异丙烯基

Then Doripenem came into the market in the July ,2005. We studied the synthesis of Doripemen.Firstly, we synthesized the chemical 2 from the starting material------o-hydroxylphenylacylamine through Reformastky reaction, alkylation, Diekmann reaction, enolization, esterification and etc. Secondly, we synthesized the chemical 3 from L — hydroxylproline through the protection of carboxyl, amidogen and hydroxyl group, reduction by NaBr, SN_2 substitution and Mitsumobu reaction.

我们以水杨酰胺为起始原料，经Reformatsky反应、烷基化、Diekmann环合、烯醇化、酯化等反应合成双环母核2；再从L-羟基脯氨酸出发，经酯化保护羧基、保护氨基、保护羟基、硼氢化还原酯得醇、Sn2取代和Mitsumobu反应等合成巯基侧链3；最后由化合物3经脱保护、水解得硫醇，和化合物2在二异丙基乙基胺的作用下缩合，最后Pd／C催化脱保护，历经16步反应最终得到产物多尼培南。

The molybdenum-based multiphasic oxide catalysts were prepared and tested in the selective oxidation of isobutylene to methacrolein reaction.

研究了添加不同助剂对钼基复合氧化物催化剂对异丁烯选择性氧化制备甲基丙烯醛反应的影响。

Poly(N-isopropylacrylamide-co-2-hydroxyethyl methacrylate)/clay hydrogel was copolymerized with NIPA and HEMA cross-linked by clay to form a new kind of nanocomposite hydrogel P(NIPA-co-HEMA)/clay was obtained.

以无机粘土为交联剂制备了具有温度、pH双重敏感性的聚(N-异丙基丙烯酰胺-co-甲基丙烯酸-β-羟乙酯)/粘土纳米复合水凝胶P(NIPA-co-HEMA/clay，并用红外和X衍射对其结构和形态进行了表征。

Three methods are used to prepare molecular imprinted polymers,which include conventional bulk technique or polymerization with ultraviolet initiated in low temperature and polymerization with silica-gel as sacrificial materials. In the polymerization procedure , Sulfamethazine(SM2)and Sulfisoxazole were used as target template molecules, methacrylic acid and 4-vinylpyridine(4-VP) and acrylamide were selected as functional monomers, ethylene glycol dimethacrylate as crosslinker, azobisisobutyronitrile was used as initator.

主要工作如下：首先，以磺胺异噁唑和磺胺二甲嘧啶为模板，分别以4-乙烯基吡啶，甲基丙烯酸，丙烯酰胺为功能单体，以二甲基丙烯酸乙二醇酯为交联剂，偶氮二异丁腈为引发剂，采用了传统方法(60℃恒温水浴)、牺牲硅胶法及低温紫外光聚合法等三种方法合成了一系列的磺胺类药物印迹聚合物。

In the present study,a novel microgel was designed by the incorporation of temperature sensititive N-isopropylacrylamide and pH sensitive acrylic acid to copolymerize with glucosamine derivative,acrylamido-2-deoxy-glucose. The novel microgel has favorable biocompatibility,tissue-targeting and stimuli-responsibility to pH and temperature.

本文利用具有生物相容性的氨基葡萄糖单糖衍生物、具有温敏性的异丙基丙烯酰胺及具有pH敏感性的丙烯酸共聚得到了全新的微凝胶，新型微凝胶具有良好的生物相容性、组织靶向性和对温度、pH的刺激响应性。

The leftover from bamboo processing was comminuted into bamboo fine powder, which was surface-treaded with a coupling agent of ethenyl tri (β-methoxyethoxy) silane; and then in the presence of initiator dicumyl peroxide, the powder was compounded with styrene-isoprene block copolymer/bromobutyl rubber blend to prepare a crosslinked vibration-absorbing rubber composite material.

将竹加工的边角料粉碎并用乙烯基三硅烷偶联剂处理，再与苯乙烯－异戊二烯嵌段共聚物和溴化丁基橡胶的共混物进行复合，在过氧化二异丙苯引发剂的作用下制得交联型橡胶吸振复合材料。

Acrylamio-2-methyl propane sulfonic acid is applied in the production of water-based latex,which copolymerizes with acrylic acid,styrene or vinyl acetate to turn out latex resin.

2-丙烯酰胺基-2-甲基丙磺酸应用于水基性胶乳的生产过程中，与丙烯酸、苯乙烯或醋酸乙烯发生异分子聚合而生成胶乳树脂。

We studied the infection ofthe different reactant ratios to the degree of nitration when the polystyrere was nitrified. Thena series PS-NH_2 With different concentrations of amidocyanogen were gained by reducingPS-NO_2. At last the high active acryloylthiourea were grafted on the amidocyamogens.

在聚苯乙烯的硝化过程中，研究了不同的反应物配比对硝化度的影响，并对不同硝化度的硝基聚苯乙烯进行还原反应，得到了胺基含量不同的系列胺基聚苯乙烯，最后利用聚苯乙烯上的胺基和高活性的丙烯酰基异硫氰酸酯进行加成，合成AGPS。

This paper mainly studies the synthesis of 2-Isopropyl-5-Methyl-2-Hexenal from the optimum reaction conditions of from self aldol condensation of Isovaleraldehy,with NaOH solution as the catalyst of the condensation.

本文以NaOH水溶液为催化剂，探讨了异戊醛Aldol缩合制备可可醛(2异丙基5甲基2己烯醛)的最佳反应条件：反应温度50℃、反应时间9h、催化剂NaOH水溶液的浓度2mol.L1、OH-/异戊醛为1/1，主产物可可醛的产率为92.2%。

The surface activity and micelle behavior of the copolymers in aqueous solution were deterimned by surface tension methods.

在水溶液中，聚N-异丙基丙烯胺大分子随著温度升高会产生分子链的折叠，它的最低临界溶解温度为3236℃﹝4﹞，即在低于LCST时，它能完全溶解于水溶液中，而在LCST之上，则会产生沉淀。

We have no common name for a mime of Sophron or Xenarchus and a Socratic Conversation; and we should still be without one even if the imitation in the two instances were in trimeters or elegiacs or some other kind of verse--though it is the way with people to tack on 'poet' to the name of a metre, and talk of elegiac-poets and epic-poets, thinking that they call them poets not by reason of the imitative nature of their work, but indiscriminately by reason of the metre they write in.

索夫农 、森那库斯和苏格拉底式的对话采用的模仿没有一个公共的名称；三音步诗、挽歌体或其他类型的诗的模仿也没有——人们把&诗人&这一名词和格律名称结合到一起，称之为挽歌体诗人或者史诗诗人，他们被称为诗人，似乎只是因为遵守格律写作，而非他们作品的模仿本质。

The relationship between communicative competence and grammar teaching should be that of the ends and the means.

交际能力和语法的关系应该是目标与途径的关系。