异丁烯

Selective oxidation of isobutylene to methacrolein is a key step in the production of methyl methacrylate from isobutylene.

异丁烯选择氧化制备甲基丙烯醛是异丁烯法制备甲基丙烯酸甲酯的关键步骤。

The experimental results showed that: the adsorption of methanol and isobutylene conform to Elovich equation. The adsorption quantity of methanol was bigger than that of isobutylene, but the adsorption rate was slower.

采用过渡应答技术对甲醇和异丁烯在改性b分子筛上的吸附行为进行了研究，研究结果表明：异丁烯和甲醇在改性b分子筛上符合先快吸附后慢吸附的Elovich吸附规律。

The behaviors of methanol and isobutylene adsorbed over a modified-b zeolite catalyst were studied by the transient response method in a chromatogram-reactor. The experimental results showed that: the adsorption of methanol and isobutylene conform to Elovich equation.

摘 要：采用过渡应答技术对甲醇和异丁烯在改性b分子筛上的吸附行为进行了研究，研究结果表明：异丁烯和甲醇在改性b分子筛上符合先快吸附后慢吸附的Elovich吸附规律。

Kinetics of isobutylene hydration reaction catalyzed by fine powder of NKC-9 ion exchange resin,and effects of catalyst concentration,temperature,pressure,stirring rate and isobutylene concentration on reaction were studied in a semibatch reactor.

采用半连续反应过程，使用NKC -9离子交换树脂细粉，改变催化剂浓度、反应温度、反应压力、搅拌转速和异丁烯浓度等条件，对异丁烯水合反应动力学进行了实验研究。

The mass transter can be enhanced ,when we introduce sulfuric acid and cuprous oxide into this system.The model is formed to describe the transference of the martial between the four phases: gas-liquid-liquid-gas, which can explain some problems. We analyze the dead of the catalyst, and make a conclusion that the surface of the catalyst is covered with some compounds such as bluestone, which lessen the activity points of the catalyst and debase the activity.

在SO_4~(2-)／ZrO_2-La_2O_3催化的反应系统中加入稀硫酸和氧化亚铜促进了异丁烯和一氧化碳的传质、使反应得以快速，高选择性的进行，异丁烯的转化率达95％以上，特戊酸的收率达47％；讨论了g-l-l-s传质过程；对催化剂作了失活分析，催化剂失活的原因是因为反应后的催化剂表面覆盖了一层硫酸盐，使催化剂的活性中心数减少，活性降低。

IR analysis indicated that both of the results were accorded with their standards IR spectrum and that the products of alkylation and animation were polyisobutylene succinic anhydride and ashless dispersant TEPA.

通过烃化产物和胺化产物的红外光谱分析，并分别与其标准谱图对照比较，看出产物红外谱图与标准谱图相符，可以确认烃化产物和胺化产物即为聚异丁烯丁二酸酐和聚异丁烯丁二酰亚胺无灰分散剂。

This item plans to construct 5 thousand t/y Tert - butylamine production equipment which uses internally developed independently isobutene cyanide process for the production of raw materials for pure isobutylene, purity of 99.5% of the domestic production of tert - butylamine.

该装置采用国内自主开发的异丁烯氰化法生产工艺，以纯异丁烯为原料，生产纯度为99.5％的叔丁胺产品。

The results show that isobutene oligomerization is fast liquid-solid reaction. Under the temperature of 80 ℃～120 ℃ and pressure of 2.0 MPa, the products of oligomerization are mainly dimers and trimers of isobutene. The yield of trimers is higher than that of dimers and the mass fraction of trimers decreases with reaction temperature increasing. The yield of tetramers is much lower than that of dimmers and trimers. The tetramers are formed by reaction of isooctenes and C8 carbonium ion.

结果表明，异丁烯齐聚反应为快速液固相催化反应，在80 ℃～120 ℃，2.0 MPa的实验条件下，反应产物主要是异丁烯的二聚物和三聚物，且三聚物的收率远高于二聚物，两者的浓度比值随反应温度的升高而下降；少量四聚物的生成主要源于碳八烯烃与碳八正碳离子的反应。

Under optimal conditions: reaction temperature 80 - 90 ℃, V: V 4 - 5 , linear flowrate of C4 raffinate 0.45 - 0.55 mrn/s

在此条件下，异丁烯的转化率可达88.8％。工业装置运转结果表明，异丁烯转化率大于75％。

The catalyst for IB dimerization, reactive site, reactive mechanism and dynamics research date was reviewed in this paper and try to explain the mechanism of selectivity enhancing by adding Tertiary butyl alcohol during IB dimerization and provide reference for the study of dimerization afterwards.

本文对异丁烯二聚催化剂、反应活性位、机理及动力学研究成果进行了综述，试图解释在异丁烯二聚时，加入的叔丁醇对二聚反应选择性提高的作用机理，为今后二聚反应的研究提供参考。

James, son of Zebedee, and John the brother of James, whom he named Boanerges, that is, sons of thunder

载伯德的儿子雅各伯和雅各伯的弟弟若望，并为他们起名叫"波纳尔革"，就是"雷霆之子"

The southern Hungarian university city of Szeged will host part of the project, amounting to 40 percent of the total investment, which will mostly be paid for through Hungary's EU structural funds.

位于塞格德南部的匈牙利大学将负责部分项目，总计占总投入资金的40%。大部分资金将由匈牙利的欧盟结构基金会支付。