平衡常数

Clau (5, 10, 20〓) was bound to rat plasma a greater extent than clau, while in rabbit plasma the reverse was the case. By Scatchard plots using bovine serum albumin, clau had a higher equilibrium constant and the greater numbers of binding sites than its antipode.

在与大鼠血浆蛋白的结合中，clau的结合率平均为28.37±0.31（n=3，三个剂量5，10，20μM），clau的结合率平均为38.05±2.61（n=3），clau结合率低于clau；而在与兔血浆蛋白的结合中，clau的结合率平均为47.21±4.91（n=3，三个剂量），clau的结合率平均为41.43±5.21（n=3），clau的结合率略高于clau；在与牛血清白蛋白的结合中，clau的结合率也高于clau，立体选择方向与兔血浆蛋白结合相同，而与大鼠血浆蛋白结合相反，提示存在种属差异；在与系列浓度的牛血清白蛋白结合中，通过Scatchard作图法求得蛋白结合点数和平衡常数；在clau，N和K分别为90.02±35.76和5.326±1.196（n=4）；在clau，N和K分别为59.92±20.39和4.203±1.250（n=4），两者的比值分别为1.50和1.27；进一步说明clau对映体的蛋白结合存在立体选择性差异。

Formulas of distribution ratios of ethanol and butanol were proposed, and calculated results coincide with experimental results.

由实验数据回归出了络合剂与醇的络合比及络合萃取平衡常数，建立了醇的分配系数的关联式。

In part four, a new method of protein assay based on charge-transfer reaction of protein with chloranil has been established.

第四部分，作者首次建立了以四氯苯醌荷移反应测定蛋白质的新方法，并测定了蛋白质结合四氯苯醌的最大结合数和反应平衡常数。

Extraction mechanism of chlorophenol for alcohol was also investigated by infrared spectrogram of loaded organic phase.

酚类对醇类稀溶液提供的络合萃取平衡常数与络合剂化学结构存在密切的关系。

The thermodynamic parameters in the separation of enantiomers of amino acid derivatives and diastereomers of cinchona alkaloids were calculated and the dissociation constants of cinchonine and cinchonidine on the cinchonine imprinted monolithic disk were determined by frontal analysis.

计算了氨基酸衍生物对映体以及辛可纳非对映异构体分离过程的热力学参数并利用前沿色谱法测定了辛可宁和辛可尼丁在盘状分子印迹整体柱上的离解平衡常数。

As the sample of Yuanliangshan tunnel in Chongqing-Huaihua Railway, based on the full analysis of groundwater specimens, five chemical equations are designed to calculate evaluating data by the relation of activity, equilibrium constant and Gibbs free energy. According to the two criterion of partial pressure of carbon dioxide and reaction direction, the result calculated shows the groundwater has weak corrasion to carbonate rocks, which should be avoided to do harm to tunnel.

以渝怀线圆梁山隧道为实例，通过隧道内地下水取样进行了全分析，其中CO(上标 2-下标 3)离子作为"中间过渡态"离子，由于只存在微小量未被检出；使用水质分析结果数据设计了五个化学反应方程式，通过活度、反应平衡常数及吉布斯自由能之间关系进行热力学计算，依据二氧化碳气体分压P(下标 CO2)与反应进行两个方向化学反应判据开展分析，结果表明地下水具有弱侵蚀性，在隧道工程中应避免其引起危害。

By using equilibrium constant, activity coefficient, water activity and relative humidity of deliquescence properties in secondary aerosol model, we set the model and tested the sensitiveness.

本论文的研究内容主要将大气中二次气胶生成机制并入光化学轨迹模式中，利用大气气相-气胶之间热力动性质平衡常数(K、活性系数、水活度、相对潮解湿度，建置二次气胶模组，并测试二次气胶模组对各影响因子的敏感度。

The features of this dissertation are lie in: a The concept of"Influence Distance"was presented to quantitatively express"corner effect", systematicly studied on the influence of all factors on"influence distance". It could provide reference to angle designing from the view of heat treatment; b Deeply studied on the influence of shape factor to carbon concentration field. It could provide reference to gear designing from the view of heat treatment; c New model was set up to describe the two-dimensional concentration field of carbide dispersion carburizing. The shortcomings of"effective diffusion constant method"and"equilibrium constant method"were overcome in this model.

本文的特色在于：①提出了用"尖角影响距离"定量描述"尖角效应"的方法，并系统研究了各种因素对"尖角影响距离"的影响规律，从热处理角度为工件尖角部位的设计提供依据；②首次深入研究了齿轮的各种形状因素对浓度场的影响，从热处理角度为齿轮设计提供依据；③建立了能够更有效地模拟过饱和渗碳浓度场的数学模型，该模型克服了"有效扩散系数法"及"平衡常数法"的不足，与"最小自由能法"可互为补充。

Natural gas process ; balance constant ; vaporation rate ; calculation method ; gas-liquid balance.

天然气加工；平衡常数；汽化率；计算方法；汽液平衡

DSC thermal analyzer, X-ray diffractometry, Infrared thermal photography technique, Mossbauer spectra, High resolution electron microscope, Positron annihilation techniques, Infrared absorption spectra, Internal friction analyzer with an inverted torsion pendulum, magnetic balance and melt spinning technique were employed in the tests.

本文采用钡蒸气平衡法，用柔性石墨密封的钼反应室，使用自制的TiN和BaS坩锅，在双温带钼算炉内，测定了纯铁液中Ba-O、Ba-S和Ba-P反应的平衡常数和活度相互作用系数，测定了Ni，Cr，Ti，Si，Al对钡的活度相互作用系数以及钡在纯铁液中的溶解度。

Breath, muscle contraction of the buttocks; arch body, as far as possible to hold his head, right leg straight towards the ceiling (peg-leg knee in order to avoid muscle tension).

呼气，收缩臀部肌肉；拱起身体，尽量抬起头来，右腿伸直朝向天花板（膝微屈，以避免肌肉紧张）。

The cost of moving grain food products was unchanged from May, but year over year are up 8%.

粮食产品的运输费用与5月份相比没有变化，但却比去年同期高8％。