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平衡浓度

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According to the experimental data,the equilibrium phase diagram and the physico-chem.

采用等温蒸发法研究了四元体系K+、Na+∥CO32-、HCO3--H2O 35℃相平衡及平衡液相的密度、电导率、折光率和pH值,测定了该四元体系在35℃条件下平衡溶液的浓度及物化性质。

Fifty female patients who were selected to schedule for mammary gland tumor excision surgery, were divided into 2 groups(n=25 in each group): group A: received propofol's half-effective concentration at 3.0 μg/ml in Marsh model by TCI; group B: received propofol's half-effective concentration at 4.0 μg/ml in Marsh model by TCI. All patients were given remifentanil in Minto model by TCI after being given propofol which reached the balance between effect-site concentration and blood plasma concentration. The target concentration of remifentanil was determined by a modification of Dixon's up-and-down method. Laryngeal mask insertion was attempted after 10 mins, the insertion condition and success rate were observed, then the suitable target concentration of remifentanil(ECe50) were calculated.

50例女性乳腺良性手术患者随机分为2组(n=25),A组:靶控输注丙泊酚效应室浓度3.0 μg/ml;B组:靶控输注丙泊酚效应室浓度4.0 μg/ml(均为Marsh药代模型),待其效应室浓度和血浆浓度达平衡后给予靶控输注效应室浓度瑞芬太尼,运用Dixon's序贯法确定喉罩置入时瑞芬太尼浓度,10分钟后置入喉罩并观察喉罩置入条件与成功率,计算出相应的瑞芬太尼适宜靶浓度(ECe50值)。

Through the experiments on hydration of AH in the following sulphate(Li_2SO_4、MgSO_4 、 Al_2(SO_4)_3 、MnSO_4 、CuSO_4 、CoSO4 、CdSO_4 、ZnSO_4 、NiSO_4 、FeSO_4), dissoluble sulfate hydrate origining from hydration process of AH affects it's hydrous rate, hydrous rate of AH does not connect with Z/R of cation in stimulation, theory that Z/R affect hydrous rate of AH does not exist. Third, hydration of AH in dissoluble sulfate complies with dissolve-nucleate -grow theory, concentration of Ca~2+ from dissolving of CaSO_4 is higher than one of CaSO_4·2H_2O, calcium sulphate dihydrite gets a motivity of crystallization. dissoluble sulfate takes the following function: double-salt or dissoluble sulfate hydrate from hydration of AH in it becomes heterogeneous particle and a kind of nucleation catalyzer, and reduces surface barrier when DH becomes crystal because the crystal of DH precedently appears in uneven place. Results indicate hydration of AH does not conform with double-salt theory, but it conform with this mechanism: dissolve-nucleate-grow, formation of DH is an uneven nucleation and crystalizaion process.

通过对CaSO_4在Na_2SO_4 、K_2SO_4 、Rb_2SO_4 、Cs_2SO_4 、(NH_4)_2SO_4溶液中水化过程,以及CaSO_4·2H_2O、CaSO_4与以上硫酸盐反应速度、产物的研究,说明复盐理论不正确;CaSO_4在(Li_2SO_4、MgSO_4 、 Al_2(SO_4)_3 、MnSO_4 、CuSO_4 、CoSO_4 、CdSO_4 、ZnSO_4 、NiSO_4 、FeSO_4)溶液中水化,水化过程中硫酸盐水合物的析晶影响着无水硫酸钙水化,与激发剂阳离子Z/R值大小无关,阳离子的Z/R参数影响水化率的规律并不存在; 3、无水硫酸钙在可溶性硫酸盐中的水化按照溶解-成核-生长理论进行,CaSO_4达到溶解平衡时Ca~2+的浓度大于CaSO_4·2H_2O溶解平衡的Ca~2+的浓度,CaSO_4·2H_2O获得结晶的驱动力,可溶性硫酸盐起到形成晶核的作用:水化过程与CaSO_4生成复盐或析出水合物所形成的细小物相,作为异质微粒使母相中存在不均匀性,这些不均匀性有效地降低成核时的表面能位垒,使CaSO_4·2H_2O晶核优先地在这些具不均匀性的地方形成,因此这些物质起成核催化剂作用。

The gel dynamics experiments showed that the gel formation law was similar with the other polymer systems, which wasrelated with dense surface under the soft coagulating condition and the thickening gel; the square of gel thickness was linear with coagulation time. The qualitative analysis of the surface puckers of fibers spun from wet spinning and dry-jet wet spinning was made. The positions where the die swell appeared were not the same and the die swell appeared at the air gap where the fiber would markedly been elongated and vary little in the coagulant, thus the surface of fiber spun from dry-jet wet spinning was more smooth. The radial component concentration gradient was responsible for the radial structure of PAN fiber spun from dry-jet wet spinning. The thicker surface with microvoid structure of

对湿纺和干湿纺进行比较表层沟槽的产生进行定性分析,原因在于孔口胀大区域出现在不同位置,在干湿纺中,溶液的孔口胀大出现在空气层,并在该区完成大部分形变,进入凝固浴后形变很小,纤维表面较为光滑;干湿纺PAN纤维径向结构存在差异,这与丝条内组分由于双扩散进行导致径向上存在浓度差异直接相关;凝固强度较大的体系,可以获得厚度较大且孔结构尺寸较小的皮层;含较少缠结的PAN原液在纤维成形后截面很圆整,但原液缠结浓度增大时成形后圆整度下降;PAN纤维成形是一个远离平衡的过程,凝固作用缓和的体系可以使成形过程靠近平衡,可获得更大尺寸的孔洞结构;原液中少量的非溶剂添加剂显著改变纤维径向结构,可获得孔洞尺寸更小和更为均一的径向结构,这与径向浓度差异的减小、分相时间的集中相关;PAN原液的成形纤维表面依赖于凝固强度;由AFM对相近凝固条件下成形的PAN膜进下

Under the steady state assumption, equilibrium concentration of benzo pyrene in air is very low (1. 3×10〓mol/m〓) with almost all of the chemical absorbed on particles.

稳态条件下,气相中苯并芘的平衡浓度相当低,仅1.3×10〓mol/m〓,且在气相中几乎所有的物质都吸附在颗粒物上,以气态形式存在的量微不足道。

It was revealed that the balanced DO concentration appeared soon after the reaction stage starting,and DO level rose quickly in large range when COD was degraded to its nondegradation concentration under that condition,no matter that change the aeration rate or the MLSS concentration in large range,or change the initial COD concentration gradually or suddenly in the various experimental conditions.

结果表明,无论使曝气量或初始污泥浓度大幅度变化,还是逐渐或突然改变初始有机物浓度等各种试验条件,都会在反应阶段开始不久出现所谓平衡DO浓度现象;当有机物达到其难降解浓度时DO浓度迅速地大幅度升高。

The effects of solution\'s pH value, mol ratio between phenyl aldehyde and L-Arginine, concentrations of sodium chloride, ammonia chloride andL-Lystine, initial concentration of L-Arginine on precipitation rate of a -tolylene arginine were investigated, the results indicated that phenyl aldehyde precipitation method\'s appropriate pH value was higher than 11, suitable mol ratio between phenyl aldehyde and L-Arginine was 1.25, initial concentration of L-Arginine was must higher than 15g/L, sodium chloride had little effect on precipitation rate, on the contrary, ammonia chloride and L-Lystine had great effect on it, both of them must be eliminated; At the same time, adsorption isotherm at 25 C of L-Lystine on anion exchange resin A was measured, the result showed that the maximal equilibrium adsorbance was 30mg/g, the influences of solution\'s pH value, temperature, concentration of chloride ion on adsorption of L-Lystine by anion exchange resin A were also studied, the results indicated that appropriate operational pH value was 0.5 0.2, the effect of temperature on adsorption ratio was little, process could be operated at room temperature, the concentration of chloride ion must be eliminated.

考察了溶液pH值、苯甲醛与L-精氨酸摩尔比、氯化钠与氯化铵浓度、L-赖氨酸浓度、L-精氨酸初始浓度对苯甲醛沉淀L-精氨酸的影响,结果表明,沉淀反应的适宜pH值大于11,苯甲醛与L-精氨酸的适宜摩尔比为1.25,(来源:Aa6BC论文网www.abclunwen.com)L-精氨酸适宜的初始浓度在15g/L以上,氯化钠的存在对沉淀率基本上没有影响,而氯化铵和L-赖氨酸的存在使沉淀率下降;同时测定了25℃时阴离子交换树脂A吸附L-赖氨酸的吸附等温线,表明其最大平衡吸附量为30mg/g,考察了溶液pH值、温度、氯离子浓度对阴离子交换树脂A吸附脱除L-赖氨酸的影响,结果显示从L-精氨酸和L-赖氨酸混合液中吸附分离出L-赖氨酸的适宜pH值为10.5±0.2,温度对L-赖氨酸吸附率影响不大,吸附过程可在室温下进行,氯离子的存在使L-赖氨酸的吸附率降低。

An attempt was made to remove color from simulated wastewaters containing Acid Scarlet GR and Reactive violet K-3R by cloud point extraction using a nonionic surfactant of Triton X-114. The influence of the concentrations, equilibrium temperature and equilibrium time on the extraction efficiency was tested. The experimental results show that the extraction efficiency to dye increases with increasing concentration of TX-114 and salt or decreasing initial dye concentration.

本文选用非离子表面活性剂TX-114作浊点萃取剂,研究了由酸性大红与活性紫构成的单元和二元混合染料模拟有色废水的萃取脱色过程,讨论了表面活性剂浓度、染料浓度、盐浓度、平衡温度、平衡时间等因素对萃取效率的影响结果表明,提高表面活性剂浓度、盐浓度有利于提高萃取效率,而染料浓度增加则使萃取效率略有下降。

Through various means (for example, to inject a small number of PN junction carrier) disturbance belt electronic price band Hole and the balance of concentration, according to which non-minority-carrier in the compound and a photon.

通过各种方法(例如向PN结注入少数载流子)扰动导带电子和价带空穴的平衡浓度,致使非平据少数载流于复合而产生光子。

The empirical Freundlich equation was successfully employed to describe the adsorption process. Due to hydrogen-bonding interaction between the tertiary amino groups on the resin and the amino groups of p-methylaniline, the adsorption capacity towards p-methylaniline of NDA-8 is higher than that of NKA when the equilibrium concentration is 5 mmol/L.

结果表明:2种树脂吸附对甲苯胺均符合Freundlich等温吸附方程,NDA-8树脂表面叔氨基与对甲苯胺之间的氢键作用可有效强化吸附能力,在平衡浓度均为5mmol/L的情况下,其吸附容量达到NKA的1.5~1.6倍。

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