异丁

In comparison with the organic solvents as reaction medium, higher conversion was achieved the tert-ethyl valerate could be formed in the ionic liquid medium.

当反应体系中存在水时，有特戊酸生成。表明反应中2，2，4-三甲基戊烷首先发生β-断裂反应，生成叔丁基正碳离子和异丁烯。

The results showed that the ashless dispersant prepared had low temperature dispersivity.

结果表明，本实验合成获得的聚异丁烯丁二酰亚胺无灰分散剂产品具有低温分散性能。

Low temperature dispersivity of ashless dispersant TEPA was analyzed by the sludge spot distribution test.

以油泥斑点分散试验法对合成产物聚异丁烯丁二酰亚胺无灰分散剂进行低温分散性能测试。

Amination reaction was carried out at temperature of 90℃ to 150℃ for 2h to 10h and then ashless dispersant of polyisobutylene succinimide would be obtained after dehydration with the operations of vacuum distillation and filtration.

结果发现，实验在N_2保护下进行，BPO／PIB质量比为0.035，MA／PIB摩尔比为1.3，反应温度为150℃，反应时间为12h，搅拌速率为250rpm，引发剂过氧化苯甲酰以丁酮为溶剂分六次，时间间隔为30分钟，均量地加入反应器时，烃化反应物聚异丁烯的转化率最高。

The emission amount of tail gas in polyisobutylene succinimide production is very large,and the concentration of oil in the recovered chlorhydric acid by absorption is too high to sell.

针对聚异丁烯丁二酰亚胺生产工艺中废气排放量大、尾气吸收得到的盐酸含油量高、难以销售等问题，在分析原因的基础上，对尾气吸收系统进行了技术改进。

A process for preparingp-fluo-2-(2-methyl-3-propionyl)-4-oxy-N,3-diphenyl-phenylbutylamide includes such steps as Friedle-Craft acylating of newly prepared phenylacetyl chloride and fluorobenzene under catalysis of AlCl3 to obtain 4-fluoro-phenylbenzyl ketone, brominating at carbonyl alpha position under catalysis of less AlCl3 to obtain alpha-bromo-4-fluo-phenylbenzyl ketone, and condensing with isobutyryl acetanilide under action of sodium ethoxide.

本发明涉及一种制备对氟－2－(2－甲基－3－氧丙基)－4－氧－N，3－二苯基－苯丁酰胺(1)的方法，其包括以下步骤：新制的苯乙酰氯与氟苯在AlCl3催化下进行Friedle－Craft酰化反应，得到对4－氟－苯基苄基酮(4)；化合物(4)在少量AlCl3催化下进行羰基α位溴化，得到α－溴－4－氟－苯基苄基酮(5)；然后(3)异丁酰乙酰苯胺在乙醇钠作用下与化合物(5)进行缩合。

SM6 and SM7 of uncrystal were analyzed through GC-MS, the results showedthat SM6 main contained unsaturated fatty aldehyde with fragrance, i.e.-2,4-decadienal(58%), tetradecanoic acid (55.78%), 2-decenal(50%), Phthalic acid isobutylundecyl ester(47%), 2, 4-Decadienal(41%), 2-Undecenal (31%), 2-Methyl-Z,Z-3, 13-octadecadi-enol(18.84%), and SM7 contained saturation alkanes, i.e. 1, 2-Benzenedicarboxylic acid, butyl cyclohexyl ester(23.90%), Triacontane(22.63%),Nonacosane(21.04%), Heptadecane(18.84%), Octacosane(13.58%). Toxicological experiments were done to insure the pigment safety.

并对紫红丝膜菌色素非晶体部分的黄色油状物SM6和紫色粉末物SM7作了GC-MS分析，结果显示SM6中主要为具有香气成分的不饱和脂肪醛，其中含量较高的依次为：-2，4-癸二烯醛(58％)、十四烷酸(55.78％)、2-癸烯醛(50％)、邻苯二甲酸异丁基十一烷酯(47％)、2，4-癸二烯(41％)、2-十一碳烯醛(31％)、2-甲基-Z，Z-3，13-十八碳二烯酸(18.45％)等；SM7中主要为饱和直链烷烃，其中含量较高的依次为：1，2-苯二羧酸丁基环己酯(23.90％)、三十烷(22.63％)、二十九烷(21.04％)、十七烷(18.84％)、二十八烷(13.58％)。

By reacting isobutyraldehyde with diethyl oxalate using sodium methoxide as catalyst,3-methyl-2-oxobutanoic acid,sodium salt was prepared by one pot.

采用甲醇钠催化异丁醛与草酸二乙酯反应，一釜法合成了3-甲基-2-氧代丁酸钠。

Ab initio and density functional theory (B3LYP) in G98 were employed to study the following four direct aldol reactions between acetone and isobutyraldehyde or 3,3-dimethylbutyric aldehyde or benzaldehyde or 4-bromo-phenyl aldehyde catalyzed by-proline .

中文摘要：本文采用G98程序包中的从头计算方法和密度泛函方法计算研究了-脯氨酸催化丙酮与异丁醛、3，3-二甲基丁醛、苯甲醛及对溴苯甲醛的不对称直接羟醛缩合反应，共计四个反应体系。

Bone marrow mesenchymal stem cells could differentiate into osteoblasts, adipocytes and neural like cells with osteoblast inductor (β-sodium glycerophosphate, dexamethasone, vitamin C), lipoblast inductor (dexamethasone, 3-isobutyl-1-methylxanthine, bovine insulin, indometacin) and serum-free medium inductor (dimethyl sulphoxide, butylated hydroxyanisole) respectively. Osteoblast marker (alkaline phosphatase, osteocalcin mRNA, calcium node), adipocyte marker (lipid droplet, PPAR γ-2mRNA) and neural cell-like marker (nissl body, neuron specific enolase, neurofilament protein) were respectively determined by the immunohistochemical method, polymerase chain reaction and immunocytochemical method.

分别采用成骨细胞诱导剂（β-甘油磷酸钠，地塞米松，维生素C）、成脂肪细胞诱导液（地塞米松，甲基异丁酸黄嘌呤，牛胰岛素，吲哚美辛）及二甲基亚砜和羟基丁酸苯甲醚无血清培养基诱导剂干预细胞向成骨、脂肪、神经细胞分化，经免疫组织化学染色、PCR、免疫细胞染色方法检测成骨标志物（碱性磷酸酶、骨钙素mRNA、钙结节）、脂肪标志物（脂滴、PPARγ-2mRNA）、以及类神经标志物（尼克氏体、神经烯醇化酶、神经丝蛋白）。

With Death guitarist Schuldiner adopting vocal duties, the band made a major impact on the scene.

随着死亡的吉他手Schuldiner接受主唱的职务，乐队在现实中树立了重要的影响。

But he could still end up breakfasting on Swiss-government issue muesli because all six are accused of nicking around 45 million pounds they should have paid to FIFA.

不过他最后仍有可能沦为瑞士政府&议事餐桌&上的一道早餐，因为这所有六个人都被指控把本应支付给国际足联的大约4500万英镑骗了个精光。