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The molybdenum-based multiphasic oxide catalysts were prepared and tested in the selective oxidation of isobutylene to methacrolein reaction.

研究了添加不同助剂对钼基复合氧化物催化剂对异丁烯选择性氧化制备甲基丙烯醛反应的影响。

Aim To synthesize new type of octane number improver for gasoline , methoxyisobutyrate.

目的合成一种新型汽油辛烷值改进剂─甲氧基异丁酸烷基酯。

The catalytic system composed of NHPI and transition metal ion can catalyze effectively ethane into acetic acid,cyclane into dicarboxylic acid,toluene into benzoic acid,alkene into epoxide,alkyne into acetylenic ketone,and amide into imide;NHPI used alone can catalyze adamantane to be carbonylated,hydrogen peroxide prepared by oxidization alcohol;NHPI combined with as...

NHPI与过渡金属离子组成的催化体系能高效地催化乙烷氧化为乙酸、环烷烃氧化为二元羧酸、甲苯氧化为苯甲酸、烯烃氧化为环氧化物、炔烃氧化为炔酮、酰胺氧化为酰亚胺;NHPI单独使用能催化金刚烷发生氧化羰基化反应、催化氧化醇制取过氧化氢;NHPI与有机助催化剂如偶氮二异丁腈、溴化季铵盐、蒽醌和醇等也能催化分子氧氧化反应。

HMT general synthesis is aluminum chloride as a catalyst, isopropyl - toluene right with the new hexene, or 2 January 2 3 1 2 1-butene six-olefins reaction.

HMT的合成一般是以三氯化铝为催化剂,由对异丙基甲苯与新己烯、或2,3一二甲基一2一丁烯等六碳烯烃反应生成。

In the polymerization procedure,S--α-phenyl ethylamine was used as target template molecules,methacrylic acid was selected as functional monomers, ethylene glycol dimethacrylate or divinylbenzene as crosslinker, azobisisobutyronitrile or benzophenone was used as irritator.

以S--α-苯乙胺为模板,甲基丙烯酸为功能单体,分别以二甲基丙烯酸乙二醇酯、二乙烯基苯为交联剂,偶氮二异丁睛或二苯甲酮为引发剂,采用了本体聚合法、悬浮聚合法合成了一系列的S--α-苯乙胺印迹聚合物。

For the first time, enantiomers of C2-symmetric 1,1 -spirobiindane-7,7'-diol were resolved with crude menthyl chloroformate by phase-transfer catalysis in the presence of tetrabutylammonium bromide. The reaction was carried out at 0℃-rt. The diastereomers of SPINOL bis-menthyl carbonate can be separated by simple crystallization using alcohol. The hydrolysis of the diastereomers was carried out via aqueous NaOH/EtOH solution.

首次通过相转移催化的方法对螺双二氢茚二酚进行了有效的拆分,用L--氯甲酸薄荷醇酯做拆分剂,以四丁基溴化铵为催化剂在0℃-室温下进行酯化反应生成非对映体衍生物,以乙醇作溶剂,通过重结晶的方法分离衍生物,在水-乙醇混合溶剂条件下,用强碱NaOH或KOH分别水解,制得相应的光学纯度大于99%ee的两个异构体SPINOL,其中总收率:--SPINOL,78.2%;--SPINOL,80.6%。

Gas chromatograph/mass spectrometer system was used to analyze polycyclic aromatic hydrocarbon (PAHs, including naphthalin, anthracene and fluoranthene) and phthalic acid ester [PAEs, including dimethyl phthalate, diethyl phthalate, diisobutyl phthalate and di(2-ethylhexyl) phthalate] concentration in water samples taken from every treatment units of a large-scale waterworks in a western city whose water source is the upstream of Yangtze river.

以多环芳烃(包括萘、蒽、荧蒽三种物质)和邻苯二甲酸酯包括邻苯二甲酸二甲酯(DMP、邻苯二甲酸二乙酯、邻苯二甲酸二异丁酯、邻苯二甲酸二(2-乙基己基)酯4种物质作为研究对象,采用GC-MS方法测定了以长江为原水的某大型城市给水厂各工艺段水样中的上述物质。

In order to solve the problems such as multiple components in products, long time of rectification, high energy consumption, low yield and purity of product occurring during the production of p - octyl phenol, the effects of reaction conditions including reaction temperature, reaction time, the molar ratio of phenol to diisobutene on the conversion and yield of the product were examined.

为解决对辛基酚生产过程中精馏时存在组分多、精馏时间长、能耗高、产品收率和纯度低等问题,用正交实验探讨反应温度、反应时间、苯酚与二异丁烯原料摩尔比3因素对原料转化率和产品对辛基酚收率的影响。

In order to decrease copolymerization loss of isoprene during thermal dimerization of cyclopentadiene in C5-fraction,the effect of three inhibitors,diethylhydroxylamine,p-tert-butylcatechol and o-nitrophenol,on dienes' polymerization in the process was investigated by experiment with sealed glasstube.

为减少C5馏分环戊二烯热二聚过程中异戊二烯的聚合损失,采用封管实验方法考察了添加阻聚剂二乙基羟胺、对叔丁基邻苯二酚、邻硝基苯酚对热二聚过程中各二烯烃组分聚合程度的影响。

The inhibition effect of 2,2,6,6-tetramethyl-4-hydroxylpiperidine-oxyl and some phenols and quinones on the AIBN initiated radical polymerization of styrene was studied by using dilatomitry method.

用膨胀计法,研究了2,2,6,6-四甲基-4-羟基哌啶氧自由基及一些醌、酚类化合物对偶氮二异丁腈引发的苯乙烯自由基聚合的阻聚效应。结果表明,当 St在80℃聚合时,加入TMHPO·或TMHPO·-BQ,阻聚效果较为显著。

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