异位

All the compounds are characterized by IR and elemental analysis.we design and prepare a bipyridinium supramolecular compound and six coordination compounds, which are also characterized by IR, elemental analysis and X-ray structure analysis. According to X-ray structure analysis, hydrogen bonds and n-n stocking interactions participate in the architecture of three-dimensional framework [H2L1 (NO3)2 (H2O)2]n; one-dimensional zigzag coordination polymer [Hgl21.5CH3OH]n; binuclear metallamacrocycle (HgI2L2)2 3H2O; helical double-stranded one-dimensional coordination polymer [Co2(L2)2-2CH3OH]n; double-stranded one-dimensional coordination polymer [Co2(L3)2-CH3OH-CH3CN]n; and three-dimensional compound [Cu(C5H4NCOO)2(H2O)2]-H2O with hydrogen bonds, three-dimensional coordination polymer {[Cd(C5H6NCOO)2H2O]-DMF}n, which are indirectly obtained from the precursor ligand L3 through metal ion induced the hydrolysis of diamide and self-assembled with the hydrolyzate.

我们首次合成了一个双吡啶鎓超分子化合物和六个过渡金属配合物，并通过IR谱，元素分析和X-ray晶体衍射分析对它们进行了表征。X-ray晶体结构分析表明：超分子化合物[H_2L1·(NO_3)_2·(H_2O)_2]_n是由多种氢键和芳香环间的π-π堆积作用构建的三维无限结构；[HgI_2(L1)·1.5CH_3OH]_n是一维锯齿状配位聚合物；(HgI_2L2)_2·3H_2O是双核金属大环化合物；[Co_2(L2)_2·2CH_3OH]_n是具有一维双螺旋结构的配位聚合物；[Co_2(L3)_2·CH_3OH·CH_3CN]_n为一维双链结构的配位聚合物；以及由非直线形配体L3在金属离子Cu和Cd的诱导作用下发生水解，并且金属离子与水解产物——异烟酸根离子自组装，形成了三维氢键超分子化合物[Cu(C_5H_4NCOO)_2(H_2O)_2]·H_2O和三维配位聚合物{[Cd(C_5H_6NCOO)_2H_2O]·DMF}_n。

For each data bit sent or received,the high order bit of the current remainder is XORed with the data bit and then the remainder is shifted left one bit and the low-order bit set to zero.

对于每个被发送或者被收到的数据位，当前余项的最高一位和数据位进行异或，然后，余项是左移1位，并且，最低一位置零。

A series of study methods which can not research in this field begin to exert important affection. On the basis of the previous research, the following major innovative work was carried out in this dissertation.(1) Several methods including fluorescence spectra, CD and FT-IR specta methods were used to study the interaction of isoquinoline alkaloid、isoflavones and Rhein with serum albumin, and the results from every method was in good agreement;(2) The binding constants、the numbers of binding site、the binding region and the interaction force involving in the interaction of drugs and serum albumin were confirmed by Scatchard equation and Vant Hoff equation.

基于研究生物大分子与小分子相互作用具有极其重要的意义，本博士论文在前人工作的基础上，主要进行了以下几方面的创新性研究：(1)利用荧光光谱法、圆二色谱法、红外光谱法以及分子模拟等多种方法相结合研究了异喹啉类生物碱，异黄酮类化合物以及大黄酸与人血清白蛋白的相互作用，获得了准确一致的信息；(2)根据Scatchard方程和Vant Hoff方程详细研究计算了异喹啉类生物碱以及大黄酸与蛋白质结合机理包括结合常数、结合位点数、结合区域、结合力。

Microcalorimetric measurements of NH~3 adsorption on catalysts reveal that the remarkable strong acidity and catalytic activity of the Al- promoted catalysts are caused by a change of distribution of acid site strengths and an enhancement in the number of strong and intermediate-strong acid sites effective for the n-butane isomerization and benzoylation of toluene.

NH~3吸附微量热结果表明，Al促进样品的强酸性和催化活性的显著提高是由于样品表面的酸位强度分布发生了变化，有利于正丁烷异构化反应和苯甲酰化反应的中强酸位和强酸位的酸量显著增加。

The results showed that: with the regression analysis of Betula platyphylla, Pinus koraiensis, Abies nephrolepis, Picea koyamai var koraiensis, and Betula costata, there was a significant negative correlation between neighborhood interference index and the growth (0.40~0.89) and the correlation extent depended on the neighborhood influence zone and slope. The neighborhood influence zone corresponding to maximal regression coefficient R~2 was the neighborhood influence radius. Based on the linear subsection regression between neighborhood interference index and influence zone of five species, the neighborhood interference index increased with the increasing zone and there was a previous increasing trend in a certain scope, while the increasing trend slackened beyond the zone. The neighborhood influence zone corresponding to transition point was the neighborhood influence radius. The neighborhood interference index positively correlated with the neighborhood influence zone and the range of R~2 was 0.40-0.64. With the analysis of tree cores of Juglans mandshurica, Fraxinus mandshurica at middle and lower slope in a plot which was fostered in 1995, the distance which the growth release farthest neighborhood and object stub was judged, thus the neighborhood interference radius was inferred. According to the studies, we found that the neighborhood interference radius was different among different trees, even if the neighborhood interference radius of the identical tree species also had the difference at different slopes.

结果表明：通过对白桦、红松、冷杉、红皮云杉和枫桦树种进行邻体干扰指数与生长量回归分析发现，邻体干扰指数与生长量呈显著负相关(0.40～0.89)，相关程度因邻体影响范围和坡位而异，R~2达到最大值所对应的影响范围即为邻体影响半径；通过对白桦、红松、冷杉、红皮云杉和枫桦树种进行邻体干扰指数与影响范围的线性分段拟合，邻体干扰指数随影响范围的增加而增加，其在一定的范围内上升较快，而超出该范围后上升的幅度变慢，变化的转折点所对应的影n向范围可以判定为邻体影响半径，线性回归显著(0.40～0.64)；通过对1995a抚育的胡桃楸、水曲柳样树进行研究，分析邻体树种的中坡位和下坡位的生长锥芯，判断产生生长释放的最远邻木与基株树桩所对应的距离，推断邻体影响半径；根据研究发现，邻体影响半径因树种不同有一定的差异，即使同一树种的邻体影响半径在不同坡位也有一定的差异。

For a disubstituted complex, MA4B2, the planar arrangement gives three isomers, the familiar ortho, meta, and para arrangement s of organic chemistry.

对于双取代络合物MA4B2，其平面排列有三个异构体，常见的为有机化学中的邻位、间位和对位排列。

The products have an isoxazole mother core with 3-morpholinopyridyl substitution and possess an approxi-mately planar structure. In addition a number of ester groups, amino groups, triazole groups and oxazolidi-none groups were introduced to 5-position of the isoxazole mother core.

这些化合物均以异噁唑为母核，具有近似的平面结构，在异噁唑环的3-位引入吗啉吡啶基，而在5-位引入酯基、取代氨基、三唑环和噁唑烷酮环。

In order to extend the effect and security of image encryption algorithm.An image encryption algorithm is presented based on three-dimension chaotic system and bit-computation.The permutation sequences and binary sequences are generated using three-dimension chaotic system.Firstly,the image is pretreated using chaotic system and permutation transformation,then the pixel's gray value's bit sequences are permuted using the permutation sequences generated before,at last,the pixel's gray value's bit sequences are computed by using XOR operating and the binary sequences.

为了改进图像加密算法的安全性和效率，提出了一种基于三维混沌系统和位运算的数字图像加密算法，利用三维混沌序列的坐标分量分别产生置换序列和二值序列，在对待加密图像进行预处理的基础上，先应用混沌置换序列对预处理的结果图像进行基于灰度值位序列的置换操作，然后再应用产生的二值序列对结果图像的灰度值位序列进行位异或加密运算。

The algorithm splits the original image to some blockes and do DCT transform,chooses three low-frequency coefficients in every block,quantizes them and chooses the least significance bits,then does the xor operations with the corresponding bits of water mark.,the result is the key.At the same time,we choose three high-frequency,and do the same operation and generate the other key.

该方法对原始图像进行分块DCT变换，每块取三个DCT低频系数，把这三个系数量化后取最低有效位，与水印的对应位进行异或运算得到密钥；再取三个高频系数进行异或等运算得到另一密钥。

Cis-C=C configuration on 2 position is easily isomerized to trans-form in environment according to literatures, but cycloproyl do it difficut relatively. So, replacement of 2,3- allyl unit by cyclopropyl group might give a practical method to get over the problem.

为解决脱落酸2位双键在环境中易光异构化为反式结构的问题，依据电子等排体原理，将2，3-位的烯丙型的结构改变为环丙型结构，将可能解决光异构化的问题。

This one mode pays close attention to network credence foundation of the businessman very much.

这一模式非常关注商人的网络信用基础。

Cell morphology of bacterial ghost of Pasteurella multocida was observed by scanning electron microscopy and inactivation ratio was estimated by CFU analysi.

扫描电镜观察多杀性巴氏杆菌细菌幽灵和菌落形成单位评价遗传灭活率。