并四苯

This dissertation deals with the synthetic method of benzotellurazoles containing various substituents in benzene nuclei: introducing tellurium atom to the acetanilide derivatives in ortho-position by direct or indirect ways, then reduced and cyclized to give substituted benzotellurazoles directly or indirectly.

本文系统研究了含各类取代基的苯并碲唑杂环的合成方法，即向原料中用四氯化碲以直接或间接定位的方法引入碲，再经过直接或间接还原关环法制备苯并碲唑。

Benzoin condensation using imidazolium based ionic liquids as solvent for the first time has been successfully achieved. The reaction conditions have been studied in detail. When under 65 and with 0.5 equiv. NaOH in ionic liquid l-butyl-3-methyl-imidazolium tetraborate, benzoin was obtained in excellent yield of 91%. Recycling of ionic liquid has been available.

首次探索并成功实现了在咪唑鎓盐离子液体中进行苯偶姻缩合反应，详细探讨了反应条件，当反应在65℃下和0.5当量NaOH存在下以及在离子液体4-丁基-1-甲基咪唑鎓四氟硼酸盐中进行时，苯偶姻产率可达91％；并对离子液体进行了有效回收再利用。

In part four, a new method of protein assay based on charge-transfer reaction of protein with chloranil has been established.

第四部分，作者首次建立了以四氯苯醌荷移反应测定蛋白质的新方法，并测定了蛋白质结合四氯苯醌的最大结合数和反应平衡常数。

Is now an annual production capacity of calcium chloride, bromide, DecaBDE, DBDPE three bromine phenol, Tetrabromobisphenol A, octabromodiphenyl ether, benzyl bromide, diphenyl ether, dibenzo ethane and other chemicals, 5,000 tons of bromine, hydrogen bromide by-product 5000 tons, the product export to Europe and Southeast Asia market, the company owns self import and export rights, and have passed the ISO9001: 2000 certification, is the most full-bromine chemical species, product quality, one of the best high-tech enterprises.

现已形成年产氯化钙，溴素，十溴二苯醚、十溴二苯乙烷、三溴苯酚、四溴双酚A、八溴醚、溴化苄、二苯醚，二苯乙烷等各类溴化学品5000吨，副产溴化氢5000吨，产品出口欧洲和东南亚市场，公司拥有自营进出口权，并已通过ISO9001：2000认证，是国内溴化学品种最全、产品质量最好的高新技术企业之一。

1 To mimic the active centers of tyrosinate iron enzymes whichcontain phenolate donors, new tripodal ligand, N-(2-hydroxybenzyl)-N, N-bis(2-benzimidazolymethyl) aminewhich contain imidazoleand phendate groups were designed and synthesized and its iron com-plexes 〓(2)(where Mim=N-Methylimidazole) and Fe 〓(3) were prepared andcharacterized by various spectroscopic methods.

1.1 为了模拟酪酸铁酶活性中心，设计并合成了含有酚羟基和苯骈咪唑基四齿配体N，N-(2-羟基苯)-N，N-二氨，并合成它的铁配合物：Fe〓、Fe〓〓(2)和Fe〓，并经各种谱学手段表征了这些铁配合物。

They are 4-(2- hydroxy-3-butynlenoxy) benzoic acid (1, WA), 5-chloro-7, 8-dihydroxy-7-methyl- 6-oxo-3- [ -3, 4-dihydroxy-3, 5-dimethyl-l-heptylene] -1H-8, 8a-dihydrobenzo [2, 3-c] pyran (2, WB),-2-(2-methyl-2-dibutene diamido)-2-butenoic acid (3, B5262), 3, 4-dihydro-9, 10-dihydroxy-7-methoxy-3-methyl-1H-naphtho [2, 3- c] pyran-1-one (4, A73 semi-Vioxanthin), 8, 8'-bis (6, 9-dioxo-3,4-dihydro-10- hydroxy-7-methoxy-3-methyl-1H-naphtho [2, 3-c] pyran-1-one)(5, A122 Xanthomegnin), 2, 5-dioxo-3a-hydroxymethyl-3, 3a, 6, 6a-tetrahydro-furo [2, 3-b] furan (6, 1003-2), 7-acety1-5-chloro-6, 8-dioxo-7-methyl-3- [ -3, 5-dimethyl-1, 3- diheptylene] -4aH-benzo [2, 3-c] pyran (7, M2-2 sclerotiorin), respectively.

它们分别被命名为4-（2-羟基-3-丁炔氧基）苯甲酸（1，WA）、5-氯-7，8-二羟基-7-甲基-6-氧代-3-[-3，4-二羟基-3，5-二甲基-1-庚烯基]-1H-8，8a-二氢苯并[2，3-c]吡喃（2，WB）、-2-（2-甲基-2-丁烯二酰亚胺基）-2-丁烯酸（3，B5262）、3，4-氢-9，10-二羟基-7-甲氧基-3-甲基-1H-萘并［2，3-c］吡喃-1-酮（semi-Vioxanthin，4，A73）、8，8'-双（6，9-二氧代-3，4-二氢-10-羟基-7-甲氧基-3-甲基-1H-萘并［2，3-c］吡喃-1-酮）（Xanthomegnin，5，A122）、2，5-二氧代-3a-羟甲基-3，3a，6，6a-四氢-呋喃并［2，3-b］呋喃（6，1003-2），7-乙酰基-5-氯-6，8-二氧代-7-甲基-3-［-3，5-二甲基-1，3-庚二烯基］-4aH-苯并2，3-c］吡喃（Sclerotiorin，7，M2-2）。

The synthesis method of the invention is as follows: first, 5-amino-2-(p-aminophenyl)- benzoxazole and aliphatic diacid are respectively recrystallized; NMP is distilled; solubilizer is dried; second, in an atmosphere of nitrogen, after Py and NMP are mixed evenly and added to a sealed reactor, the solubilizer is added into the reactor, followed by the 5-amino-2-(p-aminophenyl)- benzoxazole, then the mixture in the reactor is stirred; second, in an atmosphere of nitrogen, the mixture in the second step is stirred and heated to 50-150 DEG C, then the aliphatic diacid is added, followed by TPP for condensation; fourth, after methanol is poured into the reactor, the sediment is separated out from the mixture, filtered, washed and dried, so the semi-aromatic polyamide containing oxazole ring is obtained.

本发明的合成方法如下：一、分别重结晶5-氨基-2-苯并唑与脂肪族二酸；蒸馏NMP；干燥增溶剂；二、在氮气气氛下，Py与NMP混匀后加入密封的反应器中，再加入增溶剂，然后加入5-氨基-2-苯并唑，搅拌；三、在氮气气氛下，将步骤二的混合液搅拌并升温至50℃～150℃后加入脂肪族二酸，再加入TPP后缩聚；四、再倾入甲醇析出沉淀，过滤，清洗沉淀，再干燥；即得到含唑环半芳香聚酰胺。

Four series and sixteen solid complexes of rare earth chloride with 1-naphthoic acid (L_1),benzoic acid (L_2),phenylacetic acid (L_3) and Mandelic acid (L_4) have been synthesized by method of solid state reaction at low temperature,and then these complexes were characterized by chemical analysis methods.

本文采用低温固相合成法，以稀土氯化物、1—萘甲酸(HL_1)、苯甲酸(HL_2)、苯乙酸(HL_3)、苯羟乙酸(HL_4)为原料，以六次甲基四胺为质子受体，合成并表征了四个系列十六种固态配合物。

The optimum reaction condition for preparation of CoPcY is as follows: a , using CoCl2 as the exchanged salt ; b , complexation temperature of 180 ; c . complexation catalyst of NH4C1 and A1C13 .2, The unsymmetrically substituted cobalt phthalocyanine complexes were synthesized by statistical condensation of phthalic anhydride and tetrabromophthalic anhydride, and further immobilized in MCM-41 molecular sieves by zeolite synthesis method, as well as characterized by XRD,FT-IR,DRS, 1HNMRetc. The catalytic property of CoPcBrx/MCM-41was tested by cyclohexane oxidation using H2O2 or t-BOOH as oxidant.

2采用本路线制备CoPcY的最佳条件为：a、采用氯化钴作为待交换的金属盐；b、络合温度以180℃为宜；c、起始反应物为苯酐、尿素、氯化铵、氯化铝、CoY时，制备出的CoPcY的催化性能最好； 2、首次采用苯酐和四溴苯酐均相浓缩统计合成法制得了不对称取代的金属钴酞菁络合物，并采用~1HNMR、FTIR、DRS等对其进行了结构表征；此外，采用沸石合成法将其固定于MCM-41中孔分子筛，并对其催化性能进行了考察。

Bisbenzimidazolium salts were used as a tetrahydrofolate coenzyme model, and thus the biomimetic synthesis of twenty-four acyclic diketones as precursors for macrocyclic ketones was successfully accomplished by using the addition-hydrolysis reaction of the bisbenzimidazolium salts with alkyl magnesium halide, wherein six diketones have not been reported in literature.

在本文中，受四氢叶酸辅酶的一碳单元转移反应的启发，作者以双苯并咪唑盐作为四氢叶酸辅酶模型，利用格利雅试剂与双苯并咪唑盐的加成-水解反应，成功合成了二十四种作为麝香酮及类似大环酮重要前体的长链二酮，同时，提供了一种麝香酮及类似大环酮的仿生合成新方法。

This one mode pays close attention to network credence foundation of the businessman very much.

这一模式非常关注商人的网络信用基础。

Cell morphology of bacterial ghost of Pasteurella multocida was observed by scanning electron microscopy and inactivation ratio was estimated by CFU analysi.

扫描电镜观察多杀性巴氏杆菌细菌幽灵和菌落形成单位评价遗传灭活率。