常压

Based on corn cobs , a pretreatment process in modest conditions atmospheric pressure and moderate reaction temperature was designed to fractionate lignocellulose by using formic acid .

以玉米芯为研究对象，提出了常压中温条件下甲酸预处理木质纤维素组分分离的工艺。

In the one half part, according to the strontium nature, thermodynamic calculation of correlative reaction and the principle of the vacuum aluminothermy reduction process, with the laboratory findings of preparation strontium by vacuum aluminothermy reduction compared and analyzed in different parameter conditions, a variety of factors which effect the decomposition rate of SrCO_3 and the percent reduction of strontia are gotten out. The factors include that the decomposition rate of SrCO_3 is influenced by different addition and pressure. They also include that the percent reduction of strontia is influenced by excess coefficient of reducing agent aluminium powder, the particle size of raw material or reducing agent, the pressure of barbecuing, temperature and reduction time. According to those, we can draw the conclusion as follows:(1) Decomposition temperature of SrCO_3 is decreased by adding carbon and alumina in different degree.(2) With quantitative carbon added under the vacuum condition, the decomposition temperature of SrCO_3 is decreased obviously, which can fall 150℃ compared with atmospheric pressure.(3) In keeping 1150℃ of 2.5h, under the 5Pa vacuum condition, the decomposition rate of SrCO_3 nearly keeps in 99% steadily.

在前半部分的真空铝热还原法中，根据锶的性质、相关反应的热力学计算及真空铝热还原法原理，通过对不同参数条件下的真空铝热还原法生产金属锶的实验结果的分析比较，得出了影响SrCO_3的分解率和氧化锶的还原率的种种因素，具体因素包括不同添加剂、不同气压对SrCO_3分解率的影响，还原剂铝粉的过量系数、原料与还原剂的粒度、制团压力、温度和还原时间等对氧化锶还原率的影响，得出具体结论如下：(1)添加碳和Al_2O_3能不同程度的降低SrCO_3的分解温度；(2)真空条件下加入一定量的碳可显著降低SrCO_3的分解温度，比之常压下可降低150℃之多；(3)在1150℃恒温2.5h、真空度达到5Pa的条件下，SrCO_3的分解率几乎保持稳定在99％；(4)氧化锶的还原率随还原剂过量系数的增大而增大，但是趋势越来越小，当过量系数超过25％后，氧化锶的还原率几乎不再增加；(5)氧化锶的还原率随原料与还原剂的粒度的变细而增加；(6)氧化锶的还原率随制团压力的增加而增加，但超过一定值后，氧化锶的还原率反而会下降；(7)氧化锶的还原率随还原温度的升高而增加；(8)氧化锶的还原率随还原时间延长而增加，在本实验条件下，超过2.5h趋于稳定。

Theoretical Part: Through theoretical analysis of chemothermodynamics, combustion and engineering thermodynamics, factors that affect explosion limit were determined, which include temperature, pressure, spark ignition energy, electrode shape, direction of flame propagation and size of explosion vessel.

理论部分：根据化学热力学、燃烧学和工程热力学的基础理论，从本质上定性地分析了爆炸极限的影响因素，包括温度、压力、爆炸容器的大小、点火能量大小、以及火焰传播方向等，得出了这些影响因素对爆炸极限的影响规律，以确保实验有完整的理论基础指导；在此基础上本文提出了一种新的推算在常温常压下可燃性纯质和混合工质制冷剂爆炸极限浓度的理论方法，该方法由可燃性气体的化学组成来推算上下限浓度，不需要其它条件；对混合工质制冷剂，只要再知道混合配比，即可以推算出爆炸极限，使预测爆炸极限的工作更简单、方便。

Linear solvation energy relation was firstly introduced in the paper, and the method and step of gaining the special parameters of solvent and solute were introduced in detail, and these special parameters were used to selection and optimization of extractive agent in extractive distillation. The model of predicting activity coefficient at infinite dilution was established by linear solvation energy relation. By the above theory, several candidate solvents were selected to separate C5 fraction, and by experiment of vapor-liquid phase equilibrium at atmosphere pressure, the mixture of N-methyl-pyrrolidone including 4% water was used extractive agent of separating C5 fraction. Then binary vapor-liquid phase equilibrium of the some compound in C5 fraction and N-methyl-pyrolidone were determined at atmosphere pressure and correlated by NRTL equation. Isoprene being objective compound, experiments were operated in the laboratory-scale column; the processes were simulated by RadFrac model in ASPEN PLUS. And by the combination of experiment and simulation, the new process of separation of C5 was established.

本文首先对线性溶剂化能关系进行了分析介绍，也介绍了采用溶剂化能关系得到溶质溶剂特性参数的方法步骤，并将这些参数用于萃取精馏萃取剂的选择与优化；也通过线性溶剂化能关系式建立无限稀释活度系数预测模型，取得了一定的预测精度；将通过上述方法初选的溶剂进行了常压汽液平衡的测定研究，通过实验研究选定含水4%的N-甲基吡咯烷酮溶液做为C5分离的萃取剂，测定了大量N-甲基吡咯烷酮与C5组分的二元平衡数据，并进行关联计算；以异戊二烯为目标产物在实验室规模的精馏塔内进行了C5分离的实验研究，取得大量塔内数据；通过选用合适的热力学模型，采用ASPEN中RadFrac模块对分离过程进行模拟研究，通过实验与模拟相结合，建立了C5分离的新工艺，为将来的工业化打下了坚实的基础。

Working fluid is provided at constant pressure and temperature.

工质是在常压和常温下提供的。

In our work, a new continuous thermodynamics method for petroleum fraction phase equilibrium calculation has been proposed, in which true boiling point distillation curves for petroleum fractions were considered to be a continuous distribution function and the distribution variable was TBP temperature, and at the same time, a spline method was used in the distribution function calculation.

在以上工作的基础上，建立了具有普遍实用性的常压塔精馏计算的数学模型，并对多个工业装置进行了实际的模拟，模拟结果与装置的实际情况符合良好，在预测塔的抽出温度，抽出产品的性质，以及各个侧线产品收率等方面都得到满意的结果。

In the experiment, compared to atmosphere distillation, low-pressure distillation is proved to be able to save more nourishment, remain more yeast for the fermentation with cornstalk and finally give more energy saving.

与常压精馏相比较，低压低温精馏能够减少醪糟中营养物质的损失，更多地保存了酶活力和发酵菌体的活性，为醪糟进行下一步的秸秆固态发酵饲料生产提供保证；而且有利于进行浓醪精馏，实现大幅度的节能。

First we study the the structure of cryolite in the high temperature.

第二部分是高压部分，进一步探索冰晶石的物质结构，测试了冰晶石常压到21.2GPa下的拉曼谱线，并作了相关的理论分析。

Urea-cyanamide method: With different catalyst, under the condition of some temperature and time, urea and ammonia manufacture cyanamide under normal pressure.

尿素-氰胺法：使用改性分子筛做催化剂，在一定温度和停留时间等反应条件下，在氨气气氛中，使尿素在常压下脱水一步制备氰胺。

The synthesis of thiourea can be divided into two steps. First, cyanamide was produced by dehydration of urea. Second, cyanamide reacted with Na_2S in water solution, which produce thiourea and NaOH.

首先第一步通过尿素常压脱水制备氰胺，第二步氰胺与硫化钠溶液在一定温度下反应生成硫脲及氢氧化钠，而氢氧化钠与通入的硫化氢气体生成硫化钠，从而继续参与反应。

Breath, muscle contraction of the buttocks; arch body, as far as possible to hold his head, right leg straight towards the ceiling (peg-leg knee in order to avoid muscle tension).

呼气，收缩臀部肌肉；拱起身体，尽量抬起头来，右腿伸直朝向天花板（膝微屈，以避免肌肉紧张）。

The cost of moving grain food products was unchanged from May, but year over year are up 8%.

粮食产品的运输费用与5月份相比没有变化，但却比去年同期高8％。