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The major products were methane, ethylene, propylene, butylene, butadiene, cyclopentadiene, benzene, toluene, styrene, vinyl-substituted cyclopentene derivatives and C5/C6 isomers pentadiene, met...

热裂解主要产物为甲烷、乙烯、丙烯、丁烯、丁二烯、环戊二烯、苯、甲苯、苯乙烯、环戊烯的乙烯基取代物及C5,C6异构体(戊二烯、环戊烯的甲基取代物、环己烯、己二烯和环戊二烯甲基取代物),其中,C1~C4、环戊二烯、苯、甲苯、乙烯基取代环戊烯为初始产物。

ABSTRACT In this paper, by employing dicarboxylic acids with special conformation, i.

利用几个结构上有特点的二元羧酸,即2,6-吡啶二甲酸、三个异构体苯二甲酸,顺丁烯二酸和4,4'-联苯甲酸作为首要桥基配体,并结合使用含氮中性配。。。

A series of segmented thermally stimulated shape-memory polyurethanes, which consist of polyethylene adipate glycolas the soft segment and 4,4'-diphenylmethane diisocyanate-1,4-butanediol-DPA(which consists of ring components) as the hard segment were synthesized by one-step polymerization.

以聚己二酸乙二醇酯二醇为软段、4,4' -二苯基甲烷二异氰酸酯 1,4 丁二醇含环状结构的扩链剂DPA为硬段,采用一步聚合法制备了一种具有热致形状记忆功能的多嵌段聚氨酯弹性体。

In this article, we have been investigated that synthesizing and properties of shape memory polyurethane. The shape memory polyurethane was synthesized from PCL diol, MDI(4, 4'-diphenylmethane diisocyanate) and BDO (1,4-butanediol) in this experiment. We analyzed that the effect of differential mole ratio of monomers to synthesized SMPU. Besides, the various concentrations of Nano-silver were mixed with SMPU. Mechanical properties and shape memory behavior of SMPU nanocomposite films were investigated.

本研究目的为藉由改变4,4'-二苯甲基二异氰酸盐(4,4'-diphenylmethane diisocyanate, MDI)/聚己内酯二元醇(polycaprolactone diol, PCL diol)/1,4-丁二醇(1,4-butanediol, BDO)等不同莫耳比制备形状记忆型聚氨基甲酸酯(Shape Memory Polyurethane, SMPU);并探讨改变不同单体莫耳比及添加不同浓度奈米银溶液对其物性及形状记忆性的影响。

Other methyl nucleophiles includingMeMgBr, MeCeCl2, MeTiCl3, Me3Al, Me3ZnMgCl, MeMnClwere tried, but in all these cases no detectable amount of exo-C8-methylated product was obtained. Although protecting C3-carbonyl as 1,3-dioxolanes could be achieved, the serious enolization of C8-carbonyl was still problematic. Converting C9-furan ring to α,β-butenolide did depress the enolization, but desired C8-methylation was completely replaced by migration of the double bond of the butenolide.

在本论文的早期阶段,主要着眼于解决二环[3.2.1]-C8-羰基加成甲基所遇到的C9-呋喃环差向异构化和C3与C8两个羰基之间化学选择性的问题:通过引入不同金属降低甲基试剂的碱性并没有取得甲基化的成功;通过不同的方法将C3-羰基掩蔽,但是C8-羰基的烯醇化依然无法抑制;虽然通过将呋喃环转化为α,β-不饱和-γ-丁内酯可以抑制烯醇化,但内酯环上的双键迁移又成了新的竞争反应。

Our results have shown that the analgesic effect of morphine administered to nucleus accumbens was blocked by intra-habenula injection of naloxone or ME antiserum, whereas the analgesic effect of morphine injected into habenula was attenuated by intra-PAG administration of naloxone or muscimol, and enhanced by bicuculline methochoride (BMC, an antagonist of GABA receptor).

本工作实验结果表明,在伏核内注射吗啡产生的镇痛作用可被缰核内注射NX或ME抗体所大部阻断,而缰核内注射吗啡产生的镇痛作用又可被PAG内注射NX或γ-氨基丁酸受体激动剂异鹅羔胺所削弱,被GABA受体阻断剂氯甲基荷包牡丹碱所增强。

In the forth part, the heterotactic enthalpic pairwise interaction coefficients between amino acids and butanediol isomers (1,3-butanediol, 1,4-butanediol and 2,3-butanediol) at 298.15K and 310.15K are discussed.

第五部分:采用密度泛函理论等方法研究了甘氨酸分子分别与丁二醇的三种异构体分子以1:1的比例形成的氢键络合物,从B3LYP6-31G到6-31 G基组水平进行了优化,利用结合能数据讨论了焓对作用系数的差别。

HMT general synthesis is aluminum chloride as a catalyst, isopropyl - toluene right with the new hexene, or 2 January 2 3 1 2 1-butene six-olefins reaction.

HMT的合成一般是以三氯化铝为催化剂,由对异丙基甲苯与新己烯、或2,3一二甲基一2一丁烯等六碳烯烃反应生成。

The results indicate that little conversion of iodobenzene was observed on unmodified carrier supported catalysts; and a conversion of 100% and a selectivity of above 98% to trans-isomers were found over 10%Cu/5%KF/ZnO, 20%Cu/10%KF/ZnO.

结果表明,对碘苯与丙烯酸正丁酯的Heck反应的催化性能,未改性催化剂基本没有活性,而改性后,10%Cu/5%KF/ZnO、20%Cu/10%KF/ZnO催化剂的催化转化率为100%和反式异构体的选择性为98%以上。

Acrylic acid and ester mainly is acrylic acid, methyl acrylate, ethyl acrylate, butyl acrylate, isobutyl acrylate, etc.

丙烯酸及酯主要是指丙烯酸、丙烯酸甲酯、乙酯、丁酯、异辛酯等。

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We have no common name for a mime of Sophron or Xenarchus and a Socratic Conversation; and we should still be without one even if the imitation in the two instances were in trimeters or elegiacs or some other kind of verse--though it is the way with people to tack on 'poet' to the name of a metre, and talk of elegiac-poets and epic-poets, thinking that they call them poets not by reason of the imitative nature of their work, but indiscriminately by reason of the metre they write in.

索夫农 、森那库斯和苏格拉底式的对话采用的模仿没有一个公共的名称;三音步诗、挽歌体或其他类型的诗的模仿也没有——人们把&诗人&这一名词和格律名称结合到一起,称之为挽歌体诗人或者史诗诗人,他们被称为诗人,似乎只是因为遵守格律写作,而非他们作品的模仿本质。

The relationship between communicative competence and grammar teaching should be that of the ends and the means.

交际能力和语法的关系应该是目标与途径的关系。

This is not paper type of business,it's people business,with such huge money involved.

这不是纸上谈兵式的交易,这是人与人的业务,而且涉及金额巨大。