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For intramolecular electron transfer reactions in solution,the fluctuations of the intramolecular vibrational modes are much faster than that of solvent mode.Thus,the reaction-diffusion equation is commonly used to describe the motion of solvent,with a sink function to treat the vibrational high-frequency mode.Based on this theory-so -called the Sumi-Marcus theory,we proposed an imaginary-time split operator approach to solve the reaction-diffusion equation.The approach is applied to evaluate the intermolecular ET rate between oxazine 1 and N,N-dimethlaniline.By measuring the two average survival times of the donor state probability and the rate constant in long time limit,the full kinetics of the ET is revealed with a variety of sink functions.

对于扩散控制的溶液中的电子转移反应,分子内振动模的运动比溶剂运动快很多,Sumi-Marcus理论提出用反应扩散方程(reaction-diffusion equation)处理溶剂的扩散运动,而分子内的振动用sink函数来表示,我们基于此理论发展了用虚时间分裂算符的方法(imaginary-time Split operator approach)解反应扩散方程,并将其应用于嗪1(oxazine 1,OX1)和N,N-二甲基苯胺分子之间的电子转移反应,Sink函数采用几种不同的微扰表达式,通过计算得到给体几率衰减的两种平均速率和长时间极限下的速率常数,揭示了该体系电子转移过程中的一些动力学性质。

By analyzing the relationship between the deforming precision of Active Lap and corresponding force generated by moment actuators, a new structure of Active Lap for manufacturing a Φ1800mm, F/1.5 large paraboloidal mirror is obtained. Its progressed performance has been proved with 60 units micro-displacement sensor array.

通过分析能动磨盘的变形精度与对应的驱动器产生力大小的关系,优化设计出适用于Φ1.8m、F/1.5主镜加工的磨盘结构,改善的性能在60路光栅位移传感器阵列上得到验证,新结构磨盘已应用于Φ1.8m、F/1.5抛光面主镜的加工工程中。

To understand the properties of the transfer function of parallel tube-manifold system in wind tunnel test,an analysis is made of several parameters related to the transfer function on the basis of the dissipative model with some qualitative rules on perallel tube-manifold system obtained.

风洞刚性模型测压试验是获得建筑结构风荷载的重要方法。刚性模型的测压管路系统一般包括模型表面的金属短管及连接金属管和传感器的PVC管等管道元件。为了得到结构风压的完整信息,应在模型表面布置尽可能密集的测点。

The opposition is less loved than it should be, given the parlous economy

因经济问题缠身,反对党没能得到它应受的拥护

The act of stealing virtual network property should get the negativity evaluation of the penal code in time.

盗窃网络虚拟财产行为应及时得到刑法的否定性评价。

Secondly, investors' reactions to information should be regulated even if there is a perfect information disclosure system.

第二,即使信息得到完美的披露,投资者对于信息的反应也应作为监管的内容。

Chapter 7. Make use of the unified field equation studied intrinsic magnetic field for planets, got that the magnetic induction equation is satisfied with the motion of planetary inside matter.

第七章 利用统一场方程研究了行星的固有磁场,也得到了行星内部物质运动所应满足的磁感应方程。

It is to be remedied by using those means that shall invigorate the frame, and promote the child''s general health (a daily plunge into the cold bath, or sponging with cold salt water, will be found signally efficacious), and by avoiding the original cause of the distortion never allowing the child to get upon his feet.

它是要予以纠正利用这些手段应振兴的框架内,促进child'一般健康的(每日陷入冷战浴,或海绵冷盐水,会被发现signally有效),并避免原来的事业的失真,决不让儿童得到后,他的双脚。

The minor principal stress of slab, the maximum acceleration in up-down stream direction and permanent deformation of the dam body for three-directional earthquake excitation are obviously different from those for unidirectional and two-directional earthquake loading.

计算表明,多向地震动下的面板峰值小主应力、顺河向峰值加速度及坝体的永久变形均与单向和双向输入时显著不同,实际工程计算时应同时考虑三个方向的地震动;振动型地震激励引起的坝体反应明显大于冲击型地震激励;随着地震动强度的增加,峰值加速度、峰值剪应变、面板应力和周边缝变形等增加;面板刚度对面板的应力值和周边缝的变位具有较大影响,当面板模量取值较低时,计算所得到的"面板"应力集中部位不甚明显,计算结论为新型的"土工膜面板堆石坝"提供了理论依据。

In our experience, manipulation of DRUJ to restore full forearm rotation after rigid fixation of both ulna and radius is a very important procedure to those cases with marked contracture of supination and/or pronation of forearm, also is a kind of prediction of the prognosis.

经验亦告诉我们,在手术中将桡、尺骨做强稳的固定后,术者对DRUJ的manipulation,使前臂得到最大范围的旋转,应是提高术后成绩一个很重要的步骤,尤其是对合并有前臂旋转障碍的病例,同时也是预后的一个指标。

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推荐网络例句

The split between the two groups can hardly be papered over.

这两个团体间的分歧难以掩饰。

This approach not only encourages a greater number of responses, but minimizes the likelihood of stale groupthink.

这种做法不仅鼓励了更多的反应,而且减少跟风的可能性。

The new PS20 solar power tower collected sunlight through mirrors known as "heliostats" to produce steam that is converted into electricity by a turbine in Sanlucar la Mayor, Spain, Wednesday.

聚光:照片上是建在西班牙桑路卡拉马尤城的一座新型PS20塔式太阳能电站。被称为&日光反射装置&的镜子将太阳光反射到主塔,然后用聚集的热量产生蒸汽进而通过涡轮机转化为电力