异丁基

The influence of each condition on the reaction speed and yield was studied, and the optimal conditions were: the ratio of the amount of substance of aromatic amine and heptafluoro-isopropyl iodine was 1:1.1~1.5, the amount of substance of sodium dithionite, sodium bicarbonate, aniline compounds were respectively 1.1~1.3, the amount of substance of phase transfer catalyst TBAB and aniline compounds was 0.05~0.1, the concentration of aniline compound was 0.5~1.0 mol/L, reaction temperature was 10~20 ℃, and the solvent was aether.

最佳结果为：芳胺与七氟异丙基碘的物质的量比1：1.1~1.5，连二亚硫酸钠、碳酸氢钠与苯胺的物质的量分别为1.1~1.3，相转移催化剂四丁基溴化铵与苯胺的物质的量比在0.05~0.1，溶剂总用量使苯胺浓度在0.5~1.0 mol/L；反应温度10~20℃；溶剂采用乙醚。取代基供电子性越强，反应时间越短，产率越高；氨基的对位优先反应，氨基的邻位较难发生反应；且七氟异丙基总是优先取代在芳环电子云密度较高的位置上。

The course of thermal reaction for iso-butyl mercaptan, di-n-butyl sulfide and di-n-butyl disulfide is free radical mechanism.

对于异丁硫醇、丁硫醚、丁基二硫化物的热反应，其热转化的途径是自由基机理。

G. the perfumes. The wall forming materials were TDI (2, 4-toluene diisocyanate) or 80/20TDI, triphenyl methane triisocyanate and biphenyl methane-4, 4-diisocyanate , Poly vinyl alcohol was used as protective colloid and GPE2040 was used as the emulsifier.

壁材单体分别使用了2，4-甲苯二异氰酸酯、80／20-甲苯二异氰酸酯、三苯基甲烷-4，4′，4-三异氰酸酯和二苯甲烷-4，4′-二异氰酸酯；保护胶体是聚乙烯醇；乳化剂是聚醚2040；催化剂使用二月桂酸二丁基锡。

The mixed collectors studied were as following: benzyl arsonic acid-sodium butyl xanthate for walframite flotation, salicylohydroxamic acid-F〓, salicylohydroxamic acid-cupferron, salicylohydroxamic acid-TBP , F〓-TBP, cupferron-benzohydroxamic acid etc. for cassiterite flotation and mixed aliphatic acid or aliphatic amine for beryl or spodumene flotation.

研究过程中，本文选用了如下具体实例：苄基胂酸与丁基黄药浮选黑钨矿，水杨羟肟酸与F〓、水杨羟肟酸与铜铁灵、水杨羟肟酸与磷酸三丁酯、F〓与磷酸三丁酯、铜铁灵与苯异羟肟酸两两结合浮选锡石，混合脂肪胺与混合脂肪酸浮选锂辉石与绿柱石。

A process for preparingp-fluo-2-(2-methyl-3-propionyl)-4-oxy-N,3-diphenyl-phenylbutylamide includes such steps as Friedle-Craft acylating of newly prepared phenylacetyl chloride and fluorobenzene under catalysis of AlCl3 to obtain 4-fluoro-phenylbenzyl ketone, brominating at carbonyl alpha position under catalysis of less AlCl3 to obtain alpha-bromo-4-fluo-phenylbenzyl ketone, and condensing with isobutyryl acetanilide under action of sodium ethoxide.

本发明涉及一种制备对氟－2－(2－甲基－3－氧丙基)－4－氧－N，3－二苯基－苯丁酰胺(1)的方法，其包括以下步骤：新制的苯乙酰氯与氟苯在AlCl3催化下进行Friedle－Craft酰化反应，得到对4－氟－苯基苄基酮(4)；化合物(4)在少量AlCl3催化下进行羰基α位溴化，得到α－溴－4－氟－苯基苄基酮(5)；然后(3)异丁酰乙酰苯胺在乙醇钠作用下与化合物(5)进行缩合。

Both star copolymer precursors are hydrolyzed in the acidic conditions, then the corresponding recovered star copolymers of EO and glycidol with multi pending hydroxylmethyls are esterified with 2-bromoisobutyryl bromide to produce the ATRP macroinitiators with multi pending bromoisobutyryl groups . Then the latters initiate the polymerization of styrene to form the corresponding amphiphilic three- and four-arm star PEO-g-PS.

在阴离子共聚EPEE单体和环氧乙烷单体的过程中，通过变换引发剂体系中的醇的结构(由原来的二元醇变成多元醇，如三羟甲基丙烷和季戊四醇)，合成了星形结构的共聚物，通过水解反应脱去保护基团后，再与2-溴异丁酰溴反应，得到链的侧端挂有很多2-溴异丁酸酯基的星形大分子引发剂，通过ATRP聚合机理引发苯乙烯聚合得到PEO为主链，PS为侧链的星形一接枝共聚物。

The conversion of isobutyraldehyde and the selectivity to 2,4,6-triisopropyl-1,3,5-trioxane were 91.1% and 99.8% respectively under optimum reaction condition isobutyraldehyde 25.0 g, [Et3NH]Cl/FeCl3 ( x (FeCl3)＝0.62 1.0 g, 25 ℃ for 1 h .

在最佳的反应条件下（异丁醛25.0 g， [Et3NH]Cl/FeCl3 x (FeCl3=0.62 1.0 g， 25 °C，N2保护下反应1 h，异丁醛的转化率为91.1%，对2，4，6-三异丙基-1，3，5-三氧噁烷的选择性达99.8%。

A series of lanthanide complexes (Ln = Er, Nd, Yb) with infrared emission properties were designed and synthesized by using different anionic ligands [1 -phenyl-3-methyl-4-(4-tertbutylbenzoyl)-5-pyrazolone and l-phenyl-3-methyl-4--5-pyrazolone and 2-naphtoyl trifluoroacetone] and netural ligands (2,2-dipyridine, phenanthroline, triphenylphosphine oxide and water). Three crystal structures of these complexes were obtained and structure studied, and the properties of photoluminescence and fluorescent lifetime were studied in detail.

我们通过选用不同的第一配体[1-苯基-3-甲基-4-(4-异丁酰基)-5-吡唑酮，1-苯基-3-甲基-4-(4-叔丁基苯甲酰基)-5-吡唑酮和2-萘基三氟乙酰丙酮]和第二配体(2，2-联吡啶，邻菲啰啉，三苯基氧膦)合成了16个稀土红外配合物(Ln=Er，Nd，Yb)，获得了其中三个配合物的单晶结构，研究了这些稀土红外配合物的光致发光和荧光寿命等性质。

A four-ball tester was used to evaluate the load carrying and antiwear properties of bismuth dibutyldithiocarbamate,bis-dibutyldithiocarbamates(V7723),sulfurized isobutylene,molybdenum ester non sulfur and phosphorus in a mineral oil respectively and their synergistic effects.

利用四球试验机评价了二丁基二硫代氨基甲酸铋与二丁基二硫代氨基甲酸酯(V7723)、硫化异丁烯和非硫磷钼酸酯添加剂的极压和抗磨性能，以及它们之间的极压和抗磨协同作用。

The results showed 3 types of aluminum compound prepared in this paper all had good poison protection effectiveness on such impurities as stannous chloride,lead oxide,sodium hydrogen sulfate,and so on.Moreover,the mechanism of the poison of catalyst was also discussed.

结果表明，合成的3种防中毒剂即防－1、防－2(主要成分为乙酰丙酮合铝)及防－3(主要成分为二乙酰丙酮基异丙氧基铝)对二月桂酸二丁基锡、氯化亚锡、二正丁胺、硫脲、氧化铅及硫酸氢钠等杂质均有较好的防中毒作用；不同防中毒剂对不同杂质的防中毒作用有一定的选择性。

For a big chunk of credit-card losses; the number of filings (and thus charge-off rates) would be rising again, whether

年美国个人破产法的一个改动使得破产登记急速下降，而后引起了信用卡大规模的亏损。

Eph. 4:23 And that you be renewed in the spirit of your mind

弗四23 而在你们心思的灵里得以更新