-和β-型〓链，梯形链〓，12中的脚手架结构，以及15和16中的&三明治&层状结构等。

The results are following:(1)We investigated the influence of the positional isomeric effect on structures.Due to the less space-crowding,it is easier for 3-pytpy to behave as bridging ligand than 2-pytpy under the same reaction conditions,while,it is easier for 2-pytpy to function as tridentate chelating ligand to construct supramolecular structures.

研究结果如下：(1)研究了两个吡啶取代三联吡啶配体的位置异构效应对配合物结构的影响。3-pytpy配体比2-pytpy具有更小的空间位阻，在相同的合成条件下容易以单-三齿桥联方式配位；而2-pytpy更易以三齿螯合形式配位，通过π…π堆积作用形成超分子结构。

The central 5, 5'-disubstituted bipyridine units of each ligand coordinate theNi or Fe ion, while all the terminal 6-monosubstituted bipyridine units of the ligands keep free of coordination, as the result trinuclear triple-stranded helicate 〓 can not form. This is considered to be caused by the steric hindrance of the methylene substituents α to the chelating nitrogens of the terminal bipyridine units and the strain caused by linkage mode.

配体L〓与Ag作用得到〓，两个配体链相互缠绕着两个Ag离子周围形成双股螺旋结构并以头尾式排列(见图3)，由于配体中位于配位N原子α或β位的末端甲基或次甲基取代基的空间位阻阻碍了头对头式异构体的形成，也正是由于配体头尾式排列而使Ag双股螺旋得以形成，这一结果表明该螺旋体的组装过程中自发地采取了空间阻碍尽可能小的那个构型。

But we don't care about Battlegrounds.

但我们并不在乎沙场中的显露。

Ah! don't mention it, the butcher's shop is a horror.

啊！不用提了。提到肉，真是糟透了。