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底面双晶

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The copper atom is in a planar coordination site of [N_2O_2] and it devites from the mean plane by only 0.80 pm. Byπ-πstacking interactions, a alabastrine structure was obtained.(2)Schiff-base complex [Cu(H_2O)]·H_2O, where H3GS is the 3-carboxyl -salicylidene glycine, was synthesized and characterized by elemental analysis, IR spectra and single-crystal analysis. The crystal belongs to monoclinic system, space group P2(1)/c, a=848.46(3)pm, b=681.54(3)pm, c=1967.16(8)pm,β=95.8210(10)°, Z=4, R_1=0.0279, wR_2=0.0724. The copper atom is in a square-pyramidal field with the base

结果表明该晶系属单斜晶系,空间群P2(1)/c,晶胞参数:a=848.46(3)pm,b=681.54(3)pm,c=1967.16(8)pm,α=90°,β=95.8210(10)°,γ=90°,Z=4,R_1=0.0279,wR_2=0.0724,Cu原子位于轻微变形的四方锥场底心,底面被氮原子、酚氧原子、甘氨酸羧基的一个氧原子和一个水分子氧原子占据,而甘氨酸羧基的另一个氧原子占据相邻分子的锥顶,因而形成一维链状结构;合成了单核双聚配合物Na_2[Cu_2_2]·2H_2O ,铜三核配合物Cu_3_2·5H_2O和铜锌异三核配合物ZnCu_2_2·5H_2O,并用元素分析,IR光谱,电子光谱和磁化率测定对配合物的组

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