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Linear solvation energy relation was firstly introduced in the paper, and the method and step of gaining the special parameters of solvent and solute were introduced in detail, and these special parameters were used to selection and optimization of extractive agent in extractive distillation. The model of predicting activity coefficient at infinite dilution was established by linear solvation energy relation. By the above theory, several candidate solvents were selected to separate C5 fraction, and by experiment of vapor-liquid phase equilibrium at atmosphere pressure, the mixture of N-methyl-pyrrolidone including 4% water was used extractive agent of separating C5 fraction. Then binary vapor-liquid phase equilibrium of the some compound in C5 fraction and N-methyl-pyrolidone were determined at atmosphere pressure and correlated by NRTL equation. Isoprene being objective compound, experiments were operated in the laboratory-scale column; the processes were simulated by RadFrac model in ASPEN PLUS. And by the combination of experiment and simulation, the new process of separation of C5 was established.

本文首先对线性溶剂化能关系进行了分析介绍,也介绍了采用溶剂化能关系得到溶质溶剂特性参数的方法步骤,并将这些参数用于萃取精馏萃取剂的选择与优化;也通过线性溶剂化能关系式建立无限稀释活度系数预测模型,取得了一定的预测精度;将通过上述方法初选的溶剂进行了常压汽液平衡的测定研究,通过实验研究选定含水4%的N-甲基吡咯烷酮溶液做为C5分离的萃取剂,测定了大量N-甲基吡咯烷酮与C5组分的二元平衡数据,并进行关联计算;以异戊二烯为目标产物在实验室规模的精馏塔内进行了C5分离的实验研究,取得大量塔内数据;通过选用合适的热力学模型,采用ASPEN中RadFrac模块对分离过程进行模拟研究,通过实验与模拟相结合,建立了C5分离的新工艺,为将来的工业化打下了坚实的基础。

Some approved aneugens Trip terygiuwlIypogaucum (evelHutch, colchicine, thiabendazole, a tropine sulfate,d-ubocurarine was added into the reactive system respectively and the changes of their absorption values were taken down during different periods under the conditions of 37 0C and 350nm .

本研究通过多步聚合和解聚合反应从猪脑中分离纯化微管蛋白,建立微管蛋白的体外聚合和解聚合反应平衡体系,并将已证实的非整倍体诱发剂(昆明山海棠根部水抽提物、2-(4′-噻唑)苯丙咪唑、硫酸阿托品、d-筒箭毒碱)分别加入此反应平衡体系中,于37℃、350nm条件下,记录此体系不同时期的吸光值变化,与阳性对照物和溶剂对照处理平衡体系后的吸光值在相同时间点作比较,以此评估这几类非整倍体诱发剂对离体条件下的微管蛋白聚合的影响,寻求这几类非整倍体诱发剂是否可通过抑制微管蛋白聚合作用途径而诱发非整倍体。

The free energy for PPS crystals formed during the crystallization isothermally from melt decreased by incorporating POI in to the matrix.

POI是PPS的增塑剂,成核剂和扩链剂,与POI共混使得PPS结晶速率增加,平衡熔点上升,表面折叠自由能降低。

Combining chemical complexation and physics extraction of monobasic and polybasic carboxylic acid, the universal liquid-liquid equilibrium model with clear physical meaning was successfully induced.

详细研究了萃取剂浓度、稀释剂浓度、水相pH值、温度和羧酸初始浓度等因素对络合萃取平衡的影响以及萃取剂的再生条件。

By introducing amphiphilic balance (P0),hydrophilic balance,and amphiphilic matching coefficient,the amphiphilic balance and comb-shaped copolymers of the polycarboxylate superplasticizer were investigated.

通过引入两亲平衡值(P0)、亲水平衡因子、两亲匹配系数等概念对共聚物减水剂两亲平衡、结构与性能关系进行了研究。

Solid desiccants Solid desiccants are characterized by an internal porous structure that contains very large internal surface areas with very small radii of curvature. The equilibrium partial pressure of water vapour above such concave surfaces is much less than that above plane surfaces and so solid desiccants exhibit a very great affinity for water.

坚实干燥剂坚实干燥剂为包含非常大内部表面以非常小半径曲度的一个内部多孔结构描绘。water.vapour 平衡部份压力在这样凹面表面之上是较少比那在平面表面之上和因此坚实干燥剂陈列非常巨大亲合力为水。

The uptake rate and equilibrium time of organochlorine pesticides were obtained during the laboratory experiment. All the equilibrium time are 594 hours except that δ-BHC's is 234 hours and both p, p'-DDE and o, p-DDT's are 70 hours. Uptake rates of α-BHC, hexachlorobenzene,β-BHC,γ-BHC,δ-BHC, heptachlor, aldrin, heptachlor epoxide, p, p'-DDE, dieldrin, endrin, p, p'-DDD, o, p-DDT and p, p'-DDT are 0.061, 0.071, 0.098, 0.066, 0.033, 0.014, 0.007, 0.062, 0.108, 0.052, 0.029, 0.032, 0.061mL/h, respectively.

得出了有机氯农药在水相和半透膜之间分配的平衡时间和富集系数,平衡时间除δ-BHC为234h和p,p'-DDE、o,p-DDT为70h外,其余组分均为594h;α-BHC、六氯苯、β-BHC、γ-BHC、δ-BHC、七氯、艾氏剂、七氯环氧、p,p'-DDE、狄氏剂、异狄氏剂、p,p'-DDD、o,p'-DDT、p,p'-DDT富集系数分别为:0.061、0.071、0.098、0.066、0.033、0.014、0.007、0.062、0.108、0.052、0.029、0.032、0.061mL/h。

Technical grade propylene(92-93 percent,the balance being propane ) and anhydrous fertilizer grade ammonia are satisfactory.

技术级的丙烯(92-93%,平衡剂为丙烷)和无水化肥级氨水就能满足要求。

The evaluation methods for coke factor and gas factor of FCC equilibrium catalysts were discussed.

探讨了催化裂化平衡剂生焦因子和生氢因子的评价方法。

The influence of operation condition, metal content of equilibrium catalysts and properties of feed oil on coke factor and gas factor was investigated.

考察了操作条件、平衡剂金属含量以及原料油性能对生焦因子和生氢因子的影响规律。

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