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Aniline compounds containing heptafluoroisopropyl was synthesized through taking sodium dithionite as evocating agent, and introducing heptafluoroisopropyl by free radical electrophilic substitution on benzene ring.

以连二亚硫酸钠为引发剂,在苯环上通过自由基亲电取代反应引入七氟异丙基,合成了一系列含七氟异丙基的苯胺类衍生物,研究了各种条件对反应的速度和收率的影响。

The constituents were extracted by some solvents. 18 constituents were isolated from Chloroform fraction by different chromatography. 15 constituents were identified by IR ,MS and NMR as follows: 3-sitosterol, P-sitosterylpalm itate,succinate acids, 1, 4-benzenediol, 1, 2-benzenediol, p-hydroxybenzaldehyde, syringaresinol, oleanolic acid, usolic acid, ethyl caffeate , Rosmarinic acid ethylster and etc. In such constituents ,nine compounds were isolated for first time from Origanum vulgare L..

牛至药材经水煮醇沉法所得浸膏,利用溶剂法和色谱法从中分离得到18个单体成分,通过IR、MS、NMR等波谱技术鉴定了其中的15个化合物,分别为β-谷甾醇(1)、β-胡萝卜苷(2)、琥珀酸(3)、对-二苯酚(4)、邻-二苯酚(5)、对羟基苯甲醛(6)、1.2-二羟基-4-异丙基-5-甲基苯(7)、新木脂素(8)、丁香脂素(9)、齐墩果酸(10)、乌苏酸(11)、4-二十六烯(12)、正二十六醇(13)、咖啡酸乙酯(14)、迷迭香酸乙酯(15)等,其中化合物3、4、5、6、7、8、9、14、15等9种化合物均为首次从该属植物中分离得到。

Mission:"equality and mutual benefit, reputation first, unity and cooperation and friendship between the long-term" supply products: ethylenediamine; diethylamide; triethylamine; Diethylenetriamine; three ethylene diamine; three ethylene amines 40; 40 Five ethylene amines; five ethylene amines 6; caprolactam; DMF; allyl amine; N, N dimethylaniline; propylamine; are butylamine; are TOA; 3 Poly Cyanamide; 1,2 c diamine; ethanolamine; diethanolamine, triethanolamine; potassium iodide, potassium hydroxide, potassium permanganate, toluene, xylene, toluene of chlorine ; Acetone, butanone; acetylacetone; ethyl acetate, butyl acetate; Y-butyrolactone; DMC; acetyl of methyl acetate; Sanfu acetyl acid; Sanfu acetyl B Ethyl; methanol, ethanol, isopropanol; propylene glycol; glycerol; propargyl alcohol; 1.3 propylene glycol; xylitol; acetic acid; have acid; mercaptoacetic acid; vary Bitterness; adipic acid; trifluoroacetic acid; oxalic acid, the amino acid; o-amygdalin acid; DL-Acid; anhydrous piperazine; six non-piperazine, furfural, castor oil, ethylene Aldehyde; glutaraldehyde, multi-POM; isopropyl ether; anisole; tetrahydropyrrole; pure pyridine; 1.2 dichloroethane; methylene chloride, chloroform, carbon tetrachloride; hydrazine hydrate; Nonylphenol;-m-cresol; Se phenol; phenol; the tert-butyl phenol; Titanium Dioxide; iron; full Tangfen; Bisphenol A; azo two different nitrile; sodium azide; sodium carbonate ; Sodium chloride; iron oxide; cuprous chloride; thionyl chloride; D4; sodium bicarbonate; ammonia, potassium chloride; anhydrous sodium sulphite; ammonium persulfate; glycol Dingmi; B Glycol ether; calcium chloride; cyclohexanone; cyclohexane, methyl tertiary butyl ether, potassium carbonate, ferric chloride, potassium nitrate; Linsuansanna; zinc oxide; sodium nitrite; antimony oxide; Tartrate; OP-10; TX-10; tablets base; AES; sodium benzoate, sodium citrate; partial sodium silicate, sodium perborate, a sodium carbonate, sodium benzene; Asia sodium chlorate; Wuluo Care products; urea; hydrochloric acid, sulfuric acid, lactic acid; amino acid, hydrogen peroxide, ammonium bicarbonate

公司宗旨:"平等互利,信誉至上,团结合作,友谊长久"乙二胺;二乙胺;三乙胺;二乙烯三胺;三乙烯二胺;三乙烯四胺;四乙烯五胺;五乙烯六胺;己内酰胺;二甲基甲酰胺;烯丙基胺;N,N二甲基苯胺;正丙胺;正丁胺;正辛胺;三聚氰胺;1,2丙二胺;一乙醇胺;二乙醇胺;三乙醇胺;碘化钾;氢氧化钾;高锰酸钾;甲苯;二甲苯;对氯甲苯;丙酮;丁酮;乙酰丙酮;醋酸乙酯;醋酸丁酯;Y-丁内酯;碳酸二甲酯;乙酰乙酸甲酯;三伏乙酰乙酸;三伏乙酰乙酸乙酯;甲醇;无水乙醇;异丙醇;丙二醇;丙三醇;丙炔醇;1.3丙二醇;木糖醇;冰醋酸;己醛酸;巯基乙酸;异辛酸;己二酸;三氟乙酸;乙二酸;对氨基苯乙酸;邻氯苦杏仁酸;DL-扁桃酸;无水哌嗪;六无哌嗪;糠醛;蓖麻油;乙二醛;戊二醛;多聚甲醛;异丙醚;苯甲醚;四氢吡咯;纯吡啶;1.2二氯乙烷;二氯甲烷;三氯甲烷;四氯化碳;水合肼;壬基酚;纯间甲酚;硒酚;苯酚;对叔丁基苯酚;钛白粉;铁粉;全糖粉;双酚A;偶氮二异丁腈;叠氮化钠;碳酸钠;氯化钠;三氧化二铁;氯化亚铜;氯化亚砜;D4;碳酸氢钠;氨水;氯化钾;无水亚硫酸钠;过硫酸铵;乙二醇丁醚;乙二醇乙醚;氯化钙;环己酮;环己烷;甲基叔丁基醚;碳酸钾;三氯化铁;硝酸钾;磷酸三钠;氧化锌;亚硝酸钠;氧化锑;酒石酸;OP-10;TX-10;粒碱;AES;苯甲酸钠;柠檬酸钠;偏硅酸钠;过硼酸钠;过碳酸钠;苯磺酸钠;亚氯酸钠;乌洛托品;尿素;盐酸;硫酸;乳酸;氨基磺酸;双氧水;碳酸氢铵

According to the differences of the materials, there are many methods of synthesis for benzofuranol , such as the pyrocatechol method, the cyclohexanone method, the o-chlorophenol method, the nitrophenol method, the methoxy phenol method, and so on.

根据原料的不同,呋喃酚合成方法可分为邻苯二酚法、邻氯苯酚法、环己酮法、硝基苯酚法、愈创木酚法、邻异丙基酚法、羟基苯异酮法等,文章对前几种较常见的合成方法的原理及工艺进展进行了详细的综述,并展望了呋喃酚合成方法的发展趋势。

Mission:"equality and mutual benefit, reputation first, unity and cooperation and friendship between the long-term" supply products: ethylenediamine; diethylamide; triethylamine; Diethylenetriamine; three ethylene diamine; three ethylene amines 40; 40 Five ethylene amines; five ethylene amines 6; caprolactam; DMF; allyl amine; N, N dimethylaniline; propylamine; are butylamine; are TOA; 3 Poly Cyanamide; 1,2 c diamine; ethanolamine; diethanolamine, triethanolamine; potassium iodide, potassium hydroxide, potassium permanganate, toluene, xylene, toluene of chlorine ; Acetone, butanone; acetylacetone; ethyl acetate, butyl acetate; Y-butyrolactone; DMC; acetyl of methyl acetate; Sanfu acetyl acid; Sanfu acetyl B Ethyl; methanol, ethanol, isopropanol; propylene glycol; glycerol; propargyl alcohol; 1.3 propylene glycol; xylitol; acetic acid; have acid; mercaptoacetic acid; vary Bitterness; adipic acid; trifluoroacetic acid; oxalic acid, the amino acid; o-amygdalin acid; DL-Acid; anhydrous piperazine; six non-piperazine, furfural, castor oil, ethylene Aldehyde; glutaraldehyde, multi-POM; isopropyl ether; anisole; tetrahydropyrrole; pure pyridine; 1.2 dichloroethane; methylene chloride, chloroform, carbon tetrachloride; hydrazine hydrate; Nonylphenol;-m-cresol; Se phenol; phenol; the tert-butyl phenol; Titanium Dioxide; iron; full Tangfen; Bisphenol A; azo two different nitrile; sodium azide; sodium carbonate ; Sodium chloride; iron oxide; cuprous chloride; thionyl chloride; D4; sodium bicarbonate; ammonia, potassium chloride; anhydrous sodium sulphite; ammonium persulfate; glycol Dingmi; B Glycol ether; calcium chloride; cyclohexanone; cyclohexane, methyl tertiary butyl ether, potassium carbonate, ferric chloride, potassium nitrate; Linsuansanna; zinc oxide; sodium nitrite; antimony oxide; Tartrate; OP-10; TX-10; tablets base; AES; sodium benzoate, sodium citrate; partial sodium silicate, sodium perborate, a sodium carbonate, sodium benzene; Asia sodium chlorate; Wuluo Care products; urea; hydrochloric acid, sulfuric acid, lactic acid; amino acid, hydrogen peroxide, ammonium bicarbonate

公司宗旨:&平等互利,信誉至上,团结合作,友谊长久&乙二胺;二乙胺;三乙胺;二乙烯三胺;三乙烯二胺;三乙烯四胺;四乙烯五胺;五乙烯六胺;己内酰胺;二甲基甲酰胺;烯丙基胺;N,N二甲基苯胺;正丙胺;正丁胺;正辛胺;三聚氰胺;1,2丙二胺;一乙醇胺;二乙醇胺;三乙醇胺;碘化钾;氢氧化钾;高锰酸钾;甲苯;二甲苯;对氯甲苯;丙酮;丁酮;乙酰丙酮;醋酸乙酯;醋酸丁酯;Y-丁内酯;碳酸二甲酯;乙酰乙酸甲酯;三伏乙酰乙酸;三伏乙酰乙酸乙酯;甲醇;无水乙醇;异丙醇;丙二醇;丙三醇;丙炔醇;1.3丙二醇;木糖醇;冰醋酸;己醛酸;巯基乙酸;异辛酸;己二酸;三氟乙酸;乙二酸;对氨基苯乙酸;邻氯苦杏仁酸;DL-扁桃酸;无水哌嗪;六无哌嗪;糠醛;蓖麻油;乙二醛;戊二醛;多聚甲醛;异丙醚;苯甲醚;四氢吡咯;纯吡啶;1.2二氯乙烷;二氯甲烷;三氯甲烷;四氯化碳;水合肼;壬基酚;纯间甲酚;硒酚;苯酚;对叔丁基苯酚;钛白粉;铁粉;全糖粉;双酚A;偶氮二异丁腈;叠氮化钠;碳酸钠;氯化钠;三氧化二铁;氯化亚铜;氯化亚砜;D4;碳酸氢钠;氨水;氯化钾;无水亚硫酸钠;过硫酸铵;乙二醇丁醚;乙二醇乙醚;氯化钙;环己酮;环己烷;甲基叔丁基醚;碳酸钾;三氯化铁;硝酸钾;磷酸三钠;氧化锌;亚硝酸钠;氧化锑;酒石酸;OP-10;TX-10;粒碱;AES;苯甲酸钠;柠檬酸钠;偏硅酸钠;过硼酸钠;过碳酸钠;苯磺酸钠;亚氯酸钠;乌洛托品;尿素;盐酸;硫酸;乳酸;氨基磺酸;双氧水;碳酸氢铵

To synthesize the octreotide, Phe-Leu-Glu-Glu-Leu and C_(15)H_(31)-CO-Lys-Thr -Thr-Lys-Ser peptides, the strategies are as followings: Fmoc- group as protective group for α-NH_2; TBTU, DIEA and HOBt as coupling reagent; and ethanedithiol -phenol - thioanisole - H_2O - TFA ( 2.5:5:5:5:82.5 , V/V ) as cleaving solution.

采用Fmoc固相合成法,以苯并三哗四甲基脲四氟硼酸盐、二异丙基乙胺和1-羟基苯骈三氮唑为缩合剂;苯酚—乙二硫醇—苯甲硫醚—水—三氟乙酸(5:5:2.5:5:82.5,V/V)为切割试剂,合成了奥曲肽、Phe-Leu-Glu-Glu-Leu及C_(15)H_(31)-CO-Lys-Thr-Thr-Lys-Ser三种小分子多肽,并对奥曲肽的合成规模进行了放大。

Isopropyl 1,3 benzodioxolane was synthesized from catechol and isobutyric aldehyde using the phosphotungstic acid supported on activated carbon as catalyst.

以邻苯二酚和异丁醛为原料,活性炭固载磷钨酸为催化剂合成了杀虫剂呋喃丹的中间体2 -异丙基- 1,3-苯并二氧五环。

The copolymer of N isopropylacrylamide and acrylamido azobenzene was synthesized for the study of the effect of the photoisomerization of a water soluble copolymer containing azobenzene groups on the photocontrolled release behavior of liposomes.

为了研究侧链含有偶氮苯基的水溶性共聚物的光异构化对脂质体内包容物的光控释放的影响,设计合成了N-异丙基丙烯酰胺和丙烯酰胺基偶氮苯的共聚物。

A new corrosion inhibitor and Universal antibacterial reagent, namely, the copolymer of N-isopro-pylacrylamide and N-allyl-1-benzoyl-3-phenyl-4,5-dihydro-4-formamido pyrazole was prepared.

合成了一种新的腐蚀抑制及广谱抑菌剂:N-异丙基丙烯酰胺与N-烯丙基-1-苯甲酰基-3-苯基-4,5-2H-4甲酰胺基吡唑的共聚物PNIPAM-Co-PBPCP。

In pacemaker cells of SA node superfused with the oxygenated K—H solution, MDP, APA, V〓, VDD, RPF and APD〓 were—45±5mv, 48±4mv, 2. 4±0.9v/s, 89±8 mv/s, 200±11bpm and 206±15ms, respectively. Anoxia (perfused for 20min with a modified K—H solution gassed with 100% N〓 and deprived of glucose) increased MDP, APA and V〓, and decreased VDD and RPF in a timedependent manner. At anoxia for 20min, the above parameters were—58±5mv, 64±5mv, 11. 7±2. 7v/s, 24±7mv/s, 92±11bpm and 179± 14ms, respectively. ADase (10U/L).

环戊腺苷和苯基异丙基腺苷不仅能增加豚鼠窦房结起搏细胞APA、MDP和〓,且能减小VDD、RPF和〓在环戊腺苷20nmol/L浓度时,MDA、APA和〓分别增值5.4±0.7mv、7.6±0.9mv和2.4±0.5v/s,VDD、RPF和〓分别降低32±4mv/s、68±9bpm和31±12ms(p.05或0.01)。0.1μmol/L 8—苯茶碱和10μmol/L格列苯脲能明显地抑制环戊腺苷的电生理效应。

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Now, however, all children continue in "comprehensive" schools, and the eleven-plus determines which courses of study the child will follow.

然而现在,所有的孩子都要在综合学校继续学习,所以这次考试只是决定他们将要学习哪些课程。

Cultivatable land , and led to a general recognition that development must not be carried at the cost of agriculture .

城区的迅速扩大在很多情况下侵占了宝贵的可耕地,使人们普遍认识到发展不能以牺牲农业为代价。

Detailed Intrinsic Reaction Coordination calculations were carried out to guarantee the optimized transition-state structures being connected to the related tautomers.

同时,做了详尽的内禀反应坐标计算,以保证所得到的过渡态连接相应的始末异构体。